{"data":{"id":"10.6084/m9.figshare.c.2853580.v1","type":"dois","attributes":{"doi":"10.6084/m9.figshare.c.2853580.v1","prefix":"10.6084","suffix":"m9.figshare.c.2853580.v1","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Bakir, Mohammed","nameType":"Personal","givenName":"Mohammed","familyName":"Bakir","affiliation":[],"nameIdentifiers":[]},{"name":"Conry, Rebecca","nameType":"Personal","givenName":"Rebecca","familyName":"Conry","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Synthesis, spectroscopic and X-ray crystallographic properties of manganese compounds of keto- and enol-coordinated di-2-pyridyl ketone benzoyl hydrazone (dpkbh). Reactions of [Mn(CO)\u003csub\u003e5\u003c/sub\u003eBr] with dpkbh"}],"publisher":"Figshare","container":{},"publicationYear":2016,"subjects":[{"subject":"Biochemistry"},{"subject":"29999 Physical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Physical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Physical sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Molecular Biology"},{"subject":"59999 Environmental Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Earth and related environmental sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Earth and related environmental sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"39999 Chemical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Chemical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Chemical sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Science Policy"},{"subject":"Developmental Biology"}],"contributors":[],"dates":[{"date":"2016-03-08","dateType":"Created"},{"date":"2016-05-28","dateType":"Updated"},{"date":"2016","dateType":"Issued"}],"language":null,"types":{"ris":"GEN","bibtex":"misc","citeproc":"article","schemaOrg":"Collection","resourceType":"Collection","resourceTypeGeneral":"Collection"},"relatedIdentifiers":[{"relationType":"IsSupplementTo","relatedIdentifier":"10.1080/00958972.2016.1162789","relatedIdentifierType":"DOI"},{"relationType":"IsIdenticalTo","relatedIdentifier":"10.6084/m9.figshare.c.2853580","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":[],"formats":[],"version":null,"rightsList":[{"rights":"CC-BY","rightsUri":"http://creativecommons.org/licenses/by/3.0/us"}],"descriptions":[{"description":"Reactions between [Mn(CO)\u003csub\u003e5\u003c/sub\u003eBr] and dpkbh in low boiling solvents in air gave \u003ci\u003efac\u003c/i\u003e-[Mn\u003csup\u003eI\u003c/sup\u003e(CO)\u003csub\u003e3\u003c/sub\u003e(κ\u003csup\u003e2\u003c/sup\u003e-N\u003csub\u003epy\u003c/sub\u003e,N\u003csub\u003eim\u003c/sub\u003e-dpkbh)Br]·H\u003csub\u003e2\u003c/sub\u003eO, [Mn\u003csup\u003eII\u003c/sup\u003eBr\u003csub\u003e2\u003c/sub\u003e(κ\u003csup\u003e3\u003c/sup\u003e-N\u003csub\u003epy\u003c/sub\u003e,N\u003csub\u003eim\u003c/sub\u003e,O-dpkbh)], and [Mn\u003csup\u003eII\u003c/sup\u003e(κ\u003csup\u003e3\u003c/sup\u003e-N\u003csub\u003epy\u003c/sub\u003e,N\u003csub\u003eim\u003c/sub\u003e,O-dpkbh-H)\u003csub\u003e2\u003c/sub\u003e]·0.5H\u003csub\u003e2\u003c/sub\u003eO (N\u003csub\u003eim\u003c/sub\u003e = imine nitrogen and N\u003csub\u003epy\u003c/sub\u003e = pyridyl nitrogen). Crystallization of \u003ci\u003efac\u003c/i\u003e-[Mn\u003csup\u003eI\u003c/sup\u003e(CO)\u003csub\u003e3\u003c/sub\u003e(κ\u003csup\u003e2\u003c/sup\u003e-N\u003csub\u003epy\u003c/sub\u003e,N\u003csub\u003eim\u003c/sub\u003e-dpkbh)Br]·H\u003csub\u003e2\u003c/sub\u003eO from dmso or CH\u003csub\u003e3\u003c/sub\u003eCN produced dark red crystals of [Mn\u003csup\u003eII\u003c/sup\u003e(κ\u003csup\u003e3\u003c/sup\u003e-N\u003csub\u003epy\u003c/sub\u003e,N\u003csub\u003eim\u003c/sub\u003e,O-dpkbh-H)\u003csub\u003e2\u003c/sub\u003e]·nX (X = dmso, n = 1 and X = H\u003csub\u003e2\u003c/sub\u003eO, n = 0.22). This is in contrast to the reaction of [Re(CO)\u003csub\u003e5\u003c/sub\u003eCl] with dpkbh in refluxing toluene to form \u003ci\u003efac\u003c/i\u003e-[Re\u003csup\u003eI\u003c/sup\u003e(CO)\u003csub\u003e3\u003c/sub\u003e(κ\u003csup\u003e2\u003c/sup\u003e-,N\u003csub\u003epy\u003c/sub\u003e,N\u003csub\u003epy\u003c/sub\u003e-dpkbh)Cl] which can be crystallized from CH\u003csub\u003e3\u003c/sub\u003eCN, dmso or dmf to form \u003ci\u003efac\u003c/i\u003e-[Re\u003csup\u003eI\u003c/sup\u003e(CO)\u003csub\u003e3\u003c/sub\u003e(κ\u003csup\u003e2\u003c/sup\u003e-,N\u003csub\u003epy\u003c/sub\u003e,N\u003csub\u003epy\u003c/sub\u003e-dpkbh)Cl]·nX (X = CH\u003csub\u003e3\u003c/sub\u003eCN, n = 0 and solvate = dmso or dmf, n = 1). Infrared spectral measurements are consistent with keto coordination of dpkbh to Mn(I) in \u003ci\u003efac\u003c/i\u003e-[Mn\u003csup\u003eI\u003c/sup\u003e(CO)\u003csub\u003e3\u003c/sub\u003e(κ\u003csup\u003e2\u003c/sup\u003e-N\u003csub\u003epy\u003c/sub\u003e,N\u003csub\u003eim\u003c/sub\u003e-dpkbh)Br]·H\u003csub\u003e2\u003c/sub\u003eO and Mn(II) in [Mn\u003csup\u003eII\u003c/sup\u003eBr\u003csub\u003e2\u003c/sub\u003e(κ\u003csup\u003e3\u003c/sup\u003e-N\u003csub\u003epy\u003c/sub\u003e,N\u003csub\u003eim\u003c/sub\u003e,O-dpkbh)] plus enol coordination of the amide-deprotonated dpkbh, to the Mn(II) center in [Mn\u003csup\u003eII\u003c/sup\u003e(κ\u003csup\u003e3\u003c/sup\u003e-N\u003csub\u003epy\u003c/sub\u003e,N\u003csub\u003eim\u003c/sub\u003e,O-dpkbh-H)\u003csub\u003e2\u003c/sub\u003e]·0.5H\u003csub\u003e2\u003c/sub\u003eO. Electronic absorption spectral measurements in non-aqueous solvents indicate sensitivity of \u003ci\u003efac\u003c/i\u003e-[Mn\u003csup\u003eI\u003c/sup\u003e(CO)\u003csub\u003e3\u003c/sub\u003e(κ\u003csup\u003e2\u003c/sup\u003e-N\u003csub\u003epy\u003c/sub\u003e,N\u003csub\u003eim\u003c/sub\u003e-dpkbh)Br]·H\u003csub\u003e2\u003c/sub\u003eO and [Mn\u003csup\u003eII\u003c/sup\u003e(κ\u003csup\u003e3\u003c/sup\u003e-N\u003csub\u003epy\u003c/sub\u003e,N\u003csub\u003eim\u003c/sub\u003e,O-dpkbh-H)\u003csub\u003e2\u003c/sub\u003e]·0.5H\u003csub\u003e2\u003c/sub\u003eO to changes in their outer-shell environments. X-ray crystallographic analyses elucidated the identities of [Mn\u003csup\u003eII\u003c/sup\u003eBr\u003csub\u003e2\u003c/sub\u003e(κ\u003csup\u003e3\u003c/sup\u003e-N\u003csub\u003epy\u003c/sub\u003e,N\u003csub\u003eim\u003c/sub\u003e,O-dpkbh)] and [Mn\u003csup\u003eII\u003c/sup\u003e(κ\u003csup\u003e3\u003c/sup\u003e-N\u003csub\u003epy\u003c/sub\u003e,N\u003csub\u003eim\u003c/sub\u003e,O-dpkbh-H)\u003csub\u003e2\u003c/sub\u003e]·nX and divulged weaker coordination of [dpkbh] to Mn(II) in [Mn\u003csup\u003eII\u003c/sup\u003eBr\u003csub\u003e2\u003c/sub\u003e(κ\u003csup\u003e3\u003c/sup\u003e-N\u003csub\u003epy\u003c/sub\u003e,N\u003csub\u003eim\u003c/sub\u003e,O-dpkbh)] and stronger coordination of [dpkbh-H]\u003csup\u003e−\u003c/sup\u003e to Mn(II) in [Mn\u003csup\u003eII\u003c/sup\u003e(κ\u003csup\u003e3\u003c/sup\u003e-N\u003csub\u003epy\u003c/sub\u003e,N\u003csub\u003eim\u003c/sub\u003e,O-dpkbh-H)\u003csub\u003e2\u003c/sub\u003e]·0.22H\u003csub\u003e2\u003c/sub\u003eO. Low-temperature X-ray structural analyses were employed to account for the disorder in the structure of [Mn\u003csup\u003eII\u003c/sup\u003e(κ\u003csup\u003e3\u003c/sup\u003e-N\u003csub\u003epy\u003c/sub\u003e,N\u003csub\u003eim\u003c/sub\u003e,O-dpkbh-H)\u003csub\u003e2\u003c/sub\u003e] and the short NH bond distance observed in the structure of [Mn\u003csup\u003eII\u003c/sup\u003eBr\u003csub\u003e2\u003c/sub\u003e(κ\u003csup\u003e3\u003c/sup\u003e-N\u003csub\u003epy\u003c/sub\u003e,N\u003csub\u003eim\u003c/sub\u003e,O-dpkbh)]. A \u003ci\u003ePLATON\u003c/i\u003e Squeeze treatment was invoked to account for the fractional occupancy of lattice water in the structure of [Mn\u003csup\u003eII\u003c/sup\u003e(κ\u003csup\u003e3\u003c/sup\u003e-N\u003csub\u003epy\u003c/sub\u003e,N\u003csub\u003eim\u003c/sub\u003e,O-dpkbh-H)\u003csub\u003e2\u003c/sub\u003e].","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"<?xml version="1.0" encoding="UTF-8"?>
<resource xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns="http://datacite.org/schema/kernel-4" xsi:schemaLocation="http://datacite.org/schema/kernel-4 http://schema.datacite.org/meta/kernel-4/metadata.xsd">
  <identifier identifierType="DOI">10.6084/M9.FIGSHARE.C.2853580.V1</identifier>
  <creators>
    <creator>
      <creatorName nameType="Personal">Bakir, Mohammed</creatorName>
