{"data":{"id":"10.6084/m9.figshare.c.3145930.v1","type":"dois","attributes":{"doi":"10.6084/m9.figshare.c.3145930.v1","prefix":"10.6084","suffix":"m9.figshare.c.3145930.v1","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Burg, Ariela","nameType":"Personal","givenName":"Ariela","familyName":"Burg","affiliation":[],"nameIdentifiers":[]},{"name":"Fastovesky, Ella","nameType":"Personal","givenName":"Ella","familyName":"Fastovesky","affiliation":[],"nameIdentifiers":[]},{"name":"Shamir, Dror","nameType":"Personal","givenName":"Dror","familyName":"Shamir","affiliation":[],"nameIdentifiers":[]},{"name":"Kornweitz, Haya","nameType":"Personal","givenName":"Haya","familyName":"Kornweitz","affiliation":[],"nameIdentifiers":[]},{"name":"Meyerstein, Dan","nameType":"Personal","givenName":"Dan","familyName":"Meyerstein","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"The reaction between the peroxide VO(η\u003csup\u003e2\u003c/sup\u003e-O\u003csub\u003e2\u003c/sub\u003e)(pyridine-2-carboxylate)·2H\u003csub\u003e2\u003c/sub\u003eO and Fe\u003csup\u003eII\u003c/sup\u003e\u003csub\u003eaq\u003c/sub\u003e is not a Fenton-like reaction"}],"publisher":"Figshare","container":{},"publicationYear":2016,"subjects":[{"subject":"Biophysics"},{"subject":"Biochemistry"},{"subject":"29999 Physical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Physical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Physical sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Medicine"},{"subject":"Physiology"},{"subject":"FOS: Biological sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Biological sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"59999 Environmental Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Earth and related environmental sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Earth and related environmental sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"39999 Chemical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Chemical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Chemical sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"19999 Mathematical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Mathematics","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Mathematics","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Cancer"},{"subject":"Computational Biology"}],"contributors":[],"dates":[{"date":"2016-04-19","dateType":"Created"},{"date":"2016-05-12","dateType":"Updated"},{"date":"2016","dateType":"Issued"}],"language":null,"types":{"ris":"GEN","bibtex":"misc","citeproc":"article","schemaOrg":"Collection","resourceType":"Collection","resourceTypeGeneral":"Collection"},"relatedIdentifiers":[],"relatedItems":[],"sizes":[],"formats":[],"version":null,"rightsList":[{"rights":"CC-BY","rightsUri":"http://creativecommons.org/licenses/by/3.0/us"}],"descriptions":[{"description":"The reduction of VO(η\u003csup\u003e2\u003c/sup\u003e-O\u003csub\u003e2\u003c/sub\u003e)(pyridine-2-carboxylate) by Fe(H\u003csub\u003e2\u003c/sub\u003eO)\u003csub\u003e6\u003c/sub\u003e\u003csup\u003e2+\u003c/sup\u003e proceeds via formation of the transient complex (pyridine-2-carboxylate)(O)V\u003csup\u003eV\u003c/sup\u003e(μ-η\u003csup\u003e2 \u003c/sup\u003e: η\u003csup\u003e2\u003c/sup\u003e-O\u003csub\u003e2\u003c/sub\u003e)Fe\u003csup\u003eII\u003c/sup\u003e(H\u003csub\u003e2\u003c/sub\u003eO)\u003csub\u003e3\u003c/sub\u003e\u003csup\u003e2+\u003c/sup\u003e that is transformed via intramolecular electron transfer into (pyridine-2-carboxylate)(O)V\u003csup\u003eIV\u003c/sup\u003e(μ-η\u003csup\u003e2 \u003c/sup\u003e: η\u003csup\u003e2\u003c/sup\u003e-O\u003csub\u003e2\u003c/sub\u003e)Fe\u003csup\u003eIII\u003c/sup\u003e(H\u003csub\u003e2\u003c/sub\u003eO)\u003csub\u003e3\u003c/sub\u003e\u003csup\u003e2+\u003c/sup\u003e. The latter transient reacts with another Fe(H\u003csub\u003e2\u003c/sub\u003eO)\u003csub\u003e6\u003c/sub\u003e\u003csup\u003e2+\u003c/sup\u003e to yield 2Fe(H\u003csub\u003e2\u003c/sub\u003eO)\u003csub\u003e6\u003c/sub\u003e\u003csup\u003e3+\u003c/sup\u003e + V\u003csup\u003eV\u003c/sup\u003eO(OH)(pyridine-2-carboxylate)\u003csup\u003e+\u003c/sup\u003e. These results point out that: (1) V\u003csup\u003eV\u003c/sup\u003e does not activate the η\u003csup\u003e2\u003c/sup\u003e bound peroxide toward the Fenton-like reaction. In this aspect, V\u003csup\u003eV\u003c/sup\u003e differs from Fe\u003csup\u003eIII\u003c/sup\u003e in (H\u003csub\u003e2\u003c/sub\u003eO)\u003csub\u003e5\u003c/sub\u003eFe–OOH\u003csup\u003e2+\u003c/sup\u003e and (2) transients of the type L\u003csub\u003em\u003c/sub\u003eM\u003csup\u003en\u003c/sup\u003e(μ-η\u003csup\u003e2 \u003c/sup\u003e: η\u003csup\u003e2\u003c/sup\u003e-O\u003csub\u003e2\u003c/sub\u003e)M′L″\u003csub\u003el\u003c/sub\u003e have to be considered in the reductions of complexes of η\u003csup\u003e2\u003c/sup\u003e-bound peroxides.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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