10.15480/882.1984
Kücüker, Mehmet Ali
Mehmet Ali
Kücüker
115070991X
Wieczorek, Nils
Nils
Wieczorek
1176431889
Kuchta, Kerstin
Kerstin
Kuchta
0000-0002-0956-8247
1014529964
Copty, Nadim K.
Nadim K.
Copty
0000-0002-4807-7790
Biosorption of neodymium on Chlorella vulgaris in aqueous solution obtained from hard disk drive magnets
Public Library of Science (PLos)
2017
kinetic biosorption models
Biowissenschaften, Biologie
TUHH Universitätsbibliothek
TUHH Universitätsbibliothek
2019-01-28
2019-01-28
2017-04-07
en
Journal Article
PLoS ONE 4 (12): e0175255 (2017)
https://tubdok.tub.tuhh.de/handle/11420/1987
urn:nbn:de:gbv:830-882.025897
10.15480/882.1984
11420/1987
10.1371/journal.pone.0175255
https://creativecommons.org/licenses/by/4.0/
In recent years, biosorption is being considered as an environmental friendly technology for the recovery of rare earth metals (REE). This study investigates the optimal conditions for the biosorption of neodymium (Nd) from an aqueous solution derived from hard drive disk magnets using green microalgae (Chlorella vulgaris). The parameters considered include solution pH, temperature and biosorbent dosage. Best-fit equilibrium as well as kinetic biosorption models were also developed. At the optimal pH of 5, the maximum experimental Nd uptakes at 21, 35 and 50°C and an initial Nd concentration of 250 mg/L were 126.13, 157.40 and 77.10 mg/g, respectively. Analysis of the optimal equilibrium sorption data showed that the data fitted well (R2= 0.98) to the Langmuir isotherm model, with maximum monolayer coverage capacity (qmax) of 188.68 mg/g, and Langmuir isotherm constant (KL) of 0.029 L/mg. The corresponding separation factor (RL) is 0.12 indicating that the equilibrium sorption was favorable. The sorption kinetics of Nd ion follows well a pseudo-second order model (R2>0.99), even at low initial concentrations. These results show that Chlorella vulgaris has greater biosorption affinity for Nd than activated carbon and other algae types such as: A. Gracilis, Sargassum sp. and A. Densus.
Bundesministerium für Bildung und Forschung (BMBF)
01DL14004
Biotechnological Approach For Recovery Of Rare Earth Elements And Precious Metals From E-Waste-(BIOREEs)
1932-6203
PLOS ONE
2017
Public Library of Science (PLos)