{"data":{"id":"10.6084/m9.figshare.c.3262930.v1","type":"dois","attributes":{"doi":"10.6084/m9.figshare.c.3262930.v1","prefix":"10.6084","suffix":"m9.figshare.c.3262930.v1","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Aysu, Tevfik","nameType":"Personal","givenName":"Tevfik","familyName":"Aysu","affiliation":[],"nameIdentifiers":[]},{"name":"Durak, Halil","nameType":"Personal","givenName":"Halil","familyName":"Durak","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Catalytic effects of borax and iron(III) chloride on supercritical liquefaction of \u003ci\u003eAnchusa azurea\u003c/i\u003e with methanol and isopropanol"}],"publisher":"Figshare","container":{},"publicationYear":2016,"subjects":[{"subject":"Biochemistry"},{"subject":"29999 Physical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Physical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Physical sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Microbiology"},{"subject":"FOS: Biological sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Biological sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Biotechnology"},{"subject":"39999 Chemical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Chemical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Chemical sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Ecology"},{"subject":"Inorganic Chemistry"},{"subject":"Plant Biology"}],"contributors":[],"dates":[{"date":"2016-06-01","dateType":"Created"},{"date":"2016-06-01","dateType":"Updated"},{"date":"2016","dateType":"Issued"}],"language":null,"types":{"ris":"GEN","bibtex":"misc","citeproc":"article","schemaOrg":"Collection","resourceType":"Collection","resourceTypeGeneral":"Collection"},"relatedIdentifiers":[{"relationType":"IsSupplementTo","relatedIdentifier":"10.1080/15567036.2014.958633","relatedIdentifierType":"DOI"},{"relationType":"IsIdenticalTo","relatedIdentifier":"10.6084/m9.figshare.c.3262930","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":[],"formats":[],"version":null,"rightsList":[{"rights":"CC-BY","rightsUri":"http://creativecommons.org/licenses/by/3.0/us"}],"descriptions":[{"description":"\u003ci\u003eAnchusa azurea\u003c/i\u003e is a lignocellulosic gramineous plant, and it has been selected as a renewable feedstock to be used in a liquefaction process to obtain biofuel. Milled \u003ci\u003eAnchusa azurea\u003c/i\u003e stalks were converted to liquid products in methanol and isopropanol with (borax or iron(III) chloride) and without catalyst in an autoclave at temperatures of 260, 280, and 300°C. The liquefaction parameter effects such as catalyst, solvents, and temperature were investigated. The highest percentages of liquid yields from methanol and isopropanol conversions were 64.70% (with borax) and 29.20% (with borax) at 300°C in the catalytic runs, respectively. The highest conversion (73.80%) was obtained in methanol with borax catalyst at the same temperature. The obtained liquid products at 300°C were analyzed and characterized by elemental, Fourier transform infrared spectroscopy and gas chromatography–mass spectrometry (GC-MS). Seventy-three different compounds have been identified by GC-MS in the liquid products obtained in methanol at 300°C.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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