{"data":{"id":"10.6084/m9.figshare.c.2127467","type":"dois","attributes":{"doi":"10.6084/m9.figshare.c.2127467","prefix":"10.6084","suffix":"m9.figshare.c.2127467","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Tan, Hong-bo","givenName":"Hong-bo","familyName":"Tan","affiliation":[],"nameIdentifiers":[]},{"name":"Zhong, Qi-di","givenName":"Qi-di","familyName":"Zhong","affiliation":[],"nameIdentifiers":[]},{"name":"Yan, Hong","givenName":"Hong","familyName":"Yan","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Studies on the photochemical oxidation of \u003ci\u003eN\u003c/i\u003e,\u003ci\u003eN\u003c/i\u003e-diacyl-1,4-dihydropyrazine derivatives"}],"publisher":"Taylor \u0026 Francis","container":{},"publicationYear":2015,"subjects":[{"subject":"Biophysics"},{"subject":"Biochemistry"},{"subject":"Physical Sciences not elsewhere classified"},{"subject":"Cell Biology"},{"subject":"Biotechnology"},{"subject":"Environmental Sciences not elsewhere classified"},{"subject":"Chemical Sciences not elsewhere classified"},{"subject":"Ecology"},{"subject":"FOS: Biological sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Immunology"},{"subject":"FOS: Clinical medicine","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"}],"contributors":[],"dates":[{"date":"2015-12-05","dateType":"Created"},{"date":"2019-08-19","dateType":"Updated"},{"date":"2015","dateType":"Issued"}],"language":null,"types":{"ris":"GEN","bibtex":"misc","citeproc":"article","schemaOrg":"Collection","resourceType":"Collection","resourceTypeGeneral":"Collection"},"relatedIdentifiers":[],"relatedItems":[],"sizes":[],"formats":[],"version":null,"rightsList":[{"rights":"Creative Commons Attribution 4.0 International","rightsUri":"https://creativecommons.org/licenses/by/4.0/legalcode","schemeUri":"https://spdx.org/licenses/","rightsIdentifier":"cc-by-4.0","rightsIdentifierScheme":"SPDX"}],"descriptions":[{"description":"The photochemical oxidation of \u003ci\u003eN,N\u003c/i\u003e-diacyl-1,4-dihydropyrazines was investigated by irradiation from a medium-pressure mercury lamp. The main products of the photooxygenation were isolated and unambiguously confirmed by \u003csup\u003e1\u003c/sup\u003eH NMR spectra, \u003csup\u003e13\u003c/sup\u003eC NMR spectra, H-H, C-H correlation spectra, high-resolution mass spectrometry, and single-crystal x-ray diffraction analysis. The complicated NMR spectra of main products were studied by variable-temperature NMR experiments. The mechanism of the photooxygenation of \u003ci\u003eN,N\u003c/i\u003e-diacyl-1,4-dihydropyrazines is suggested to be a [2 + 2] cycloaddition of oxygen to the double bond.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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","url":"https://tandf.figshare.com/collections/Studies_on_the_Photochemical_Oxidation_of_i_N_N_i_Diacyl_1_4_dihydropyrazine_Derivatives/2127467","contentUrl":null,"metadataVersion":3,"schemaVersion":"http://datacite.org/schema/kernel-4","source":"mds","isActive":true,"state":"findable","reason":null,"viewCount":0,"viewsOverTime":[],"downloadCount":0,"downloadsOverTime":[],"referenceCount":0,"citationCount":0,"citationsOverTime":[],"partCount":0,"partOfCount":0,"versionCount":0,"versionOfCount":0,"created":"2015-12-05T18:58:42.000Z","registered":"2015-12-05T18:58:43.000Z","published":"2015","updated":"2024-03-21T09:32:32.000Z"},"relationships":{"client":{"data":{"id":"figshare.ars","type":"clients"}},"provider":{"data":{"id":"otjm","type":"providers"}},"media":{"data":{"id":"10.6084/m9.figshare.c.2127467","type":"media"}},"references":{"data":[]},"citations":{"data":[]},"parts":{"data":[]},"partOf":{"data":[]},"versions":{"data":[]},"versionOf":{"data":[]}}}}