{"data":{"id":"10.6084/m9.figshare.c.2860366","type":"dois","attributes":{"doi":"10.6084/m9.figshare.c.2860366","prefix":"10.6084","suffix":"m9.figshare.c.2860366","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"K. Ramalingam","affiliation":[],"nameIdentifiers":[]},{"name":"A. Ilakkiya","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Thiuram disulfide intercalated hybrid materials of layered lead and cadmium iodides"}],"publisher":"Figshare","container":{},"publicationYear":2016,"subjects":[{"subject":"Biophysics"},{"subject":"Biochemistry"},{"subject":"29999 Physical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Physical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Physical sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Medicine"},{"subject":"Physiology"},{"subject":"FOS: Biological sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Biological sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"39999 Chemical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Chemical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Chemical sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Ecology"},{"subject":"69999 Biological Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"Cancer"}],"contributors":[],"dates":[{"date":"2016-03-23","dateType":"Created"},{"date":"2016-04-27","dateType":"Updated"},{"date":"2016","dateType":"Issued"}],"language":null,"types":{"ris":"GEN","bibtex":"misc","citeproc":"article","schemaOrg":"Collection","resourceType":"Collection","resourceTypeGeneral":"Collection"},"relatedIdentifiers":[],"relatedItems":[],"sizes":[],"formats":[],"version":null,"rightsList":[{"rights":"CC-BY","rightsUri":"http://creativecommons.org/licenses/by/3.0/us"}],"descriptions":[{"description":"Thiuram disulfide intercalates of lead(II) and cadmium(II) were prepared by the reaction of binary layered metal iodides with five dithiocarbamates in air. The intercalates were characterized by elemental analysis, Powder X-ray diffraction (XRD), infrared (IR), ultraviolet–visible spectroscopy, diffuse reflectance spectroscopy, scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy, high-resolution transmission electron microscopy (HRTEM), and atomic force microscopy (AFM) techniques. IR showed increased contribution of the thioureide bond and the presence of weak disulfide stretching frequency. Powder XRD showed the characteristic intermediate 2θ signal confirming the intercalation. Powder XRD clearly differentiated intercalates from the iodinated product of dithiocarbamate. As the bulkiness of substituents on disulfide increased, “d” also increased. The higher thermal stability associated with intercalates clearly suggests a strong ionic interaction and a difficult de-intercalation. SEM images of lead intercalates indicated crystalline nature. The intercalates appeared as rods or spheres. The