{"data":{"id":"10.6084/m9.figshare.c.2850946.v2","type":"dois","attributes":{"doi":"10.6084/m9.figshare.c.2850946.v2","prefix":"10.6084","suffix":"m9.figshare.c.2850946.v2","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"A. Bharti","affiliation":[],"nameIdentifiers":[]},{"name":"Bharati, Pooja","nameType":"Personal","givenName":"Pooja","familyName":"Bharati","affiliation":[],"nameIdentifiers":[]},{"name":"N.K. Singh","affiliation":[],"nameIdentifiers":[]},{"name":"M.K. Bharty","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"NNS tridentate thiosemicarbazide and 1,3,4-thiadiazole-2-amine complexes of some transition metal ions: syntheses, structure and fluorescence properties"}],"publisher":"Figshare","container":{},"publicationYear":2016,"subjects":[{"subject":"Biophysics"},{"subject":"Biochemistry"},{"subject":"29999 Physical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Physical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Physical sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Molecular Biology"},{"subject":"Pharmacology"},{"subject":"Biotechnology"},{"subject":"39999 Chemical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Chemical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Chemical sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Ecology"},{"subject":"FOS: Biological sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Biological sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Cancer"}],"contributors":[],"dates":[{"date":"2016-03-25","dateType":"Created"},{"date":"2016-04-26","dateType":"Updated"},{"date":"2016","dateType":"Issued"}],"language":null,"types":{"ris":"GEN","bibtex":"misc","citeproc":"article","schemaOrg":"Collection","resourceType":"Collection","resourceTypeGeneral":"Collection"},"relatedIdentifiers":[],"relatedItems":[],"sizes":[],"formats":[],"version":null,"rightsList":[{"rights":"CC-BY","rightsUri":"http://creativecommons.org/licenses/by/3.0/us"}],"descriptions":[{"description":"The reactions of Zn(II), Mn(II), and Ni(II) acetates with 1-picolinoyl-4-phenyl-3-thiosemicarbazide (Hppts) yielded [Zn(ppts)\u003csub\u003e2\u003c/sub\u003e]·CHCl\u003csub\u003e3\u003c/sub\u003e (\u003cb\u003e3\u003c/b\u003e), [Mn(ppts)\u003csub\u003e2\u003c/sub\u003e]·THF (\u003cb\u003e4\u003c/b\u003e), and [Ni(ppts)\u003csub\u003e2\u003c/sub\u003e]·THF (\u003cb\u003e5\u003c/b\u003e), respectively, but HgCl\u003csub\u003e2\u003c/sub\u003e gave a cyclized product N-phenyl-5-(pyridin-2-yl)-1,3,4-oxadiazole-2-yl-amine (\u003cb\u003e2\u003c/b\u003e). The treatment of Hppts with conc. H\u003csub\u003e2\u003c/sub\u003eSO\u003csub\u003e4\u003c/sub\u003e formed N-phenyl-5-(pyridin-2-yl)-1,3,4-thiadiazole-2-yl-amine (\u003cb\u003e1\u003c/b\u003e). Hppts is a nonfluorescent material, but \u003cb\u003e3\u003c/b\u003e, \u003cb\u003e4\u003c/b\u003e and the cyclized products 1,3,4-oxadiazole/1,3,4-thiadiazole are fluorescent. The cyclized ligand N-phenyl-5-(pyridin-2-yl)-1,3,4-thiadiazole-2-amine (\u003cb\u003e1\u003c/b\u003e) formed [Zn(2-Hppt)\u003csub\u003e2\u003c/sub\u003e(OAc)\u003csub\u003e2\u003c/sub\u003e] (\u003cb\u003e6\u003c/b\u003e) and [Cd\u003csub\u003e2\u003c/sub\u003e(2-Hppt)\u003csub\u003e2\u003c/sub\u003e(OAc)\u003csub\u003e2\u003c/sub\u003e(\u003ci\u003eμ\u003c/i\u003e-OAc)\u003csub\u003e2\u003c/sub\u003e] (\u003cb\u003e7\u003c/b\u003e) in which Cd(II) has a binuclear acetate-bridged seven coordinate pentagonal bipyramidal geometry. Complex \u003cb\u003e7\u003c/b\u003e is also a fluorescent material with maximum emission at 425 nm at an excitation wavelength of 254 nm.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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