{"data":{"id":"10.6084/m9.figshare.c.4285964.v1","type":"dois","attributes":{"doi":"10.6084/m9.figshare.c.4285964.v1","prefix":"10.6084","suffix":"m9.figshare.c.4285964.v1","identifiers":[{"identifier":"https://doi.org/10.6084/m9.figshare.c.4285964.v1","identifierType":"DOI"}],"alternateIdentifiers":[{"alternateIdentifierType":"DOI","alternateIdentifier":"https://doi.org/10.6084/m9.figshare.c.4285964.v1"}],"creators":[{"name":"Shuzhen, Ni","nameType":"Personal","givenName":"Ni","familyName":"Shuzhen","affiliation":[],"nameIdentifiers":[]},{"name":"Liang, Jiao","nameType":"Personal","givenName":"Jiao","familyName":"Liang","affiliation":[],"nameIdentifiers":[]},{"name":"Hui, Zhang","nameType":"Personal","givenName":"Zhang","familyName":"Hui","affiliation":[],"nameIdentifiers":[]},{"name":"Yongchao, Zhang","nameType":"Personal","givenName":"Zhang","familyName":"Yongchao","affiliation":[],"nameIdentifiers":[]},{"name":"Guigan, Fang","nameType":"Personal","givenName":"Fang","familyName":"Guigan","affiliation":[],"nameIdentifiers":[]},{"name":"Huining, Xiao","nameType":"Personal","givenName":"Xiao","familyName":"Huining","affiliation":[],"nameIdentifiers":[]},{"name":"Hongqi, Dai","nameType":"Personal","givenName":"Dai","familyName":"Hongqi","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Supplementary material from \"Enhancing hydrophobicity, strength and UV shielding capacity of starch film via novel co-cross-linking in neutral conditions\""}],"publisher":"Figshare","container":{},"publicationYear":2018,"subjects":[{"subject":"90499 Chemical Engineering not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Chemical engineering","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"30399 Macromolecular and Materials Chemistry not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Chemical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"}],"contributors":[],"dates":[{"date":"2018-10-31","dateType":"Created"},{"date":"2018-10-31","dateType":"Updated"},{"date":"2018","dateType":"Issued"}],"language":null,"types":{"ris":"GEN","bibtex":"misc","citeproc":"article","schemaOrg":"Collection","resourceType":"Collection","resourceTypeGeneral":"Collection"},"relatedIdentifiers":[{"relationType":"IsSupplementTo","relatedIdentifier":"10.1098/rsos.181206","relatedIdentifierType":"DOI"},{"relationType":"IsIdenticalTo","relatedIdentifier":"10.6084/m9.figshare.c.4285964","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":[],"formats":[],"version":null,"rightsList":[{"rights":"CC BY 4.0","rightsUri":"https://creativecommons.org/licenses/by/4.0"}],"descriptions":[{"description":"Starch films are developed as the biodegradable packaging materials to replace the petroleum-based materials in recent years. Thus, it is extremely beneficial to improve the hydrophobicity and mechanical strength of starch films, through a novel approach of co-cross-linking in neutral conditions, with glyoxal and AZC. In this work, systematic studies have been conducted on assessing the performance of the co-cross-linked starch along with the control starch and starch cross-linked by glyoxal or AZC alone. Results showed that the co-cross-linked starch films exhibited significantly improved hydrophobicity and strength and the wet stress reached to 1.53 MPa, compared to the control, glyoxal or AZC cross-linked starch films. More interestingly, the co-cross-linked film also demonstrated excellent UV shielding capacity and transmittance at visible wavelength range. The reaction mechanism was revealed based on the findings from UV, FT-IR and NMR spectra. This work established an innovative approach to improve the performance of starch film in neutral conditions for the packaging applications.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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","url":"https://figshare.com/collections/Supplementary_material_from_Enhancing_hydrophobicity_strength_and_UV_shielding_capacity_of_starch_film_via_novel_co-cross-linking_in_neutral_conditions_/4285964/1","contentUrl":null,"metadataVersion":1,"schemaVersion":"http://datacite.org/schema/kernel-4","source":"mds","isActive":true,"state":"findable","reason":null,"viewCount":0,"viewsOverTime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