{"data":{"id":"10.6084/m9.figshare.c.3267544","type":"dois","attributes":{"doi":"10.6084/m9.figshare.c.3267544","prefix":"10.6084","suffix":"m9.figshare.c.3267544","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"E.S. Vikulova","affiliation":[],"nameIdentifiers":[]},{"name":"I.Yu. Ilyin","affiliation":[],"nameIdentifiers":[]},{"name":"K.I. Karakovskaya","affiliation":[],"nameIdentifiers":[]},{"name":"D.A. Piryazev","affiliation":[],"nameIdentifiers":[]},{"name":"A.E. Turgambaeva","affiliation":[],"nameIdentifiers":[]},{"name":"N.B. Morozova","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Volatile iridium(I) complexes with β-diketones and cyclooctadiene: Syntheses, structures and thermal properties"}],"publisher":"Figshare","container":{},"publicationYear":2016,"subjects":[{"subject":"Biophysics"},{"subject":"Biochemistry"},{"subject":"Space Science"},{"subject":"29999 Physical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Physical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Physical sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Biotechnology"},{"subject":"39999 Chemical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Chemical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Chemical sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Sociology"},{"subject":"FOS: Sociology","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Sociology","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Inorganic Chemistry"}],"contributors":[],"dates":[{"date":"2016-06-08","dateType":"Created"},{"date":"2016-06-08","dateType":"Updated"},{"date":"2016","dateType":"Issued"}],"language":null,"types":{"ris":"GEN","bibtex":"misc","citeproc":"article","schemaOrg":"Collection","resourceType":"Collection","resourceTypeGeneral":"Collection"},"relatedIdentifiers":[{"relationType":"IsSupplementTo","relatedIdentifier":"10.1080/00958972.2016.1198955","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":[],"formats":[],"version":null,"rightsList":[{"rights":"CC-BY","rightsUri":"http://creativecommons.org/licenses/by/3.0/us"}],"descriptions":[{"description":"A series of volatile mixed-ligand iridium(I) complexes [Ir(cod)(L)] (cod = cyclooctadiene-1,5, L = R\u003csup\u003e1\u003c/sup\u003eC(O)CHC(O)R\u003csup\u003e2\u003c/sup\u003e, R\u003csup\u003e1\u003c/sup\u003e = CF\u003csub\u003e3\u003c/sub\u003e, R\u003csup\u003e2\u003c/sup\u003e = CF\u003csub\u003e3\u003c/sub\u003e – hfac \u003cb\u003e1\u003c/b\u003e, Me – tfac \u003cb\u003e2\u003c/b\u003e; \u003csup\u003e\u003ci\u003et\u003c/i\u003e\u003c/sup\u003eBu – ptac \u003cb\u003e3\u003c/b\u003e, Ph – btfac \u003cb\u003e4\u003c/b\u003e, R\u003csup\u003e1\u003c/sup\u003e = R\u003csup\u003e2\u003c/sup\u003e = Me – acac \u003cb\u003e5\u003c/b\u003e; \u003csup\u003e\u003ci\u003et\u003c/i\u003e\u003c/sup\u003eBu – thd \u003cb\u003e6\u003c/b\u003e) was synthesized and investigated in terms of usage in MOCVD processes. Compounds \u003cb\u003e3\u003c/b\u003e and \u003cb\u003e4\u003c/b\u003e were obtained for the first time. All compounds were investigated by elemental analysis, NMR spectroscopy, thermogravimetry and mass spectrometry. Crystal structures of \u003cb\u003e2\u003c/b\u003e-\u003cb\u003e4\u003c/b\u003e and \u003cb\u003e6\u003c/b\u003e were determined by single-crystal XRD. The influence of β-diketonate ligand on the thermal properties of complexes in condensed and gas phase was revealed. The following volatility order was arranged: L = hfac \u003cb\u003e1\u003c/b\u003e \u0026gt; tfac \u003cb\u003e2\u003c/b\u003e ≈ ptac \u003cb\u003e3\u003c/b\u003e \u0026gt; acac \u003cb\u003e5\u003c/b\u003e \u0026gt; thd \u003cb\u003e6\u003c/b\u003e \u0026gt; btfac \u003cb\u003e4\u003c/b\u003e. Complexes \u003cb\u003e1\u003c/b\u003e and \u003cb\u003e6\u003c/b\u003e vapors demonstrated the lowest and the highest thermostability, respectively.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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