{"data":{"id":"10.6084/m9.figshare.c.2127467.v1","type":"dois","attributes":{"doi":"10.6084/m9.figshare.c.2127467.v1","prefix":"10.6084","suffix":"m9.figshare.c.2127467.v1","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Yan, Hong","givenName":"Hong","familyName":"Yan","affiliation":[],"nameIdentifiers":[]},{"name":"Tan, Hong-bo","givenName":"Hong-bo","familyName":"Tan","affiliation":[],"nameIdentifiers":[]},{"name":"Zhong, Qi-di","givenName":"Qi-di","familyName":"Zhong","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Studies on the Photochemical Oxidation of\u003ci\u003eN,N\u003c/i\u003e-Diacyl-1,4-dihydropyrazine Derivatives"}],"publisher":"Taylor \u0026 Francis","container":{},"publicationYear":2015,"subjects":[{"subject":"Biological Sciences"},{"subject":"Immunology"},{"subject":"FOS: Clinical medicine","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Ecology"},{"subject":"FOS: Biological sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Chemistry"},{"subject":"Earth and Environmental Sciences"},{"subject":"Cell Biology"},{"subject":"Microbiology"},{"subject":"Physics"},{"subject":"Biochemistry"},{"subject":"Biophysics"}],"contributors":[],"dates":[{"date":"2015-12-05","dateType":"Created"},{"date":"2019-08-20","dateType":"Updated"},{"date":"2015","dateType":"Issued"}],"language":null,"types":{"ris":"GEN","bibtex":"misc","citeproc":"article","schemaOrg":"Collection","resourceType":"Collection","resourceTypeGeneral":"Collection"},"relatedIdentifiers":[{"relationType":"IsPreviousVersionOf","relatedIdentifier":"10.6084/m9.figshare.c.2127467","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":[],"formats":[],"version":null,"rightsList":[{"rights":"Creative Commons Attribution 4.0 International","rightsUri":"https://creativecommons.org/licenses/by/4.0/legalcode","schemeUri":"https://spdx.org/licenses/","rightsIdentifier":"cc-by-4.0","rightsIdentifierScheme":"SPDX"}],"descriptions":[{"description":"sThe photochemical oxidation of \u003ci\u003eN,N\u003c/i\u003e-diacyl-1,4-dihydropyrazines was investigated by irradiation from a medium-pressure mercury lamp. The main products of the photooxygenation were isolated and unambiguously confirmed by \u003csup\u003e1\u003c/sup\u003eH NMR spectra, \u003csup\u003e13\u003c/sup\u003eC NMR spectra, H-H, C-H COSY spectra and HRMS and single crystal X-ray diffraction analysis. The complicated NMR spectra of main products were studied by variable-temperature NMR experiments. The mechanism of the photooxygenation of \u003ci\u003eN,N\u003c/i\u003e-diacyl-1,4-dihydropyrazines is suggested to be a [2 + 2] cycloaddition of oxygen to the double bond.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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","url":"https://tandf.figshare.com/collections/Studies_on_the_Photochemical_Oxidation_of_i_N_N_i_Diacyl_1_4_dihydropyrazine_Derivatives/2127467/1","contentUrl":null,"metadataVersion":3,"schemaVersion":"http://datacite.org/schema/kernel-4","source":"mds","isActive":true,"state":"findable","reason":null,"viewCount":0,"viewsOverTime":[],"downloadCount":0,"downloadsOverTime":[],"referenceCount":0,"citationCount":0,"citationsOverTime":[],"partCount":0,"partOfCount":0,"versionCount":0,"versionOfCount":0,"created":"2015-12-05T21:22:05.000Z","registered":"2015-12-05T21:22:06.000Z","published":"2015","updated":"2024-03-21T09:32:35.000Z"},"relationships":{"client":{"data":{"id":"figshare.ars","type":"clients"}},"provider":{"data":{"id":"otjm","type":"providers"}},"media":{"data":{"id":"10.6084/m9.figshare.c.2127467.v1","type":"media"}},"references":{"data":[]},"citations":{"data":[]},"parts":{"data":[]},"partOf":{"data":[]},"versions":{"data":[]},"versionOf":{"data":[]}}}}