{"data":{"id":"10.6084/m9.figshare.c.2134259.v1","type":"dois","attributes":{"doi":"10.6084/m9.figshare.c.2134259.v1","prefix":"10.6084","suffix":"m9.figshare.c.2134259.v1","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Xiao, Yu","givenName":"Yu","familyName":"Xiao","affiliation":[],"nameIdentifiers":[]},{"name":"Zhang, Jian","givenName":"Jian","familyName":"Zhang","affiliation":[],"nameIdentifiers":[]},{"name":"Zhong-Xuanxu","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Synthesis of homochiral helical metal–organic frameworks based on lactate derivatives"}],"publisher":"Taylor \u0026 Francis","container":{},"publicationYear":2015,"subjects":[{"subject":"Biological Sciences"},{"subject":"Immunology"},{"subject":"FOS: Clinical medicine","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Sociology"},{"subject":"FOS: Sociology","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Ecology"},{"subject":"FOS: Biological sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Chemistry"},{"subject":"Earth and Environmental Sciences"},{"subject":"Microbiology"},{"subject":"Medicine"},{"subject":"Biochemistry"},{"subject":"Biophysics"}],"contributors":[],"dates":[{"date":"2015-12-14","dateType":"Created"},{"date":"2019-08-19","dateType":"Updated"},{"date":"2015","dateType":"Issued"}],"language":null,"types":{"ris":"GEN","bibtex":"misc","citeproc":"article","schemaOrg":"Collection","resourceType":"Collection","resourceTypeGeneral":"Collection"},"relatedIdentifiers":[{"relationType":"IsIdenticalTo","relatedIdentifier":"10.6084/m9.figshare.c.2134259","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":[],"formats":[],"version":null,"rightsList":[{"rights":"Creative Commons Attribution 4.0 International","rightsUri":"https://creativecommons.org/licenses/by/4.0/legalcode","schemeUri":"https://spdx.org/licenses/","rightsIdentifier":"cc-by-4.0","rightsIdentifierScheme":"SPDX"}],"descriptions":[{"description":"A pair of homochiral metal–organic frameworks (HMOFs) based on semi-rigid 5-(1-carboxyethoxy)isophthalic acid (H\u003csub\u003e3\u003c/sub\u003eCIA), [Zn\u003csub\u003e5\u003c/sub\u003e((\u003ci\u003eR\u003c/i\u003e)-CIA)\u003csub\u003e3\u003c/sub\u003e(OH)\u003csub\u003e2\u003c/sub\u003e(H\u003csub\u003e2\u003c/sub\u003eO)\u003csub\u003e4\u003c/sub\u003e]·NH\u003csub\u003e2\u003c/sub\u003e(CH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003e·4.5H\u003csub\u003e2\u003c/sub\u003eO (\u003cb\u003e1-D\u003c/b\u003e) and [Zn\u003csub\u003e5\u003c/sub\u003e((\u003ci\u003eS\u003c/i\u003e)-CIA)\u003csub\u003e3\u003c/sub\u003e(OH)\u003csub\u003e2\u003c/sub\u003e(H\u003csub\u003e2\u003c/sub\u003eO)\u003csub\u003e4\u003c/sub\u003e]·NH\u003csub\u003e2\u003c/sub\u003e(CH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003e·4.5H\u003csub\u003e2\u003c/sub\u003eO (\u003cb\u003e1-L\u003c/b\u003e), were synthesized and structurally characterized. They are enantiomers and exhibit three-dimensional framework structures. In each structure, the CIA ligands link the Zn centers into a homochiral open framework with tetranuclear and trinuclear Zn-clusters. An interesting double helix built from the connectivity between CIA ligands and Zn centers is presented. The chiral nature of \u003cb\u003e1-D\u003c/b\u003e and \u003cb\u003e1-L\u003c/b\u003e was further confirmed by CD spectra. Photoluminescence of \u003cb\u003e1-D\u003c/b\u003e was also investigated in the solid state at room temperature.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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","url":"https://tandf.figshare.com/collections/Synthesis_of_homochiral_helical_metal_organic_frameworks_based_on_lactate_derivatives/2134259/1","contentUrl":null,"metadataVersion":2,"schemaVersion":"http://datacite.org/schema/kernel-4","source":"mds","isActive":true,"state":"findable","reason":null,"viewCount":0,"viewsOverTime":[],"downloadCount":0,"downloadsOverTime":[],"referenceCount":0,"citationCount":0,"citationsOverTime":[],"par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