{"data":{"id":"10.6084/m9.figshare.c.2849971","type":"dois","attributes":{"doi":"10.6084/m9.figshare.c.2849971","prefix":"10.6084","suffix":"m9.figshare.c.2849971","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Khandolkar, Savita S.","nameType":"Personal","givenName":"Savita S.","familyName":"Khandolkar","affiliation":[],"nameIdentifiers":[]},{"name":"Näther, Christian","nameType":"Personal","givenName":"Christian","familyName":"Näther","affiliation":[],"nameIdentifiers":[]},{"name":"Bensch, Wolfgang","nameType":"Personal","givenName":"Wolfgang","familyName":"Bensch","affiliation":[],"nameIdentifiers":[]},{"name":"Bikshandarkoil R. Srinivasan","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Syntheses and structures of two new lithium-heptamolybdates"}],"publisher":"Figshare","container":{},"publicationYear":2016,"subjects":[{"subject":"Biophysics"},{"subject":"Biochemistry"},{"subject":"29999 Physical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Physical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Physical sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Cell Biology"},{"subject":"39999 Chemical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Chemical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Chemical sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Immunology"},{"subject":"FOS: Clinical medicine","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Clinical medicine","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Marine Biology"},{"subject":"Plant Biology"},{"subject":"FOS: Biological sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Biological sciences","subjectScheme":"Fields of Science and Technology (FOS)"}],"contributors":[],"dates":[{"date":"2016-03-03","dateType":"Created"},{"date":"2016-05-28","dateType":"Updated"},{"date":"2016","dateType":"Issued"}],"language":null,"types":{"ris":"GEN","bibtex":"misc","citeproc":"article","schemaOrg":"Collection","resourceType":"Collection","resourceTypeGeneral":"Collection"},"relatedIdentifiers":[{"relationType":"IsSupplementTo","relatedIdentifier":"10.1080/00958972.2016.1159679","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":[],"formats":[],"version":null,"rightsList":[{"rights":"CC-BY","rightsUri":"http://creativecommons.org/licenses/by/3.0/us"}],"descriptions":[{"description":"The synthesis, crystal structures, IR, UV–vis, \u003csup\u003e7\u003c/sup\u003eLi NMR spectra, electrochemical investigations, and conductivity studies of two new lithium-heptamolybdates, (NH\u003csub\u003e4\u003c/sub\u003e)\u003csub\u003e4\u003c/sub\u003e[Li\u003csub\u003e2\u003c/sub\u003e(H\u003csub\u003e2\u003c/sub\u003eO)\u003csub\u003e7\u003c/sub\u003e][Mo\u003csub\u003e7\u003c/sub\u003eO\u003csub\u003e24\u003c/sub\u003e]·H\u003csub\u003e2\u003c/sub\u003eO (\u003cb\u003e1\u003c/b\u003e) and (NH\u003csub\u003e4\u003c/sub\u003e)\u003csub\u003e3\u003c/sub\u003e[Li\u003csub\u003e3\u003c/sub\u003e(H\u003csub\u003e2\u003c/sub\u003eO)\u003csub\u003e4\u003c/sub\u003e(\u003ci\u003eμ\u003c/i\u003e\u003csub\u003e6\u003c/sub\u003e-Mo\u003csub\u003e7\u003c/sub\u003eO\u003csub\u003e24\u003c/sub\u003e)]·2H\u003csub\u003e2\u003c/sub\u003eO (\u003cb\u003e2\u003c/b\u003e), are reported. In \u003cb\u003e1\u003c/b\u003e the (NH\u003csub\u003e4\u003c/sub\u003e)\u003csup\u003e+\u003c/sup\u003e and [Li\u003csub\u003e2\u003c/sub\u003e(H\u003csub\u003e2\u003c/sub\u003eO)\u003csub\u003e7\u003c/sub\u003e]\u003csup\u003e2+\u003c/sup\u003e, cations are charge balanced by the heptamolybdate anion. In \u003cb\u003e2\u003c/b\u003e, the [Mo\u003csub\u003e7\u003c/sub\u003eO\u003csub\u003e24\u003c/sub\u003e]\u003csup\u003e6−\u003c/sup\u003e anion is coordinated to three unique Li\u003csup\u003e+\u003c/sup\u003e ions via a \u003ci\u003eμ\u003c/i\u003e\u003csub\u003e6\u003c/sub\u003e-hexadentate-binding mode resulting in the formation of a two-dimensional (2-D) [Li\u003csub\u003e3\u003c/sub\u003e(H\u003csub\u003e2\u003c/sub\u003eO)\u003csub\u003e4\u003c/sub\u003e(\u003ci\u003eμ\u003c/i\u003e\u003csub\u003e6\u003c/sub\u003e-Mo\u003csub\u003e7\u003c/sub\u003eO\u003csub\u003e24\u003c/sub\u003e)]\u003csup\u003e3−\u003c/sup\u003e anionic complex, charge neutralized by three (NH\u003csub\u003e4\u003c/sub\u003e)\u003csup\u003e+\u003c/sup\u003e ions. The cations, anions, and the lattice water molecules in \u003cb\u003e1\u003c/b\u003e and \u003cb\u003e2\u003c/b\u003e are linked by weak H-bonding interactions.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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