{
"@context": "http://schema.org",
"@type": "ScholarlyArticle",
"@id": "https://doi.org/10.5281/zenodo.5782859",
"identifier": {
"@type": "PropertyValue",
"propertyID": "URL",
"value": "https://zenodo.org/record/5782859"
},
"url": "https://zenodo.org/record/5782859",
"name": "{[Mn2(L-tartrate)2(H2O)].3H2O}n- A chiral MOF Adsorption and guest dependent magnetism",
"author": [
{
"name": "Rajat Saha"
},
{
"name": "Anirban Roychowdhury"
},
{
"name": "I. M. Steele"
},
{
"name": "Susobhan Biswas"
},
{
"name": "Sanjay Kumar",
"givenName": "Sanjay",
"familyName": "Kumar",
"@type": "Person"
}
],
"description": "Department of Physics, Jadavpur University, Jadavpur, Kolkata-700 032, India E-mail : kumars@phys.jdvu.ac.in, susobhanl_b@yahoo.co.in Fax: 91-33-24138917 UGC-DAE Consortium for Scientific..: Research, III/LB-8, Kolkata-700 098, India Department of Geophysical Sciences, The University of Chicago, USA Manuscript received online 06 August 2012, revised 11 September 2012, accepted 13 September 2012 A 3D nano-porous chiralmetal-organic framework (CMOF), namely, {[Mn2(tartrate)2(H2O)].3H2O}n has been synthesized at room temperature by stirring method from mixture of MnCI2.6H2O with chiral L( +)-tartrate ligand. X-Ray single crystal structure analysis indicates that complex 1 crystallizes in chiral P21 space group. Complex 1 forms only left handed helical coordination chains along crystallographic c-axis and becomes homochiral. During formation of 3D coordination framework, 1D porous channl is created along crystallographic c-axis where guest water molecules get stability through hydrogen bonding interactions. The framework remains crystalline after loss of guest water molecules and adsorption study was done with this evacuated framework. The evacuated framework shows nano-porosity and adsorbs 22 ml g-1 N2 at 77 K with type III adsorption isotherm. Guest dependent magnetic study has been carried out. Both complex 1 and the evacuated complex exhibit antiferromagnetic behavior.",
"license": [
"https://creativecommons.org/licenses/by/4.0/legalcode",
"info:eu-repo/semantics/openAccess"
],
"keywords": "3D metal-organic framework, homochirality, adsorption study, guest dependent magnetic behavior",
"inLanguage": "en",
"datePublished": "2013-08-31",
"schemaVersion": "http://datacite.org/schema/kernel-4",
"publisher": {
"@type": "Organization",
"name": "Zenodo"
},
"provider": {
"@type": "Organization",
"name": "datacite"
}
}