{
"@context": "http://schema.org",
"@type": "ScholarlyArticle",
"@id": "https://doi.org/10.6084/m9.figshare.5908792",
"url": "https://tandf.figshare.com/articles/journal_contribution/Isomeric_organic_ligand_dominating_polyoxometalate-based_hybrid_compounds_Synthesis_and_as_electrocatalysts_and_pH-sensitive_probes/5908792",
"additionalType": "Journal contribution",
"name": "Isomeric organic ligand dominating polyoxometalate-based hybrid compounds: synthesis and as electrocatalysts and pH-sensitive probes",
"author": [
{
"name": "Xiao Li",
"givenName": "Xiao",
"familyName": "Li"
},
{
"name": "Yunlong Wang",
"givenName": "Yunlong",
"familyName": "Wang"
},
{
"name": "Kunfeng Zhou",
"givenName": "Kunfeng",
"familyName": "Zhou"
},
{
"name": "Yunliang Wang",
"givenName": "Yunliang",
"familyName": "Wang"
},
{
"name": "Tao Han",
"givenName": "Tao",
"familyName": "Han"
},
{
"name": "Jingquan Sha",
"givenName": "Jingquan",
"familyName": "Sha"
}
],
"description": "By introducing isomeric organic ligands into polyoxometalate (POM) systems, two new POM-based hybrid compounds, [Cu6(m-pyttz)2(H2O)][HPMo12O40] (1) and [Ag3(p-H2pyttz)(p-Hpyttz)Cl][H2PMo12O40]·6H2O (2) (m-/p-H2pyttz = 3-(pyrid-3/4-yl)-5(1H-1,2,4-triazol-3-yl)-1,2,4-triazolyl), have been hydrothermally synthesized and characterized. Single-crystal structural analysis shows the m-pyttz ligands link CuI ions to generate a two-dimensional layer with hanger-like rhombus, which is pillared by the PMo12 anions in 1. Compound 2 exhibits a three-dimensional supramolecular framework, in which PMo12 anions are building blocks facilitating the extension of the whole structure. The influence of the coordination modes of m-/p-H2pyttz on the structures is discussed in detail. Furthermore, electrochemical properties of 1 and 2 have been studied and they display excellent electrocatalytic activities toward the reduction of nitrite and hydrogen peroxide and pH-dependent electrochemical behaviors.",
"license": "https://creativecommons.org/licenses/by/4.0/legalcode",
"keywords": "Biochemistry, Physical Sciences not elsewhere classified, Pharmacology, Biotechnology, Chemical Sciences not elsewhere classified, Ecology, FOS: Biological sciences, Biological Sciences not elsewhere classified, Mental Health",
"contentSize": "1463122 Bytes",
"dateCreated": "2018-03-08",
"datePublished": "2018",
"dateModified": "2023-06-02",
"@reverse": {
"isBasedOn": {
"@id": "https://doi.org/10.1080/00958972.2018.1443216",
"@type": "ScholarlyArticle"
}
},
"schemaVersion": "http://datacite.org/schema/kernel-4",
"publisher": {
"@type": "Organization",
"name": "Taylor & Francis"
},
"provider": {
"@type": "Organization",
"name": "datacite"
}
}