{"data":{"id":"10.6084/m9.figshare.c.3246814","type":"dois","attributes":{"doi":"10.6084/m9.figshare.c.3246814","prefix":"10.6084","suffix":"m9.figshare.c.3246814","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Onwudiwe, Damian C.","nameType":"Personal","givenName":"Damian C.","familyName":"Onwudiwe","affiliation":[],"nameIdentifiers":[]},{"name":"Ekennia, Anthony C.","nameType":"Personal","givenName":"Anthony C.","familyName":"Ekennia","affiliation":[],"nameIdentifiers":[]},{"name":"Hosten, Eric","nameType":"Personal","givenName":"Eric","familyName":"Hosten","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Syntheses, characterization, and antimicrobial properties of nickel(II) dithiocarbamate complexes containing NiS\u003csub\u003e4\u003c/sub\u003e and NiS\u003csub\u003e2\u003c/sub\u003ePN moieties"}],"publisher":"Figshare","container":{},"publicationYear":2016,"subjects":[{"subject":"Biophysics"},{"subject":"Biochemistry"},{"subject":"29999 Physical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Physical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Physical sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Microbiology"},{"subject":"FOS: Biological sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Biological sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Biotechnology"},{"subject":"59999 Environmental Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Earth and related environmental sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Earth and related environmental sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"39999 Chemical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Chemical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Chemical sciences","subjectScheme":"Fields of Science and Technology (FOS)"}],"contributors":[],"dates":[{"date":"2016-05-07","dateType":"Created"},{"date":"2016-06-01","dateType":"Updated"},{"date":"2016","dateType":"Issued"}],"language":null,"types":{"ris":"GEN","bibtex":"misc","citeproc":"article","schemaOrg":"Collection","resourceType":"Collection","resourceTypeGeneral":"Collection"},"relatedIdentifiers":[{"relationType":"IsSupplementTo","relatedIdentifier":"10.1080/00958972.2016.1186800","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":[],"formats":[],"version":null,"rightsList":[{"rights":"CC-BY","rightsUri":"http://creativecommons.org/licenses/by/3.0/us"}],"descriptions":[{"description":"Three Ni(II) dithiocarbamate complexes, [Ni(buphdtc)\u003csub\u003e2\u003c/sub\u003e] (\u003cb\u003e1\u003c/b\u003e), [Ni(buphdtc)(PPh\u003csub\u003e3\u003c/sub\u003e)(NCS)] (\u003cb\u003e2\u003c/b\u003e) and [Ni(buphdtc)(PPh\u003csub\u003e3\u003c/sub\u003e)(NC)] (\u003cb\u003e3\u003c/b\u003e) (where bu = butyl and ph = phenyl), were synthesized and characterized by elemental analysis, UVvis, and FTIR spectroscopies. Complexes \u003cb\u003e1\u003c/b\u003e and \u003cb\u003e2\u003c/b\u003e were further characterized by single-crystal X-ray structural analysis. The single-crystal X-ray structural analysis indicates a slightly distorted square planar geometry. In \u003cb\u003e2\u003c/b\u003e and \u003cb\u003e3\u003c/b\u003e, the influences of the auxiliary ligands (PPh\u003csub\u003e3\u003c/sub\u003e, NCS, and NC) on their steric and electronic properties were observed. Thermal studies of the complexes showed decomposition starting at 250–300 °C, leading to formation of nickel sulfide phases around 400 °C. The complexes were screened against some bacteria strains, \u003ci\u003eStaphylococcus aureus\u003c/i\u003e, \u003ci\u003eS\u003c/i\u003e\u003ci\u003etreptococcus pneumoniae\u003c/i\u003e, \u003ci\u003eBacillus subtilis\u003c/i\u003e, \u003ci\u003eEscherichia coli\u003c/i\u003e, \u003ci\u003eK\u003c/i\u003e\u003ci\u003elebsiella oxytoca\u003c/i\u003e and \u003ci\u003eP\u003c/i\u003e\u003ci\u003eseudomonas aeruginosa\u003c/i\u003e, and two fungi species, \u003ci\u003eA\u003c/i\u003e\u003ci\u003espergillus niger\u003c/i\u003e and \u003ci\u003eF\u003c/i\u003e\u003ci\u003eusarium oxysporum\u003c/i\u003e. The complexes showed moderate-to-strong antimicrobial potentials, with [Ni(buphdtc)\u003csub\u003e2\u003c/sub\u003e] (\u003cb\u003e1\u003c/b\u003e) displaying the best antimicrobial activity. Fluconazole and streptomycin were used as reference drugs for antifungal and antibacterial assays, respectively.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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