      <givenName>Mohammed</givenName>
      <familyName>Bakir</familyName>
    </creator>
    <creator>
      <creatorName nameType="Personal">Conry, Rebecca</creatorName>
      <givenName>Rebecca</givenName>
      <familyName>Conry</familyName>
    </creator>
  </creators>
  <titles>
    <title>Synthesis, spectroscopic and X-ray crystallographic properties of manganese compounds of keto- and enol-coordinated di-2-pyridyl ketone benzoyl hydrazone (dpkbh). Reactions of [Mn(CO)&lt;sub&gt;5&lt;/sub&gt;Br] with dpkbh</title>
  </titles>
  <publisher>Figshare</publisher>
  <publicationYear>2016</publicationYear>
  <resourceType resourceTypeGeneral="Collection">Collection</resourceType>
  <subjects>
    <subject>Biochemistry</subject>
    <subject subjectScheme="FOR">29999 Physical Sciences not elsewhere classified</subject>
    <subject subjectScheme="Fields of Science and Technology (FOS)" schemeURI="http://www.oecd.org/science/inno/38235147.pdf">FOS: Physical sciences</subject>
    <subject subjectScheme="Fields of Science and Technology (FOS)">FOS: Physical sciences</subject>
    <subject>Molecular Biology</subject>
    <subject subjectScheme="FOR">59999 Environmental Sciences not elsewhere classified</subject>
    <subject subjectScheme="Fields of Science and Technology (FOS)" schemeURI="http://www.oecd.org/science/inno/38235147.pdf">FOS: Earth and related environmental sciences</subject>
    <subject subjectScheme="Fields of Science and Technology (FOS)">FOS: Earth and related environmental sciences</subject>
    <subject subjectScheme="FOR">39999 Chemical Sciences not elsewhere classified</subject>
    <subject subjectScheme="Fields of Science and Technology (FOS)" schemeURI="http://www.oecd.org/science/inno/38235147.pdf">FOS: Chemical sciences</subject>
    <subject subjectScheme="Fields of Science and Technology (FOS)">FOS: Chemical sciences</subject>
    <subject>Science Policy</subject>
    <subject>Developmental Biology</subject>
  </subjects>
  <dates>
    <date dateType="Created">2016-03-08</date>
    <date dateType="Updated">2016-05-28</date>
    <date dateType="Issued">2016</date>
  </dates>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsSupplementTo">10.1080/00958972.2016.1162789</relatedIdentifier>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.6084/m9.figshare.c.2853580</relatedIdentifier>
  </relatedIdentifiers>
  <sizes/>
  <formats/>
  <version/>
  <rightsList>
