{"data":{"id":"10.6084/m9.figshare.c.2077712","type":"dois","attributes":{"doi":"10.6084/m9.figshare.c.2077712","prefix":"10.6084","suffix":"m9.figshare.c.2077712","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Shi, Yao-Cheng","givenName":"Yao-Cheng","familyName":"Shi","affiliation":[],"nameIdentifiers":[]},{"name":"Shi, Ying","givenName":"Ying","familyName":"Shi","affiliation":[],"nameIdentifiers":[]},{"name":"Li, Jin-ping","givenName":"Jin-ping","familyName":"Li","affiliation":[],"nameIdentifiers":[]},{"name":"Tan, Qing","givenName":"Qing","familyName":"Tan","affiliation":[],"nameIdentifiers":[]},{"name":"Yang, Wei","givenName":"Wei","familyName":"Yang","affiliation":[],"nameIdentifiers":[]},{"name":"Xie, Sun","givenName":"Sun","familyName":"Xie","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Syntheses, crystal structures, and electrochemistry of novel Fe\u003csub\u003e2\u003c/sub\u003eSN and FeSN carbonyl complexes with pendant bases"}],"publisher":"Taylor \u0026 Francis","container":{},"publicationYear":2015,"subjects":[{"subject":"Biological Sciences"},{"subject":"Sociology"},{"subject":"FOS: Sociology","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Ecology"},{"subject":"FOS: Biological sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Chemistry"},{"subject":"Earth and Environmental Sciences"},{"subject":"Biochemistry"},{"subject":"Biophysics"}],"contributors":[],"dates":[{"date":"2015-12-05","dateType":"Created"},{"date":"2019-08-19","dateType":"Updated"},{"date":"2015","dateType":"Issued"}],"language":null,"types":{"ris":"GEN","bibtex":"misc","citeproc":"article","schemaOrg":"Collection","resourceType":"Collection","resourceTypeGeneral":"Collection"},"relatedIdentifiers":[],"relatedItems":[],"sizes":[],"formats":[],"version":null,"rightsList":[{"rights":"Creative Commons Attribution 4.0 International","rightsUri":"https://creativecommons.org/licenses/by/4.0/legalcode","schemeUri":"https://spdx.org/licenses/","rightsIdentifier":"cc-by-4.0","rightsIdentifierScheme":"SPDX"}],"descriptions":[{"description":"Reactions of Fe\u003csub\u003e2\u003c/sub\u003e(CO)\u003csub\u003e9\u003c/sub\u003e with thioacylhydrazones ArCH=NNHCSPh in THF afford Fe\u003csub\u003e2\u003c/sub\u003e(CO)\u003csub\u003e6\u003c/sub\u003e(μ-κ\u003csup\u003e2\u003c/sup\u003eS:κ\u003csup\u003e2\u003c/sup\u003eN-PhC(S)=NNCHArCHArN(CHAr)N=CSPh) (\u003cb\u003e1\u003c/b\u003e, Ar = C\u003csub\u003e6\u003c/sub\u003eH\u003csub\u003e5\u003c/sub\u003e; \u003cb\u003e3\u003c/b\u003e, Ar = 4-CH\u003csub\u003e3\u003c/sub\u003eC\u003csub\u003e6\u003c/sub\u003eH\u003csub\u003e4\u003c/sub\u003e) and Fe(CO)\u003csub\u003e3\u003c/sub\u003e(κ\u003csup\u003e2\u003c/sup\u003eS:N-PhC(=S)NHNCHArCHArN(CHAr)N=CSPh) (\u003cb\u003e2\u003c/b\u003e, Ar = C\u003csub\u003e6\u003c/sub\u003eH\u003csub\u003e5\u003c/sub\u003e; \u003cb\u003e4\u003c/b\u003e, Ar = 4-CH\u003csub\u003e3\u003c/sub\u003eC\u003csub\u003e6\u003c/sub\u003eH\u003csub\u003e4\u003c/sub\u003e). They have been characterized by elemental analyses, IR, \u003csup\u003e1\u003c/sup\u003eH NMR, and \u003csup\u003e13\u003c/sup\u003eC NMR and structurally determined by X-ray crystallography. Electrochemical studies reveal that when using HOAc as a proton source, they exhibit high catalytic H\u003csub\u003e2\u003c/sub\u003e-production.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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","url":"https://tandf.figshare.com/collections/Syntheses_crystal_structures_and_electrochemistry_of_novel_Fe_sub_2_sub_SN_and_FeSN_carbonyl_complexes_with_pendant_bases/2077712","contentUrl":null,"metadataVersion":2,"schemaVersion":"http://datacite.org/schema/kernel-4","source":"mds","isActive":true,"state":"findable","reason":null,"viewCount":0,"viewsOverTime":[],"downloadCount":0,"downloadsOverTime":[],"referenceCount":0,"citationCount":0,"citationsOverTime":[],"partCount":0,"partOfCount":0,"versionCount":0,"versionOfCount":0,"created":"2015-12-05T17:53:04.000Z","registered":"2015-12-05T17:53:05.000Z","published":"2015","updated":"2024-03-21T08:45:06.000Z"},"relationships":{"client":{"data":{"id":"figshare.ars","type":"clients"}},"provider":{"data":{"id":"otjm","type":"providers"}},"media":{"data":{"id":"10.6084/m9.figshare.c.2077712","type":"media"}},"references":{"data":[]},"citations":{"data":[]},"parts":{"data":[]},"partOf":{"data":[]},"versions":{"data":[]},"versionOf":{"data":[]}}}}