{"data":{"id":"10.6084/m9.figshare.c.3256621.v1","type":"dois","attributes":{"doi":"10.6084/m9.figshare.c.3256621.v1","prefix":"10.6084","suffix":"m9.figshare.c.3256621.v1","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Johnston, Hannah M.","nameType":"Personal","givenName":"Hannah M.","familyName":"Johnston","affiliation":[],"nameIdentifiers":[]},{"name":"Palacios, Philip M.","nameType":"Personal","givenName":"Philip M.","familyName":"Palacios","affiliation":[],"nameIdentifiers":[]},{"name":"Pierce, Brad S.","nameType":"Personal","givenName":"Brad S.","familyName":"Pierce","affiliation":[],"nameIdentifiers":[]},{"name":"Green, Kayla N.","nameType":"Personal","givenName":"Kayla N.","familyName":"Green","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Spectroscopic and solid state evaluations of tetra-aza macrocyclic cobalt complexes with parallels to the classic cobalt(II) chloride equilibrium"}],"publisher":"Figshare","container":{},"publicationYear":2016,"subjects":[{"subject":"Biophysics"},{"subject":"Biochemistry"},{"subject":"29999 Physical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Physical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Physical sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Microbiology"},{"subject":"FOS: Biological sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Biological sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"59999 Environmental Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Earth and related environmental sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Earth and related environmental sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"39999 Chemical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Chemical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Chemical sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Marine Biology"},{"subject":"Mental Health"}],"contributors":[],"dates":[{"date":"2016-05-20","dateType":"Created"},{"date":"2016-05-20","dateType":"Updated"},{"date":"2016","dateType":"Issued"}],"language":null,"types":{"ris":"GEN","bibtex":"misc","citeproc":"article","schemaOrg":"Collection","resourceType":"Collection","resourceTypeGeneral":"Collection"},"relatedIdentifiers":[{"relationType":"IsSupplementTo","relatedIdentifier":"10.1080/00958972.2016.1191630","relatedIdentifierType":"DOI"},{"relationType":"IsIdenticalTo","relatedIdentifier":"10.6084/m9.figshare.c.3256621","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":[],"formats":[],"version":null,"rightsList":[{"rights":"CC-BY","rightsUri":"http://creativecommons.org/licenses/by/3.0/us"}],"descriptions":[{"description":"The Co(III) complex of 3,6,9,15-tetra-azabicyclo[9.3.1]penta-deca-1,11,13-triene (\u003cb\u003eL1\u003c/b\u003e) has been synthesized in DMF and isolated as a blue solid (\u003cb\u003e1\u003c/b\u003e) ([\u003cb\u003eL1\u003c/b\u003eCo\u003csup\u003eIII\u003c/sup\u003eClX]\u003csup\u003en+\u003c/sup\u003e, X = Cl\u003csup\u003e-\u003c/sup\u003e or DMF, n = 1 or 2). Complex \u003cb\u003e1\u003c/b\u003e exhibits solution behavior similar to the classic cobalt(II) chloride equilibrium. When \u003cb\u003e1\u003c/b\u003e is dissolved in water, the solution is pink and this complex exists as \u003cb\u003e1a\u003c/b\u003e, which consists of a cobalt(III) bound to \u003cb\u003eL1\u003c/b\u003e and two \u003ci\u003ecis\u003c/i\u003e chlorides with a perchlorate counter-ion to balance the complex charge ([\u003cb\u003eL1\u003c/b\u003eCo\u003csup\u003eIII\u003c/sup\u003eCl\u003csub\u003e2\u003c/sub\u003e][ClO\u003csub\u003e4\u003c/sub\u003e]). In contrast, when \u003cb\u003e1\u003c/b\u003e is dissolved in DMF or other organic solvents the solution is blue and is observed as \u003cb\u003e1b\u003c/b\u003e. The \u003cb\u003e1b\u003c/b\u003e complex salt contains two cobalt centers. One cobalt(III) is bound to \u003cb\u003eL1\u003c/b\u003e, Cl\u003csup\u003e-\u003c/sup\u003e, and DMF. Charge balance is accomplished by the second cobalt center: [Co\u003csup\u003eII\u003c/sup\u003eCl\u003csub\u003e4\u003c/sub\u003e]\u003csup\u003e2-\u003c/sup\u003e, thus making \u003cb\u003e1b\u003c/b\u003e (\u003cb\u003eL1\u003c/b\u003eCo\u003csup\u003eIII\u003c/sup\u003eCl(DMF)][Co\u003csup\u003eII\u003c/sup\u003eCl\u003csub\u003e4\u003c/sub\u003e]). This equilibrium was confirmed using UV-visible spectroscopy, EPR, and X-ray crystallography.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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