{"data":{"id":"10.6084/m9.figshare.c.2128808","type":"dois","attributes":{"doi":"10.6084/m9.figshare.c.2128808","prefix":"10.6084","suffix":"m9.figshare.c.2128808","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"P. McMoran, Ethan","givenName":"Ethan","familyName":"P. McMoran","affiliation":[],"nameIdentifiers":[]},{"name":"Mugenzi, Clement","givenName":"Clement","familyName":"Mugenzi","affiliation":[],"nameIdentifiers":[]},{"name":"Fournier, Kyle","givenName":"Kyle","familyName":"Fournier","affiliation":[],"nameIdentifiers":[]},{"name":"Draganjac, Mark","givenName":"Mark","familyName":"Draganjac","affiliation":[],"nameIdentifiers":[]},{"name":"Tony, Donavon","givenName":"Donavon","familyName":"Tony","affiliation":[],"nameIdentifiers":[]},{"name":"Jeong, Kwangkook","givenName":"Kwangkook","familyName":"Jeong","affiliation":[],"nameIdentifiers":[]},{"name":"Powell, Douglas R.","givenName":"Douglas R.","familyName":"Powell","affiliation":[],"nameIdentifiers":[]},{"name":"Yang, Lei","givenName":"Lei","familyName":"Yang","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Synthesis and characterization of divalent metal complexes with bipyridylamide ligands"}],"publisher":"Taylor \u0026 Francis","container":{},"publicationYear":2015,"subjects":[{"subject":"Biophysics"},{"subject":"Biochemistry"},{"subject":"Physical Sciences not elsewhere classified"},{"subject":"Medicine"},{"subject":"Cell Biology"},{"subject":"Molecular Biology"},{"subject":"Chemical Sciences not elsewhere classified"},{"subject":"Sociology"},{"subject":"FOS: Sociology","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Biological Sciences not elsewhere classified"},{"subject":"Marine Biology"}],"contributors":[],"dates":[{"date":"2015-12-05","dateType":"Created"},{"date":"2019-08-19","dateType":"Updated"},{"date":"2015","dateType":"Issued"}],"language":null,"types":{"ris":"GEN","bibtex":"misc","citeproc":"article","schemaOrg":"Collection","resourceType":"Collection","resourceTypeGeneral":"Collection"},"relatedIdentifiers":[],"relatedItems":[],"sizes":[],"formats":[],"version":null,"rightsList":[{"rights":"Creative Commons Attribution 4.0 International","rightsUri":"https://creativecommons.org/licenses/by/4.0/legalcode","schemeUri":"https://spdx.org/licenses/","rightsIdentifier":"cc-by-4.0","rightsIdentifierScheme":"SPDX"}],"descriptions":[{"description":"Reaction of \u003ci\u003eN\u003c/i\u003e-(4-pyridyl)picolinamide (4-ppa), \u003ci\u003eN\u003c/i\u003e-(4-pyridyl)nicotinamide (4-pna), \u003ci\u003eN\u003c/i\u003e-(4-pyridyl)isonicotinamide (4-pina), and \u003ci\u003eN\u003c/i\u003e-(2-pyridyl)isonicotinamide (2-pina) with divalent metal salts led to the formation of six new coordination complexes. The X-ray structure of [Zn(4-ppa)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e] (\u003cb\u003e1\u003c/b\u003e) shows a mononuclear structure with interesting intermolecular hydrogen bonding interactions. [Zn(4-pna)(OAc)\u003csub\u003e2\u003c/sub\u003e]\u003csub\u003en\u003c/sub\u003e (\u003cb\u003e2\u003c/b\u003e), Cu(4-pna)(OTf)\u003csub\u003e2\u003c/sub\u003e(DMF)\u003csub\u003e2\u003c/sub\u003e]\u003csub\u003en\u003c/sub\u003e (\u003cb\u003e3\u003c/b\u003e), {[Zn(4-pina)(DMF)\u003csub\u003e4\u003c/sub\u003e](OTf)\u003csub\u003e2\u003c/sub\u003e}\u003csub\u003en\u003c/sub\u003e (\u003cb\u003e4\u003c/b\u003e), {[Fe(4-pina)(DMF)\u003csub\u003e4\u003c/sub\u003e](OTf)\u003csub\u003e2\u003c/sub\u003e}\u003csub\u003en\u003c/sub\u003e (\u003cb\u003e5\u003c/b\u003e), and [Cu(2-pina)(OTf)\u003csub\u003e2\u003c/sub\u003e(DMF)\u003csub\u003e2\u003c/sub\u003e]\u003csub\u003en\u003c/sub\u003e (\u003cb\u003e6\u003c/b\u003e) are one-dimensional coordination polymers with conformational differences caused by the coordination donor disposition, which demonstrates the flexibility of the pyridylamide ligands in polymeric structures. Reflectance UV-visible spectra and thermal properties of the coordination polymers are also reported.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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