10.17188/1195187
None Available
Materials Data on NaSbO3 by Materials Project
LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
2020
Specialized Mix
36 MATERIALS SCIENCE
crystal structure
NaSbO3
Na-O-Sb
The Materials Project
2020
en
NaSbO3 crystallizes in the cubic Fd-3m space group. The structure is three-dimensional. Na1+ is bonded in a hexagonal planar geometry to six equivalent O2- atoms. All Na–O bond lengths are 2.56 Å. Sb5+ is bonded to six equivalent O2- atoms to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles are 48°. All Sb–O bond lengths are 2.01 Å. O2- is bonded to two equivalent Na1+ and two equivalent Sb5+ atoms to form a mixture of distorted edge and corner-sharing ONa2Sb2 tetrahedra.