{"data":{"id":"10.6084/m9.figshare.c.3150622","type":"dois","attributes":{"doi":"10.6084/m9.figshare.c.3150622","prefix":"10.6084","suffix":"m9.figshare.c.3150622","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Nuša Hojnik","affiliation":[],"nameIdentifiers":[]},{"name":"Matjaž Kristl","affiliation":[],"nameIdentifiers":[]},{"name":"Ferk, Gregor","nameType":"Personal","givenName":"Gregor","familyName":"Ferk","affiliation":[],"nameIdentifiers":[]},{"name":"Golobič, Amalija","nameType":"Personal","givenName":"Amalija","familyName":"Golobič","affiliation":[],"nameIdentifiers":[]},{"name":"Turel, Matejka","nameType":"Personal","givenName":"Matejka","familyName":"Turel","affiliation":[],"nameIdentifiers":[]},{"name":"Jagličić, Zvonko","nameType":"Personal","givenName":"Zvonko","familyName":"Jagličić","affiliation":[],"nameIdentifiers":[]},{"name":"Drofenik, Miha","nameType":"Personal","givenName":"Miha","familyName":"Drofenik","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Complexes of Eu(III), Tb(III) and Cu(II) with proton transfer compound between 2,6-pyridinedicarboxylic acid and 2-aminobenzothiazole: characterization of the structures and physical properties"}],"publisher":"Figshare","container":{},"publicationYear":2016,"subjects":[{"subject":"Biophysics"},{"subject":"Biochemistry"},{"subject":"29999 Physical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Physical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Physical sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Medicine"},{"subject":"39999 Chemical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Chemical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Chemical sciences","subjectScheme":"Fields of Science and Technology (FOS)"}],"contributors":[],"dates":[{"date":"2016-04-26","dateType":"Created"},{"date":"2016-06-02","dateType":"Updated"},{"date":"2016","dateType":"Issued"}],"language":null,"types":{"ris":"GEN","bibtex":"misc","citeproc":"article","schemaOrg":"Collection","resourceType":"Collection","resourceTypeGeneral":"Collection"},"relatedIdentifiers":[{"relationType":"IsSupplementTo","relatedIdentifier":"10.1080/00958972.2016.1182632","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":[],"formats":[],"version":null,"rightsList":[{"rights":"CC-BY","rightsUri":"http://creativecommons.org/licenses/by/3.0/us"}],"descriptions":[{"description":"A proton transfer compound, (ABTH)\u003csup\u003e+\u003c/sup\u003e(PydcH)\u003csup\u003e−\u003c/sup\u003e (\u003cb\u003e1\u003c/b\u003e), obtained from 2-aminobenzothiazole (ABT) and 2,6-pyridinedicarboxylic acid (Pydc) as well as its Eu(III), Tb(III), and Cu(II) complexes (ABT)\u003csub\u003e3\u003c/sub\u003e[Eu(Pydc)\u003csub\u003e3\u003c/sub\u003e]·5H\u003csub\u003e2\u003c/sub\u003eO (\u003cb\u003e2\u003c/b\u003e), (ABT)\u003csub\u003e3\u003c/sub\u003e[Tb(Pydc)\u003csub\u003e3\u003c/sub\u003e]·5H\u003csub\u003e2\u003c/sub\u003eO (\u003cb\u003e3\u003c/b\u003e), and (ABT)[Cu(Pydc)(PydcH)]·3H\u003csub\u003e2\u003c/sub\u003eO (\u003cb\u003e4\u003c/b\u003e) were obtained under ambient conditions and structurally verified by single-crystal X-ray diffraction analyses and further characterized by elemental analyses, powder X-ray diffraction (PXRD), infrared spectroscopy (IR), thermogravimetric analysis (TGA), and magnetic measurements. Compounds \u003cb\u003e2\u003c/b\u003e–\u003cb\u003e4\u003c/b\u003e are the first known solids containing complex anions with Pydc ligands, 2-aminobenzothiazole cations (ABT), and solvate water molecules. During the synthesis of \u003cb\u003e3\u003c/b\u003e, a secondary phase with the formula ABTCl∙H\u003csub\u003e2\u003c/sub\u003eO was obtained and characterized by elemental analysis and single-crystal X-ray diffraction. The asymmetric unit of \u003cb\u003e5\u003c/b\u003e consists of six symmetry independent ABT cations, six chlorides, and six water molecules. The two lanthanide complexes showed characteristic emissions of Eu\u003csup\u003e3+\u003c/sup\u003e and Tb\u003csup\u003e3+\u003c/sup\u003e ions. The good solubilities of these complexes in water and their luminescence properties make them attractive luminescent labels of biological molecules.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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