{"data":{"id":"10.6084/m9.figshare.c.2854474.v1","type":"dois","attributes":{"doi":"10.6084/m9.figshare.c.2854474.v1","prefix":"10.6084","suffix":"m9.figshare.c.2854474.v1","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Allenbaugh, Rachel J.","nameType":"Personal","givenName":"Rachel J.","familyName":"Allenbaugh","affiliation":[],"nameIdentifiers":[]},{"name":"Zachary, Jonathon R.","nameType":"Personal","givenName":"Jonathon R.","familyName":"Zachary","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Kinetic analysis of the mechanochemical syntheses of dialkyl 2,2′-bipyridyl-4,4′-dicarboxylate complexes of palladium"}],"publisher":"Figshare","container":{},"publicationYear":2016,"subjects":[{"subject":"Biophysics"},{"subject":"Biochemistry"},{"subject":"29999 Physical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Physical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Physical sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Microbiology"},{"subject":"FOS: Biological sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Biological sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Cell Biology"},{"subject":"Biotechnology"},{"subject":"39999 Chemical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Chemical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Chemical sciences","subjectScheme":"Fields of Science and Technology (FOS)"}],"contributors":[],"dates":[{"date":"2016-03-10","dateType":"Created"},{"date":"2016-05-30","dateType":"Updated"},{"date":"2016","dateType":"Issued"}],"language":null,"types":{"ris":"GEN","bibtex":"misc","citeproc":"article","schemaOrg":"Collection","resourceType":"Collection","resourceTypeGeneral":"Collection"},"relatedIdentifiers":[{"relationType":"IsSupplementTo","relatedIdentifier":"10.1080/02678292.2016.1157633","relatedIdentifierType":"DOI"},{"relationType":"IsIdenticalTo","relatedIdentifier":"10.6084/m9.figshare.c.2854474","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":[],"formats":[],"version":null,"rightsList":[{"rights":"CC-BY","rightsUri":"http://creativecommons.org/licenses/by/3.0/us"}],"descriptions":[{"description":"Kinetic models for the ‘molecular’ mechanochemical syntheses of α- and β-dialkyl 2,2′-bipyridyl-4,4′-dicarboxylate complexes of palladium (PdL\u003ci\u003e\u003csup\u003en\u003c/sup\u003e\u003c/i\u003eI\u003csub\u003e2\u003c/sub\u003e, where \u003ci\u003en\u003c/i\u003e specifies the number of carbons in the alkyl chain of the ligand and α and β refer to the substitution of the alkyl chain) are explored. The Johnson–Mehl–Avrami–Yerofeev–Kolmogrov (JMAYK) model was determined to best fit the data obtained via \u003csup\u003e1\u003c/sup\u003eH NMR spectroscopic analysis of the reaction mixtures over time. A rate enhancement, and corresponding increase in the Avrami exponent, was observed when the complex formed was liquid crystalline at milling temperatures.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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