diallyl-intercalate, [PbI\u003csub\u003e2\u003c/sub\u003e](H\u003csub\u003e5\u003c/sub\u003eC\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eNCSS-SSCN(C\u003csub\u003e3\u003c/sub\u003eH\u003csub\u003e5\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003e (where (H\u003csub\u003e5\u003c/sub\u003eC\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eNCSS-SSCN(C\u003csub\u003e3\u003c/sub\u003eH\u003csub\u003e5\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003e is diallylthiuram disulfide), shows “net like structures.” Intercalation of oxidized dithiocarbamates in the “galleries” of layered PbI\u003csub\u003e2\u003c/sub\u003e/CdI\u003csub\u003e2\u003c/sub\u003e is observed. HRTEM and AFM analysis of intercalates showed the particles to be nano-rods.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"PD94bWwgdmVyc2lvbj0iMS4wIiBlbmNvZGluZz0iVVRGLTgiPz4KPHJlc291cmNlIHhtbG5zOnhzaT0iaHR0cDovL3d3dy53My5vcmcvMjAwMS9YTUxTY2hlbWEtaW5zdGFuY2UiIHhtbG5zPSJodHRwOi8vZGF0YWNpdGUub3JnL3NjaGVtYS9rZXJuZWwtNCIgeHNpOnNjaGVtYUxvY2F0aW9uPSJodHRwOi8vZGF0YWNpdGUub3JnL3NjaGVtYS9rZXJuZWwtNCBodHRwOi8vc2NoZW1hLmRhdGFjaXRlLm9yZy9tZXRhL2tlcm5lbC00L21ldGFkYXRhLnhzZCI+CiAgPGlkZW50aWZpZXIgaWRlbnRpZmllclR5cGU9IkRPSSI+MTAuNjA4NC9NOS5GSUdTSEFSRS5DLjI4NjAzNjY8L2lkZW50aWZpZXI+CiAgPGNyZWF0b3JzPgogICAgPGNyZWF0b3I+CiAgICAgIDxjcmVhdG9yTmFtZT5LLiBSYW1hbGluZ2FtPC9jcmVhdG9yTmFtZT4KICAgIDwvY3JlYXRvcj4KICAgIDxjcmVhdG9yPgogICAgICA8Y3JlYXRvck5hbWU+QS4gSWxha2tpeWE8L2NyZWF0b3JOYW1lPgogICAgPC9jcmVhdG9yPgogIDwvY3JlYXRvcnM+CiAgPHRpdGxlcz4KICAgIDx0aXRsZT5UaGl1cmFtIGRpc3VsZmlkZSBpbnRlcmNhbGF0ZWQgaHlicmlkIG1hdGVyaWFscyBvZiBsYXllcmVkIGxlYWQgYW5kIGNhZG1pdW0gaW9kaWRlczwvdGl0bGU+CiAgPC90aXRsZXM+CiAgPHB1Ymxpc2hlcj5GaWdzaGFyZTwvcHVibGlzaGVyPgogIDxwdWJsaWNhdGlvblllYXI+MjAxNjwvcHVibGljYXRpb25ZZWFyPgogIDxyZXNvdXJjZVR5cGUgcmVzb3VyY2VUeXBlR2VuZXJhbD0iQ29sbGVjdGlvbiI+Q29sbGVjdGlvbjwvcmVzb3VyY2VUeXBlPgogIDxzdWJqZWN0cz4KICAgIDxzdWJqZWN0PkJpb3BoeXNpY3M8L3N1YmplY3Q+CiAgICA8c3ViamVjdD5CaW9jaGVtaXN0cnk8L3N1YmplY3Q+CiAgICA8c3ViamVjdCBzdWJqZWN0U2NoZW1lPSJGT1IiPjI5OTk5IFBoeXNpY2FsIFNjaWVuY2VzIG5vdCBlbHNld2hlcmUgY2xhc3NpZmllZDwvc3ViamVjdD4KICAgIDxzdWJqZWN0IHN1YmplY3RTY2hlbWU9IkZpZWxkcyBvZiBTY2llbmNlIGFuZCBUZWNobm9sb2d5IChGT1MpIiBzY2hlbWVVUkk9Imh0dHA6Ly93d3cub2VjZC5vcmcvc2NpZW5jZS9pbm5vLzM4MjM1MTQ3LnBkZiI+Rk9TOiBQaHlzaWNhbCBzY2llbmNlczwvc3ViamVjdD4KICAgIDxzdWJqZWN0IHN1YmplY3RTY2hlbWU9IkZpZWxkcyBvZiBTY2llbmNlIGFuZCBUZWNobm9sb2d5IChGT1MpIj5GT1M6IFBoeXNpY2FsIHNjaWVuY2VzPC9zdWJqZWN0PgogICAgPHN1YmplY3Q+TWVkaWNpbmU8L3N1YmplY3Q+CiAgICA8c3ViamVjdD5QaHlzaW9sb2d5PC9zdWJqZWN0PgogICAgPHN1YmplY3Qgc3ViamVjdFNjaGVtZT0iRmllbGRzIG9mIFNjaWVuY2UgYW5kIFRlY2hub2xvZ3kgKEZPUykiIHNjaGVtZVVSST0iaHR0cDovL3d3dy5vZWNkLm9yZy9zY2llbmNlL2lubm8vMzgyMzUxNDcucGRmIj5GT1M6IEJpb2xvZ2ljYWwgc2NpZW5jZXM8L3N1YmplY3Q+CiAgICA8c3ViamVjdCBzdWJqZWN0U2NoZW1lPSJGaWVsZHMgb2YgU2NpZW5jZSBhbmQgVGVjaG5vbG9neSAoRk9TKSI+Rk9TOiBCaW9sb2dpY2FsIHNjaWVuY2VzPC9zdWJqZWN0PgogICAgPHN1YmplY3Qgc3ViamVjdFNjaGVtZT0iRk9SIj4zOTk5OSBDaGVtaWNhbCBTY2llbmNlcyBub3QgZWxzZXdoZXJlIGNsYXNzaWZpZWQ8L3N1YmplY3Q+CiAgICA8c3ViamVjdCBzdWJqZWN0U2NoZW1lPSJGaWVsZHMgb2YgU2NpZW5jZSBhbmQgVGVjaG5vbG9neSAoRk9TKSIgc2NoZW1lVVJJPSJodHRwOi8vd3d3Lm9lY2Qub3JnL3NjaWVuY2UvaW5uby8zODIzNTE0Ny5wZGYiPkZPUzogQ2hlbWljYWwgc2NpZW5jZXM8L3N1YmplY3Q+CiAgICA8c3ViamVjdCBzdWJqZWN0U2NoZW1lPSJGaWVsZHMgb2YgU2NpZW5jZSBhbmQgVGVjaG5vbG9neSAoRk9TKSI+Rk9TOiBDaGVtaWNhbCBzY2llbmNlczwvc3ViamVjdD4KICAgIDxzdWJqZWN0PkVjb2xvZ3k8L3N1YmplY3Q+CiAgICA8c3ViamVjdCBzdWJqZWN0U2NoZW1lPSJGT1IiPjY5OTk5IEJpb2xvZ2ljYWwgU2NpZW5jZXMgbm90IGVsc2V3aGVyZSBjbGFzc2lmaWVkPC9zdWJqZWN0PgogICAgPHN1YmplY3Q+Q2FuY2VyPC9zdWJqZWN0PgogIDwvc3ViamVjdHM+CiAgPGRhdGVzPgogICAgPGRhdGUgZGF0ZVR5cGU9IkNyZWF0ZWQiPjIwMTYtMDMtMjM8L2RhdGU+CiAgICA8ZGF0ZSBkYXRlVHlwZT0iVXBkYXRlZCI+MjAxNi0wNC0yNzwvZGF0ZT4KICAgIDxkYXRlIGRhdGVUeXBlPSJJc3N1ZWQiPjIwMTY8L2RhdGU+CiAgPC9kYXRlcz4KICA8c2l6ZXMvPgogIDxmb3JtYXRzLz4KICA8dmVyc2lvbi8+CiAgPHJpZ2h0c0xpc3Q+CiAgICA8cmlnaHRzIHJpZ2h0c1VSST0iaHR0cDovL2NyZWF0aXZlY29tbW9ucy5vcmcvbGljZW5zZXMvYnkvMy4wL3VzIj5DQy1CWTwvcmlnaHRzPgogIDwvcmlnaHRzTGlzdD4KICA8ZGVzY3JpcHRpb25zPgogICAgPGRlc2NyaXB0aW9uIGRlc2NyaXB0aW9uVHlwZT0iQWJzdHJhY3QiPlRoaXVyYW0gZGlzdWxmaWRlIGludGVyY2FsYXRlcyBvZiBsZWFkKElJKSBhbmQgY2FkbWl1bShJSSkgd2VyZSBwcmVwYXJlZCBieSB0aGUgcmVhY3Rpb24gb2YgYmluYXJ5IGxheWVyZWQgbWV0YWwgaW9kaWRlcyB3aXRoIGZpdmUgZGl0aGlvY2FyYmFtYXRlcyBpbiBhaXIuIFRoZSBpbnRlcmNhbGF0ZXMgd2VyZSBjaGFyYWN0ZXJpemVkIGJ5IGVsZW1lbnRhbCBhbmFseXNpcywgUG93ZGVyIFgtcmF5IGRpZmZyYWN0aW9uIChYUkQpLCBpbmZyYXJlZCAoSVIpLCB1bHRyYXZpb2xldOKAk3Zpc2libGUgc3BlY3Ryb3Njb3B5LCBkaWZmdXNlIHJlZmxlY3RhbmNlIHNwZWN0cm9zY29weSwgc2Nhbm5pbmcgZWxlY3Ryb24gbWljcm9zY29weSAoU0VNKSwgZW5lcmd5IGRpc3BlcnNpdmUgWC1yYXkgc3BlY3Ryb3Njb3B5LCBoaWdoLXJlc29sdXRpb24gdHJhbnNtaXNzaW9uIGVsZWN0cm9uIG1pY3Jvc2NvcHkgKEhSVEVNKSwgYW5kIGF0b21pYyBmb3JjZSBtaWNyb3Njb3B5IChBRk0pIHRlY2huaXF1ZXMuIElSIHNob3dlZCBpbmNyZWFzZWQgY29udHJpYnV0aW9uIG9mIHRoZSB0aGlvdXJlaWRlIGJvbmQgYW5kIHRoZSBwcmVzZW5jZSBvZiB3ZWFrIGRpc3VsZmlkZSBzdHJldGNoaW5nIGZyZXF1ZW5jeS4gUG93ZGVyIFhSRCBzaG93ZWQgdGhlIGNoYXJhY3RlcmlzdGljIGludGVybWVkaWF0ZSAyzrggc2lnbmFsIGNvbmZpcm1pbmcgdGhlIGludGVyY2FsYXRpb24uIFBvd2RlciBYUkQgY2xlYXJseSBkaWZmZXJlbnRpYXRlZCBpbnRlcmNhbGF0ZXMgZnJvbSB0aGUgaW9kaW5hdGVkIHByb2R1Y3Qgb2YgZGl0aGlvY2FyYmFtYXRlLiBBcyB0aGUgYnVsa2luZXNzIG9mIHN1YnN0aXR1ZW50cyBvbiBkaXN1bGZpZGUgaW5jcmVhc2VkLCDigJxk4oCdIGFsc28gaW5jcmVhc2VkLiBUaGUgaGlnaGVyIHRoZXJtYWwgc3RhYmlsaXR5IGFzc29jaWF0ZWQgd2l0aCBpbnRlcmNhbGF0ZXMgY2xlYXJseSBzdWdnZXN0cyBhIHN0cm9uZyBpb25pYyBpbnRlcmFjdGlvbiBhbmQgYSBkaWZmaWN1bHQgZGUtaW50ZXJjYWxhdGlvbi4gU0VNIGltYWdlcyBvZiBsZWFkIGludGVyY2FsYXRlcyBpbmRpY2F0ZWQgY3J5c3RhbGxpbmUgbmF0dXJlLiBUaGUgaW50ZXJjYWxhdGVzIGFwcGVhcmVkIGFzIHJvZHMgb3Igc3BoZXJlcy4gVGhlIGRpYWxseWwtaW50ZXJjYWxhdGUsIFtQYkkmbHQ7c3ViJmd0OzImbHQ7L3N1YiZndDtdKEgmbHQ7c3ViJmd0OzUmbHQ7L3N1YiZndDtDJmx0O3N1YiZndDszJmx0Oy9zdWImZ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