{"data":{"id":"10.6084/m9.figshare.c.3264160","type":"dois","attributes":{"doi":"10.6084/m9.figshare.c.3264160","prefix":"10.6084","suffix":"m9.figshare.c.3264160","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Agrawal, Rati","nameType":"Personal","givenName":"Rati","familyName":"Agrawal","affiliation":[],"nameIdentifiers":[]},{"name":"Goyal, Varsha","nameType":"Personal","givenName":"Varsha","familyName":"Goyal","affiliation":[],"nameIdentifiers":[]},{"name":"Raakhi Gupta","affiliation":[],"nameIdentifiers":[]},{"name":"Bhatnagar, Pradeep","nameType":"Personal","givenName":"Pradeep","familyName":"Bhatnagar","affiliation":[],"nameIdentifiers":[]},{"name":"G. Bhargavi","affiliation":[],"nameIdentifiers":[]},{"name":"Bansal, Raj K.","nameType":"Personal","givenName":"Raj K.","familyName":"Bansal","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Synthesis, characterization, and insecticidal activity of new tin (IV) complexes"}],"publisher":"Figshare","container":{},"publicationYear":2016,"subjects":[{"subject":"Biophysics"},{"subject":"Biochemistry"},{"subject":"29999 Physical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Physical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Physical sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Medicine"},{"subject":"Biotechnology"},{"subject":"39999 Chemical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Chemical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Chemical sciences","subjectScheme":"Fields of Science and Technology (FOS)"}],"contributors":[],"dates":[{"date":"2016-06-02","dateType":"Created"},{"date":"2016-06-02","dateType":"Updated"},{"date":"2016","dateType":"Issued"}],"language":null,"types":{"ris":"GEN","bibtex":"misc","citeproc":"article","schemaOrg":"Collection","resourceType":"Collection","resourceTypeGeneral":"Collection"},"relatedIdentifiers":[{"relationType":"IsSupplementTo","relatedIdentifier":"10.1080/10426507.2015.1130048","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":[],"formats":[],"version":null,"rightsList":[{"rights":"CC-BY","rightsUri":"http://creativecommons.org/licenses/by/3.0/us"}],"descriptions":[{"description":"A three-component reaction of dimethyltin dibromide with imidazo[1,2-\u003ci\u003ea\u003c/i\u003e]pyridine, pyridine derivatives, or isoquinoline and allyl bromide in refluxing ethanol affords the ionic complex, bis(1-allylcycloiminium) dimethyltetrabromostannate (II). The reaction involves N-allylation of cycloimine accompanied by the coordination of two bromide ions with the tin atom of dimethyltin dibromide. The complexes have been characterized by infrared and \u003csup\u003e1\u003c/sup\u003eH NMR, \u003csup\u003e13\u003c/sup\u003eC NMR, and \u003csup\u003e119\u003c/sup\u003eSn NMR studies. The X-ray crystal structure analysis of a complex reveals the tin atom to be hexacoordinated and the dimethyltetrabromostannate (II) anion having octahedral geometry. Some of the complexes tested for their insecticidal activity are found to exhibit strong activity against \u003ci\u003eTribolium castaneum\u003c/i\u003e insect with LC\u003csub\u003e50\u003c/sub\u003e ranging from 0.4 to 0.8 ppm.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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