    <rights rightsURI="http://creativecommons.org/licenses/by/3.0/us">CC-BY</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">Reactions between [Mn(CO)&lt;sub&gt;5&lt;/sub&gt;Br] and dpkbh in low boiling solvents in air gave &lt;i&gt;fac&lt;/i&gt;-[Mn&lt;sup&gt;I&lt;/sup&gt;(CO)&lt;sub&gt;3&lt;/sub&gt;(κ&lt;sup&gt;2&lt;/sup&gt;-N&lt;sub&gt;py&lt;/sub&gt;,N&lt;sub&gt;im&lt;/sub&gt;-dpkbh)Br]·H&lt;sub&gt;2&lt;/sub&gt;O, [Mn&lt;sup&gt;II&lt;/sup&gt;Br&lt;sub&gt;2&lt;/sub&gt;(κ&lt;sup&gt;3&lt;/sup&gt;-N&lt;sub&gt;py&lt;/sub&gt;,N&lt;sub&gt;im&lt;/sub&gt;,O-dpkbh)], and [Mn&lt;sup&gt;II&lt;/sup&gt;(κ&lt;sup&gt;3&lt;/sup&gt;-N&lt;sub&gt;py&lt;/sub&gt;,N&lt;sub&gt;im&lt;/sub&gt;,O-dpkbh-H)&lt;sub&gt;2&lt;/sub&gt;]·0.5H&lt;sub&gt;2&lt;/sub&gt;O (N&lt;sub&gt;im&lt;/sub&gt; = imine nitrogen and N&lt;sub&gt;py&lt;/sub&gt; = pyridyl nitrogen). Crystallization of &lt;i&gt;fac&lt;/i&gt;-[Mn&lt;sup&gt;I&lt;/sup&gt;(CO)&lt;sub&gt;3&lt;/sub&gt;(κ&lt;sup&gt;2&lt;/sup&gt;-N&lt;sub&gt;py&lt;/sub&gt;,N&lt;sub&gt;im&lt;/sub&gt;-dpkbh)Br]·H&lt;sub&gt;2&lt;/sub&gt;O from dmso or CH&lt;sub&gt;3&lt;/sub&gt;CN produced dark red crystals of [Mn&lt;sup&gt;II&lt;/sup&gt;(κ&lt;sup&gt;3&lt;/sup&gt;-N&lt;sub&gt;py&lt;/sub&gt;,N&lt;sub&gt;im&lt;/sub&gt;,O-dpkbh-H)&lt;sub&gt;2&lt;/sub&gt;]·nX (X = dmso, n = 1 and X = H&lt;sub&gt;2&lt;/sub&gt;O, n = 0.22). This is in contrast to the reaction of [Re(CO)&lt;sub&gt;5&lt;/sub&gt;Cl] with dpkbh in refluxing toluene to form &lt;i&gt;fac&lt;/i&gt;-[Re&lt;sup&gt;I&lt;/sup&gt;(CO)&lt;sub&gt;3&lt;/sub&gt;(κ&lt;sup&gt;2&lt;/sup&gt;-,N&lt;sub&gt;py&lt;/sub&gt;,N&lt;sub&gt;py&lt;/sub&gt;-dpkbh)Cl] which can be crystallized from CH&lt;sub&gt;3&lt;/sub&gt;CN, dmso or dmf to form &lt;i&gt;fac&lt;/i&gt;-[Re&lt;sup&gt;I&lt;/sup&gt;(CO)&lt;sub&gt;3&lt;/sub&gt;(κ&lt;sup&gt;2&lt;/sup&gt;-,N&lt;sub&gt;py&lt;/sub&gt;,N&lt;sub&gt;py&lt;/sub&gt;-dpkbh)Cl]·nX (X = CH&lt;sub&gt;3&lt;/sub&gt;CN, n = 0 and solvate = dmso or dmf, n = 1). Infrared spectral measurements are consistent with keto coordination of dpkbh to Mn(I) in &lt;i&gt;fac&lt;/i&gt;-[Mn&lt;sup&gt;I&lt;/sup&gt;(CO)&lt;sub&gt;3&lt;/sub&gt;(κ&lt;sup&gt;2&lt;/sup&gt;-N&lt;sub&gt;py&lt;/sub&gt;,N&lt;sub&gt;im&lt;/sub&gt;-dpkbh)Br]·H&lt;sub&gt;2&lt;/sub&gt;O and Mn(II) in [Mn&lt;sup&gt;II&lt;/sup&gt;Br&lt;sub&gt;2&lt;/sub&gt;(κ&lt;sup&gt;3&lt;/sup&gt;-N&lt;sub&gt;py&lt;/sub&gt;,N&lt;sub&gt;im&lt;/sub&gt;,O-dpkbh)] plus enol coordination of the amide-deprotonated dpkbh, to the Mn(II) center in [Mn&lt;sup&gt;II&lt;/sup&gt;(κ&lt;sup&gt;3&lt;/sup&gt;-N&lt;sub&gt;py&lt;/sub&gt;,N&lt;sub&gt;im&lt;/sub&gt;,O-dpkbh-H)&lt;sub&gt;2&lt;/sub&gt;]·0.5H&lt;sub&gt;2&lt;/sub&gt;O. Electronic absorption spectral measurements in non-aqueous solvents indicate sensitivity of &lt;i&gt;fac&lt;/i&gt;-[Mn&lt;sup&gt;I&lt;/sup&gt;(CO)&lt;sub&gt;3&lt;/sub&gt;(κ&lt;sup&gt;2&lt;/sup&gt;-N&lt;sub&gt;py&lt;/sub&gt;,N&lt;sub&gt;im&lt;/sub&gt;-dpkbh)Br]·H&lt;sub&gt;2&lt;/sub&gt;O and [Mn&lt;sup&gt;II&lt;/sup&gt;(κ&lt;sup&gt;3&lt;/sup&gt;-N&lt;sub&gt;py&lt;/sub&gt;,N&lt;sub&gt;im&lt;/sub&gt;,O-dpkbh-H)&lt;sub&gt;2&lt;/sub&gt;]·0.5H&lt;sub&gt;2&lt;/sub&gt;O