{"data":{"id":"10.6084/m9.figshare.c.3689602","type":"dois","attributes":{"doi":"10.6084/m9.figshare.c.3689602","prefix":"10.6084","suffix":"m9.figshare.c.3689602","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Goehring, Lucas","nameType":"Personal","givenName":"Lucas","familyName":"Goehring","affiliation":[],"nameIdentifiers":[]},{"name":"Li, Joaquim","nameType":"Personal","givenName":"Joaquim","familyName":"Li","affiliation":[],"nameIdentifiers":[]},{"name":"Pree-Cha Kiatkirakajorn","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Supplementary material from \"Drying paint: from micro-scale dynamics to mechanical instabilities\""}],"publisher":"Figshare","container":{},"publicationYear":2017,"subjects":[{"subject":"90499 Chemical Engineering not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Chemical engineering","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"91504 Fluidisation and Fluid Mechanics","subjectScheme":"FOR"},{"subject":"FOS: Other engineering and technologies","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"30699 Physical Chemistry not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Chemical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"}],"contributors":[],"dates":[{"date":"2017-02-13","dateType":"Created"},{"date":"2017-02-13","dateType":"Updated"},{"date":"2017","dateType":"Issued"}],"language":null,"types":{"ris":"GEN","bibtex":"misc","citeproc":"article","schemaOrg":"Collection","resourceType":"Collection","resourceTypeGeneral":"Collection"},"relatedIdentifiers":[{"relationType":"IsSupplementTo","relatedIdentifier":"10.1098/rsta.2016.0161","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":[],"formats":[],"version":null,"rightsList":[{"rights":"CC BY","rightsUri":"https://creativecommons.org/licenses/by/4.0"}],"descriptions":[{"description":"Charged colloidal dispersions make up the basis of a broad range of industrial and commercial products, from paints to coatings and additives in cosmetics. During drying, an initially liquid dispersion of such particles is slowly concentrated into a solid, displaying a range of mechanical instabilities in response to highly variable internal pressures. Here we summarize the current appreciation of this process by pairing an advection-diffusion model of particle motion with a Poisson–Boltzmann cell model of inter-particle interactions, to predict the concentration gradients around a drying colloidal film. We then test these predictions with osmotic compression experiments on colloidal silica, and small-angle X-ray scattering experiments on silica dispersions drying in Hele–Shaw cells. Finally, we use the details of the microscopic physics at play in these dispersions to explore how two macroscopic mechanical instabilities—shear-banding and fracture—can be controlled.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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","url":"https://figshare.com/collections/Supplementary_material_from_Drying_paint_from_micro-scale_dynamics_to_mechanical_instabilities_/3689602","contentUrl":null,"metadataVersion":2,"schemaVersion":"http://datacite.org/schema/kernel-4","source":"api","isActive":true,"state":"findable","reason":null,"viewCount":0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