10.5061/DRYAD.61284N2
Xiao, Bangqing
Sichuan University
Zhu, Wenliang
Osaka University
Li, Zhong
Sichuan University
Zhu, Jiliang
Sichuan University
Zhu, Xiaohong
Sichuan University
Pezzotti, Giuseppe
Kyoto Institute of Technology
Data from: Tailoring morphology of cobalt-nickel layered double hydroxide
via different surfactants for high-performance supercapacitor
Dryad
dataset
2018
Bangqing Xiao
Jiliang Zhu
Giuseppe Pezzottib
Zhong Li
Xiaohong Zhu
Wenliang Zhu
surfactant
cobalt-nickel LDH
Supercapacitor
2018-08-13T18:07:00Z
2018-08-13T18:07:00Z
en
https://doi.org/10.1098/rsos.180867
15367685 bytes
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CC0 1.0 Universal (CC0 1.0) Public Domain Dedication
Tailoring the surface morphology of cobalt-nickel layered double hydroxide
(LDH) electrode materials was successfully achieved via the process of
cathodical electrodeposition by adding different surfactants
(hexamethyltetrammine (HMT), dodecyltrimethylammonium bromide (DTAB) or
cetyltrimethylammonium bromide (CTAB)). The as-prepared Co0.75Ni0.25(OH)2
with surfactants exhibited wrinkle-like, cauliflower-like, or net-like
structures that corresponded to distinct and better electrochemical
performances than the untreated one. In particular, a specific capacitance
of 1209.1 F g-1 was found for the cauliflower-like Co0.75Ni0.25(OH)2
electrode material using DTAB as the surfactant at a current density of 1
A g-1, whose structure boosted ion diffusion to present a good rate
ability of 64 % with a 50-fold increase in current density from 1 A g-1 to
50 A g-1. Accordingly, an asymmetric supercapacitor assembled by current
LDH electrode and activated carbon electrode showed an energy density as
high as 21.3 Wh kg−1 at a power density of 3625 W kg−1. The relationship
between the employment of surfactants and chemical performance of the LDH
electrode materials has been discussed.
dataprimary data
Sichuan
Chengdu
China