{"data":{"id":"10.6084/m9.figshare.c.2866801.v2","type":"dois","attributes":{"doi":"10.6084/m9.figshare.c.2866801.v2","prefix":"10.6084","suffix":"m9.figshare.c.2866801.v2","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Barman, Nikita","nameType":"Personal","givenName":"Nikita","familyName":"Barman","affiliation":[],"nameIdentifiers":[]},{"name":"Saikat Banerjee","affiliation":[],"nameIdentifiers":[]},{"name":"Brandão, Paula","nameType":"Personal","givenName":"Paula","familyName":"Brandão","affiliation":[],"nameIdentifiers":[]},{"name":"Bauzá, Antonio","nameType":"Personal","givenName":"Antonio","familyName":"Bauzá","affiliation":[],"nameIdentifiers":[]},{"name":"Frontera, Antonio","nameType":"Personal","givenName":"Antonio","familyName":"Frontera","affiliation":[],"nameIdentifiers":[]},{"name":"Saha, Amrita","nameType":"Personal","givenName":"Amrita","familyName":"Saha","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Anion-dependent structural diversity of cadmium(II) complexes: synthesis, crystal structures, luminescence properties, and unusual C-H/σ supramolecular interactions involving σ-aromatic M\u003csub\u003e2\u003c/sub\u003eX\u003csub\u003e2\u003c/sub\u003e cores"}],"publisher":"Figshare","container":{},"publicationYear":2016,"subjects":[{"subject":"Biophysics"},{"subject":"Biochemistry"},{"subject":"29999 Physical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Physical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Physical sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Medicine"},{"subject":"Biotechnology"},{"subject":"39999 Chemical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Chemical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Chemical sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Marine Biology"},{"subject":"Inorganic Chemistry"}],"contributors":[],"dates":[{"date":"2016-04-20","dateType":"Created"},{"date":"2016-05-28","dateType":"Updated"},{"date":"2016","dateType":"Issued"}],"language":null,"types":{"ris":"GEN","bibtex":"misc","citeproc":"article","schemaOrg":"Collection","resourceType":"Collection","resourceTypeGeneral":"Collection"},"relatedIdentifiers":[{"relationType":"IsSupplementTo","relatedIdentifier":"10.1080/00958972.2016.1173205","relatedIdentifierType":"DOI"},{"relationType":"IsIdenticalTo","relatedIdentifier":"10.6084/m9.figshare.c.2866801","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":[],"formats":[],"version":null,"rightsList":[{"rights":"CC-BY","rightsUri":"http://creativecommons.org/licenses/by/3.0/us"}],"descriptions":[{"description":"Four complexes based on N,N′-bis(2-pyridylmethylene)-1,3-propanediamine (L) and different Cd(II) salts have been synthesized and characterized by single-crystal X-ray diffraction analysis. The complexes are [Cd\u003csub\u003e2\u003c/sub\u003e(L)\u003csub\u003e2\u003c/sub\u003e(μ-Cl)\u003csub\u003e2\u003c/sub\u003e](ClO\u003csub\u003e4\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003e (\u003cb\u003e1\u003c/b\u003e), [Cd\u003csub\u003e2\u003c/sub\u003e(L)\u003csub\u003e2\u003c/sub\u003e(μ-Br)\u003csub\u003e2\u003c/sub\u003e](ClO\u003csub\u003e4\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003e (\u003cb\u003e2\u003c/b\u003e), [Cd(L)I](ClO\u003csub\u003e4\u003c/sub\u003e) (\u003cb\u003e3\u003c/b\u003e), and [Cd(L)(NCS)\u003csub\u003e2\u003c/sub\u003e] (\u003cb\u003e4\u003c/b\u003e). L exhibits the same coordination mode in \u003cb\u003e1\u003c/b\u003e–\u003cb\u003e4\u003c/b\u003e. The radius of each anion plays a role in affecting the structures and luminescent intensities of the final products. CdCl\u003csub\u003e2\u003c/sub\u003e, CdBr\u003csub\u003e2\u003c/sub\u003e, and CdI\u003csub\u003e2\u003c/sub\u003e react with L to produce chloride or bromido-bridged binuclear complexes and mononuclear iodido complex, respectively, whereas an unusual mononuclear trigonal prismatic (TP) \u003cb\u003e4\u003c/b\u003e is obtained when thiocyanate was used as a coligand. Photoluminescence properties of all the complexes show that the trend of fluorescence intensity is \u003cb\u003e1\u003c/b\u003e \u0026gt; \u003cb\u003e4\u003c/b\u003e \u0026gt; \u003cb\u003e2\u003c/b\u003e \u0026gt; \u003cb\u003e3\u003c/b\u003e. All four complexes exhibit different supramolecular interactions such as C–H/σ, \u003ci\u003eπ\u003c/i\u003e–\u003ci\u003eπ\u003c/i\u003e, and C–H/π and hydrogen bonding interactions. The experimental findings are complemented by density functional theory (DFT) calculations.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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