{"data":{"id":"10.6084/m9.figshare.c.2866801.v1","type":"dois","attributes":{"doi":"10.6084/m9.figshare.c.2866801.v1","prefix":"10.6084","suffix":"m9.figshare.c.2866801.v1","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Barman, Nikita","nameType":"Personal","givenName":"Nikita","familyName":"Barman","affiliation":[],"nameIdentifiers":[]},{"name":"Saikat Banerjee","affiliation":[],"nameIdentifiers":[]},{"name":"Brandão, Paula","nameType":"Personal","givenName":"Paula","familyName":"Brandão","affiliation":[],"nameIdentifiers":[]},{"name":"Bauzá, Antonio","nameType":"Personal","givenName":"Antonio","familyName":"Bauzá","affiliation":[],"nameIdentifiers":[]},{"name":"Frontera, Antonio","nameType":"Personal","givenName":"Antonio","familyName":"Frontera","affiliation":[],"nameIdentifiers":[]},{"name":"Saha, Amrita","nameType":"Personal","givenName":"Amrita","familyName":"Saha","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Anion dependent structural diversity of cadmium(II) complexes: Synthesis, crystal structures, luminescence properties and unusual C-H/σ supramolecular interactions involving σ-aromatic M\u003csub\u003e2\u003c/sub\u003eX\u003csub\u003e2\u003c/sub\u003e cores"}],"publisher":"Figshare","container":{},"publicationYear":2016,"subjects":[{"subject":"Biophysics"},{"subject":"Biochemistry"},{"subject":"29999 Physical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Physical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Physical sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Medicine"},{"subject":"Biotechnology"},{"subject":"39999 Chemical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Chemical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Chemical sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Marine Biology"}],"contributors":[],"dates":[{"date":"2016-04-04","dateType":"Created"},{"date":"2016-04-04","dateType":"Updated"},{"date":"2016","dateType":"Issued"}],"language":null,"types":{"ris":"GEN","bibtex":"misc","citeproc":"article","schemaOrg":"Collection","resourceType":"Collection","resourceTypeGeneral":"Collection"},"relatedIdentifiers":[{"relationType":"IsSupplementTo","relatedIdentifier":"10.1080/00958972.2016.1173205","relatedIdentifierType":"DOI"},{"relationType":"IsPreviousVersionOf","relatedIdentifier":"10.6084/m9.figshare.c.2866801","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":[],"formats":[],"version":null,"rightsList":[{"rights":"CC-BY","rightsUri":"http://creativecommons.org/licenses/by/3.0/us"}],"descriptions":[{"description":"Four complexes based on N,N’-bis(2-pyridylmethylene)-1,3-propanediamine (L) and different Cd(II) salts have been synthesized and characterized by single crystal X-ray diffraction analysis. The complexes are [Cd\u003csub\u003e2\u003c/sub\u003e(L)\u003csub\u003e2\u003c/sub\u003e(μ-Cl)\u003csub\u003e2\u003c/sub\u003e](ClO\u003csub\u003e4\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003e (\u003cb\u003e1\u003c/b\u003e), [Cd\u003csub\u003e2\u003c/sub\u003e(L)\u003csub\u003e2\u003c/sub\u003e(μ-Br)\u003csub\u003e2\u003c/sub\u003e](ClO\u003csub\u003e4\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003e (\u003cb\u003e2\u003c/b\u003e), [Cd(L)I](ClO\u003csub\u003e4\u003c/sub\u003e) (\u003cb\u003e3\u003c/b\u003e) and [Cd(L)(NCS)\u003csub\u003e2\u003c/sub\u003e] (\u003cb\u003e4\u003c/b\u003e). L exhibits the same coordination mode in \u003cb\u003e1\u003c/b\u003e-\u003cb\u003e4\u003c/b\u003e. The radius of each anion plays a role in affecting the structures and luminescent intensities of the final products. CdCl\u003csub\u003e2\u003c/sub\u003e, CdBr\u003csub\u003e2\u003c/sub\u003e and CdI\u003csub\u003e2\u003c/sub\u003e react with L to produce chloride or bromido bridged binuclear complexes and mononuclear iodido complex, respectively, whereas an unusual mononuclear trigonal prismatic \u003cb\u003e4\u003c/b\u003e is obtained when thiocyanate was used as a coligand. Photoluminescence properties of all the complexes show that the trend of fluorescence intensity is \u003cb\u003e1\u003c/b\u003e\u0026gt;\u003cb\u003e4\u003c/b\u003e\u0026gt;\u003cb\u003e2\u003c/b\u003e\u0026gt;\u003cb\u003e3\u003c/b\u003e. All four complexes exhibit different supramolecular interactions such as C–H/σ, π–π and C–H/π and hydrogen bonding interactions. The experimental findings are complemented by density functional theory (DFT) calculations.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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