{"data":{"id":"10.6084/m9.figshare.c.3253486.v1","type":"dois","attributes":{"doi":"10.6084/m9.figshare.c.3253486.v1","prefix":"10.6084","suffix":"m9.figshare.c.3253486.v1","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Cavero, Emma","nameType":"Personal","givenName":"Emma","familyName":"Cavero","affiliation":[],"nameIdentifiers":[]},{"name":"Serrano, José Luis","nameType":"Personal","givenName":"José Luis","familyName":"Serrano","affiliation":[],"nameIdentifiers":[]},{"name":"Giménez, Raquel","nameType":"Personal","givenName":"Raquel","familyName":"Giménez","affiliation":[],"nameIdentifiers":[]},{"name":"Piñol, Milagros","nameType":"Personal","givenName":"Milagros","familyName":"Piñol","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Liquid crystalline dendrimers based on cinnamates and coumarins"}],"publisher":"Figshare","container":{},"publicationYear":2016,"subjects":[{"subject":"Biophysics"},{"subject":"Biochemistry"},{"subject":"29999 Physical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Physical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Physical sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Microbiology"},{"subject":"FOS: Biological sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Biological sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Physiology"},{"subject":"39999 Chemical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Chemical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Chemical sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Inorganic Chemistry"}],"contributors":[],"dates":[{"date":"2016-05-13","dateType":"Created"},{"date":"2016-05-13","dateType":"Updated"},{"date":"2016","dateType":"Issued"}],"language":null,"types":{"ris":"GEN","bibtex":"misc","citeproc":"article","schemaOrg":"Collection","resourceType":"Collection","resourceTypeGeneral":"Collection"},"relatedIdentifiers":[],"relatedItems":[],"sizes":[],"formats":[],"version":null,"rightsList":[{"rights":"CC-BY","rightsUri":"http://creativecommons.org/licenses/by/3.0/us"}],"descriptions":[{"description":"New poly(propylene imine) (PPI) dendrimers modified at the periphery with mesomorphic 4-cyanobiphenyl units and cinnamate- or coumarin-based photoactive moieties were synthesised and structurally characterised. The photoactive moieties were structurally designed to be liquid crystalline compatible and to reduce the tendency towards crystallisation of the final material. Thermal and liquid crystal properties were studied by POM, DSC, TGA and XRD. The results show that all dendrimers displayed a smectic A mesophase. Dendrimers with high transparency in the visible region but with different absorption spectra were obtained, rendering materials that are easy to monitor in light-irradiation experiments.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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","url":"https://figshare.com/collections/Liquid_crystalline_dendrimers_based_o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