{"data":{"id":"10.6084/m9.figshare.c.2857216","type":"dois","attributes":{"doi":"10.6084/m9.figshare.c.2857216","prefix":"10.6084","suffix":"m9.figshare.c.2857216","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Sayın, Elvan","nameType":"Personal","givenName":"Elvan","familyName":"Sayın","affiliation":[],"nameIdentifiers":[]},{"name":"Güneş Süheyla Kürkçüoğlu","affiliation":[],"nameIdentifiers":[]},{"name":"Yeşilel, Okan Zafer","nameType":"Personal","givenName":"Okan Zafer","familyName":"Yeşilel","affiliation":[],"nameIdentifiers":[]},{"name":"Taş, Murat","nameType":"Personal","givenName":"Murat","familyName":"Taş","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Cyanide-bridged manganese(II) and chloride-bridged copper(II) complexes with 2-pyridineethanol: synthesis, structural characterization and C-H⋯M interactions"}],"publisher":"Figshare","container":{},"publicationYear":2016,"subjects":[{"subject":"Biophysics"},{"subject":"Biochemistry"},{"subject":"29999 Physical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Physical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Physical sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Cell Biology"},{"subject":"Physiology"},{"subject":"FOS: Biological sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Biological sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"39999 Chemical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Chemical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Chemical sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Mental Health"},{"subject":"Virology"},{"subject":"Computational Biology"}],"contributors":[],"dates":[{"date":"2016-03-16","dateType":"Created"},{"date":"2016-05-28","dateType":"Updated"},{"date":"2016","dateType":"Issued"}],"language":null,"types":{"ris":"GEN","bibtex":"misc","citeproc":"article","schemaOrg":"Collection","resourceType":"Collection","resourceTypeGeneral":"Collection"},"relatedIdentifiers":[{"relationType":"IsSupplementTo","relatedIdentifier":"10.1080/00958972.2016.1166218","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":[],"formats":[],"version":null,"rightsList":[{"rights":"CC-BY","rightsUri":"http://creativecommons.org/licenses/by/3.0/us"}],"descriptions":[{"description":"[Mn(hepH)\u003csub\u003e2\u003c/sub\u003eNi(μ-CN)\u003csub\u003e2\u003c/sub\u003e(CN)\u003csub\u003e2\u003c/sub\u003e]\u003csub\u003en\u003c/sub\u003e (\u003cb\u003e1\u003c/b\u003e) and [Cu\u003csub\u003e2\u003c/sub\u003e(μ-Cl)\u003csub\u003e2\u003c/sub\u003e(μ-hep)\u003csub\u003e2\u003c/sub\u003e]\u003csub\u003en\u003c/sub\u003e (\u003cb\u003e2\u003c/b\u003e) (2-pyridineethanol abbreviated to hepH) have been synthesized and characterized by FT-IR and Raman spectroscopies, elemental analyses, and single-crystal X-ray diffraction. X-ray single-crystal structure analysis reveals that the structures of \u003cb\u003e1\u003c/b\u003e and \u003cb\u003e2\u003c/b\u003e consist of 1-D infinite chains. The coordination environment of Mn(II) was identified as distorted octahedral, whereas Ni(II) has a square planar geometry in \u003cb\u003e1\u003c/b\u003e. Each Cu(II) in \u003cb\u003e2\u003c/b\u003e adopts a distorted square pyramidal geometry in which the basal plane is constructed by oxygen and nitrogen atoms from hep and a bridging chloride ligand, respectively, and the apical position is occupied by the other chloride. The 1-D chains in \u003cb\u003e1\u003c/b\u003e and \u003cb\u003e2\u003c/b\u003e are extended into a 2-D supramolecular network by O−H⋯N and weak C−H⋯Cl hydrogen bonds, respectively. Adjacent 2-D layers are further connected by C−H⋯M interactions resulting in the formation of 3-D supramolecular networks. The most remarkable properties of complexes are the presence of close C–H⋯M interactions with distance values of 2.58 and 2.93 Å between H⋯Ni and H⋯Cu, respectively. The H⋯Ni interaction distance is shorter than the corresponding values of other tetracyanonickelate(II) complexes.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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