to changes in their outer-shell environments. X-ray crystallographic analyses elucidated the identities of [Mn&lt;sup&gt;II&lt;/sup&gt;Br&lt;sub&gt;2&lt;/sub&gt;(κ&lt;sup&gt;3&lt;/sup&gt;-N&lt;sub&gt;py&lt;/sub&gt;,N&lt;sub&gt;im&lt;/sub&gt;,O-dpkbh)] and [Mn&lt;sup&gt;II&lt;/sup&gt;(κ&lt;sup&gt;3&lt;/sup&gt;-N&lt;sub&gt;py&lt;/sub&gt;,N&lt;sub&gt;im&lt;/sub&gt;,O-dpkbh-H)&lt;sub&gt;2&lt;/sub&gt;]·nX and divulged weaker coordination of [dpkbh] to Mn(II) in [Mn&lt;sup&gt;II&lt;/sup&gt;Br&lt;sub&gt;2&lt;/sub&gt;(κ&lt;sup&gt;3&lt;/sup&gt;-N&lt;sub&gt;py&lt;/sub&gt;,N&lt;sub&gt;im&lt;/sub&gt;,O-dpkbh)] and stronger coordination of [dpkbh-H]&lt;sup&gt;−&lt;/sup&gt; to Mn(II) in [Mn&lt;sup&gt;II&lt;/sup&gt;(κ&lt;sup&gt;3&lt;/sup&gt;-N&lt;sub&gt;py&lt;/sub&gt;,N&lt;sub&gt;im&lt;/sub&gt;,O-dpkbh-H)&lt;sub&gt;2&lt;/sub&gt;]·0.22H&lt;sub&gt;2&lt;/sub&gt;O. Low-temperature X-ray structural analyses were employed to account for the disorder in the structure of [Mn&lt;sup&gt;II&lt;/sup&gt;(κ&lt;sup&gt;3&lt;/sup&gt;-N&lt;sub&gt;py&lt;/sub&gt;,N&lt;sub&gt;im&lt;/sub&gt;,O-dpkbh-H)&lt;sub&gt;2&lt;/sub&gt;] and the short NH bond distance observed in the structure of [Mn&lt;sup&gt;II&lt;/sup&gt;Br&lt;sub&gt;2&lt;/sub&gt;(κ&lt;sup&gt;3&lt;/sup&gt;-N&lt;sub&gt;py&lt;/sub&gt;,N&lt;sub&gt;im&lt;/sub&gt;,O-dpkbh)]. A &lt;i&gt;PLATON&lt;/i&gt; Squeeze treatment was invoked to account for the fractional occupancy of lattice water in the structure of [Mn&lt;sup&gt;II&lt;/sup&gt;(κ&lt;sup&gt;3&lt;/sup&gt;-N&lt;sub&gt;py&lt;/sub&gt;,N&lt;sub&gt;im&lt;/sub&gt;,O-dpkbh-H)&lt;sub&gt;2&lt;/sub&gt;].</description>
  </descriptions>
</resource>
","url":"https://figshare.com/collections/Synthesis_spectroscopic_and_X_ray_crystallographic_properties_of_manganese_compounds_of_keto_and_enol_coordinated_di_2_pyridyl_ketone_benzoyl_hydrazone_dpkbh_Reactions_of_Mn_CO_sub_5_sub_Br_with_dpkbh/2853580/1","contentUrl":null,"metadataVersion":5,"schemaVersion":"http://datacite.org/schema/kernel-4","source":"api","isActive":true,"state":"findable","reason":null,"viewCount":0,"viewsOverTime":[],"downloadCount":0,"downloadsOverTime":[],"referenceCount":0,"citationCount":0,"citationsOverTime":[],"partCount":0,"partOfCount":0,"versionCount":0,"versionOfCount":0,"created":"2016-03-08T17:59:11.000Z","registered":"2016-03-08T17:59:12.000Z","published":"2016","updated":"2024-12-14T13:22:21.000Z"},"relationships":{"client":{"data":{"id":"figshare.ars","type":"clients"}},"provider":{"data":{"id":"otjm","type":"providers"}},"media":{"data":{"id":"10.6084/m9.figshare.c.2853580.v1","type":"media"}},"references":{"data":[]},"citations":{"data":[]},"parts":{"data":[]},"partOf":{"data":[]},"versions":{"data":[]},"versionOf":{"data":[]}}}}