{"data":{"id":"10.6084/m9.figshare.c.2126849.v1","type":"dois","attributes":{"doi":"10.6084/m9.figshare.c.2126849.v1","prefix":"10.6084","suffix":"m9.figshare.c.2126849.v1","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Wang, Xiuli","givenName":"Xiuli","familyName":"Wang","affiliation":[],"nameIdentifiers":[]},{"name":"Tian, Aixiang","givenName":"Aixiang","familyName":"Tian","affiliation":[],"nameIdentifiers":[]},{"name":"Xu, Na","givenName":"Na","familyName":"Xu","affiliation":[],"nameIdentifiers":[]},{"name":"Zhang, Rui","givenName":"Rui","familyName":"Zhang","affiliation":[],"nameIdentifiers":[]},{"name":"Li, Tianjiao","givenName":"Tianjiao","familyName":"Li","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"The rigid isomeric 5-(x-pyridyl)-1H-tetrazole ligands-directed various isopolymolybdate-based compounds: Assembly, structures and properties"}],"publisher":"Taylor \u0026 Francis","container":{},"publicationYear":2015,"subjects":[{"subject":"Biological Sciences"},{"subject":"Immunology"},{"subject":"FOS: Clinical medicine","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Ecology"},{"subject":"FOS: Biological sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Chemistry"},{"subject":"Earth and Environmental Sciences"},{"subject":"Biotechnology"},{"subject":"Cell Biology"},{"subject":"Biochemistry"},{"subject":"Biophysics"}],"contributors":[],"dates":[{"date":"2015-12-05","dateType":"Created"},{"date":"2019-08-19","dateType":"Updated"},{"date":"2015","dateType":"Issued"}],"language":null,"types":{"ris":"GEN","bibtex":"misc","citeproc":"article","schemaOrg":"Collection","resourceType":"Collection","resourceTypeGeneral":"Collection"},"relatedIdentifiers":[{"relationType":"IsIdenticalTo","relatedIdentifier":"10.6084/m9.figshare.c.2126849","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":[],"formats":[],"version":null,"rightsList":[{"rights":"Creative Commons Attribution 4.0 International","rightsUri":"https://creativecommons.org/licenses/by/4.0/legalcode","schemeUri":"https://spdx.org/licenses/","rightsIdentifier":"cc-by-4.0","rightsIdentifierScheme":"SPDX"}],"descriptions":[{"description":"Two new isopolymolybdate-based metal-organic complexes, [Cu\u003csub\u003e2\u003c/sub\u003e(2-ptz)\u003csub\u003e2\u003c/sub\u003e(Mo\u003csub\u003e4\u003c/sub\u003eO\u003csub\u003e14\u003c/sub\u003e)\u003csub\u003e0.5\u003c/sub\u003e] (\u003cb\u003e1\u003c/b\u003e) and [Cu\u003csub\u003e3\u003c/sub\u003e(OH)\u003csub\u003e2\u003c/sub\u003e(3-ptz)\u003csub\u003e4\u003c/sub\u003e(γ-H\u003csub\u003e4\u003c/sub\u003eMo\u003csub\u003e8\u003c/sub\u003eO\u003csub\u003e26\u003c/sub\u003e)(H\u003csub\u003e2\u003c/sub\u003eO)\u003csub\u003e4\u003c/sub\u003e]·10H\u003csub\u003e2\u003c/sub\u003eO (\u003cb\u003e2\u003c/b\u003e) (2-ptzH = 5-(2-pyridyl)-1H-tetrazole, 3-ptzH = 5-(3-pyridyl)-1H-tetrazole), constructed from isomeric ligands with different N-donor sites were synthesized under hydrothermal conditions. In \u003cb\u003e1\u003c/b\u003e, each [Mo\u003csub\u003e4\u003c/sub\u003eO\u003csub\u003e14\u003c/sub\u003e]\u003csup\u003e4-\u003c/sup\u003e cluster connected with six neighboring [Mo\u003csub\u003e4\u003c/sub\u003eO\u003csub\u003e14\u003c/sub\u003e]\u003csup\u003e4-\u003c/sup\u003e clusters through six binuclear [Cu\u003csub\u003e2\u003c/sub\u003e(2-ptz)\u003csub\u003e2\u003c/sub\u003e]\u003csup\u003e2+\u003c/sup\u003e subunits to yield a two-dimensional (2D) layer. In \u003cb\u003e2\u003c/b\u003e, bidentate inorganic [Mo\u003csub\u003e8\u003c/sub\u003eO\u003csub\u003e26\u003c/sub\u003e]\u003csup\u003e4-\u003c/sup\u003e anions link the trinuclear [Cu\u003csub\u003e3\u003c/sub\u003e(OH)\u003csub\u003e2\u003c/sub\u003e(3-ptz)\u003csub\u003e4\u003c/sub\u003e] clusters to construct a 1D chain. Adjacent chains connect through Mo-N bonds between the [Mo\u003csub\u003e8\u003c/sub\u003eO\u003csub\u003e26\u003c/sub\u003e]\u003csup\u003e4-\u003c/sup\u003e anions and pyridyl groups from the trinuclear clusters to form a 2D layer. The effect of the N-donor sites of the rigid isomeric ligands on the structures of \u003cb\u003e1\u003c/b\u003e and \u003cb\u003e2\u003c/b\u003e was discussed. The electrochemical properties and photocatalytic activities of \u003cb\u003e1\u003c/b\u003e and \u003cb\u003e2\u003c/b\u003e have also been studied.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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