{"data":{"id":"10.6084/m9.figshare.c.3262384.v1","type":"dois","attributes":{"doi":"10.6084/m9.figshare.c.3262384.v1","prefix":"10.6084","suffix":"m9.figshare.c.3262384.v1","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Pramanik, Harun A. R.","nameType":"Personal","givenName":"Harun A. R.","familyName":"Pramanik","affiliation":[],"nameIdentifiers":[]},{"name":"Chanda, Soumitra","nameType":"Personal","givenName":"Soumitra","familyName":"Chanda","affiliation":[],"nameIdentifiers":[]},{"name":"Bhattacharjee, Chira R.","nameType":"Personal","givenName":"Chira R.","familyName":"Bhattacharjee","affiliation":[],"nameIdentifiers":[]},{"name":"Pradip C. Paul","affiliation":[],"nameIdentifiers":[]},{"name":"Paritosh Mondal","affiliation":[],"nameIdentifiers":[]},{"name":"S. Krishna Prasad","affiliation":[],"nameIdentifiers":[]},{"name":"D. S. Shankar Rao","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Iron(III) metallomesogen of [N\u003csub\u003e2\u003c/sub\u003eO\u003csub\u003e2\u003c/sub\u003e] donor Schiff base ligand containing 4-substituted alkoxy chains"}],"publisher":"Figshare","container":{},"publicationYear":2016,"subjects":[{"subject":"Biophysics"},{"subject":"Biochemistry"},{"subject":"29999 Physical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Physical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Physical sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Biotechnology"},{"subject":"39999 Chemical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Chemical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Chemical sciences","subjectScheme":"Fields of Science and Technology (FOS)"}],"contributors":[],"dates":[{"date":"2016-05-31","dateType":"Created"},{"date":"2016-05-31","dateType":"Updated"},{"date":"2016","dateType":"Issued"}],"language":null,"types":{"ris":"GEN","bibtex":"misc","citeproc":"article","schemaOrg":"Collection","resourceType":"Collection","resourceTypeGeneral":"Collection"},"relatedIdentifiers":[{"relationType":"IsSupplementTo","relatedIdentifier":"10.1080/02678292.2016.1190037","relatedIdentifierType":"DOI"},{"relationType":"IsIdenticalTo","relatedIdentifier":"10.6084/m9.figshare.c.3262384","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":[],"formats":[],"version":null,"rightsList":[{"rights":"CC-BY","rightsUri":"http://creativecommons.org/licenses/by/3.0/us"}],"descriptions":[{"description":"Two new square pyramidal iron(III)-complexes of ‘salen’-type Schiff base ligands containing 4-substituted long alkoxy arms on the aromatic rings, [Fe(4-C\u003csub\u003e16\u003c/sub\u003eH\u003csub\u003e33\u003c/sub\u003eO)\u003csub\u003e2\u003c/sub\u003esalcn)]Cl and [Fe(4-C\u003csub\u003e16\u003c/sub\u003eH\u003csub\u003e33\u003c/sub\u003eO)\u003csub\u003e2\u003c/sub\u003esalophen)]Cl {salcn = N,Nʹ-cyclohexanebis(salicylideneiminato) and salophen = N,Nʹ-phenylenebis(salicylideneiminato)}, have been successfully synthesised, and their mesomorphic property investigated. The ligands and complexes were characterised by elemental analyses, UV–Vis, FT-IR, ESI–MS, \u003csup\u003e1\u003c/sup\u003eH and \u003csup\u003e13\u003c/sup\u003eC NMR (for ligands only). The phase behaviour of the iron(III) complexes were ascertained by differential scanning calorimetry, polarising optical microscopy and variable temperature PXRD study. Ligands are non-mesomorphic, however, mesomorphism got induced upon complexation with the iron(III) centre. X-ray diffraction study revealed a layer-like arrangement of the five coordinated mesomorphic iron(III) complexes. The mesophase is stable over a wide range of temperature. The density functional theory calculations were carried out using Gaussian 09 program at B3LYP level using unrestricted 6–31G (d, p) basis set to obtain the optimised geometry of the iron(III) complexes.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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