{"data":{"id":"10.6084/m9.figshare.c.2062739.v1","type":"dois","attributes":{"doi":"10.6084/m9.figshare.c.2062739.v1","prefix":"10.6084","suffix":"m9.figshare.c.2062739.v1","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Shi, Ying","givenName":"Ying","familyName":"Shi","affiliation":[],"nameIdentifiers":[]},{"name":"Shi, Yao-Cheng","givenName":"Yao-Cheng","familyName":"Shi","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Syntheses, crystal structures, and electrochemical studies of diiron complexes from the reactions of [Et\u003csub\u003e3\u003c/sub\u003eNH][(μ-RS) Fe\u003csub\u003e2\u003c/sub\u003e(CO)\u003csub\u003e6\u003c/sub\u003e(μ-CO)] with isothiocyanates"}],"publisher":"Taylor \u0026 Francis","container":{},"publicationYear":2015,"subjects":[{"subject":"Virology"},{"subject":"Developmental Biology"},{"subject":"Biological Sciences"},{"subject":"Immunology"},{"subject":"FOS: Clinical medicine","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Ecology"},{"subject":"FOS: Biological sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Chemistry"},{"subject":"Earth and Environmental Sciences"},{"subject":"Biochemistry"},{"subject":"Biophysics"}],"contributors":[],"dates":[{"date":"2015-12-05","dateType":"Created"},{"date":"2019-08-19","dateType":"Updated"},{"date":"2015","dateType":"Issued"}],"language":null,"types":{"ris":"GEN","bibtex":"misc","citeproc":"article","schemaOrg":"Collection","resourceType":"Collection","resourceTypeGeneral":"Collection"},"relatedIdentifiers":[{"relationType":"IsIdenticalTo","relatedIdentifier":"10.6084/m9.figshare.c.2062739","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":[],"formats":[],"version":null,"rightsList":[{"rights":"Creative Commons Attribution 4.0 International","rightsUri":"https://creativecommons.org/licenses/by/4.0/legalcode","schemeUri":"https://spdx.org/licenses/","rightsIdentifier":"cc-by-4.0","rightsIdentifierScheme":"SPDX"}],"descriptions":[{"description":"Reactions of [Et\u003csub\u003e3\u003c/sub\u003eNH][(μ-MeO\u003csub\u003e2\u003c/sub\u003eCCH\u003csub\u003e2\u003c/sub\u003eS)Fe\u003csub\u003e2\u003c/sub\u003e(CO)\u003csub\u003e6\u003c/sub\u003e(μ-CO)] \u003ci\u003ein situ\u003c/i\u003e generated from the mixture of MeO\u003csub\u003e2\u003c/sub\u003eCCH\u003csub\u003e2\u003c/sub\u003eSH, Et\u003csub\u003e3\u003c/sub\u003eN, and Fe\u003csub\u003e3\u003c/sub\u003e(CO)\u003csub\u003e12\u003c/sub\u003e with 2-C\u003csub\u003e5\u003c/sub\u003eH\u003csub\u003e4\u003c/sub\u003eNNCS, 3-C\u003csub\u003e5\u003c/sub\u003eH\u003csub\u003e4\u003c/sub\u003eNNCS, and EtNCS in THF, form \u003cb\u003e1\u003c/b\u003e, (μ-MeO\u003csub\u003e2\u003c/sub\u003eCCH\u003csub\u003e2\u003c/sub\u003eS)Fe\u003csub\u003e2\u003c/sub\u003e(CO)\u003csub\u003e5\u003c/sub\u003e(μ-k\u003csup\u003e2\u003c/sup\u003eN,S:k\u003csup\u003e2\u003c/sup\u003eC-2-C\u003csub\u003e5\u003c/sub\u003eH\u003csub\u003e4\u003c/sub\u003eNNHCS), \u003cb\u003e2\u003c/b\u003e, (μ-MeO\u003csub\u003e2\u003c/sub\u003eCCH\u003csub\u003e2\u003c/sub\u003eS)Fe\u003csub\u003e2\u003c/sub\u003e(CO)\u003csub\u003e6\u003c/sub\u003e(μ-k\u003csup\u003e2\u003c/sup\u003eC,S-3-C\u003csub\u003e5\u003c/sub\u003eH\u003csub\u003e4\u003c/sub\u003eNNHCS), and \u003cb\u003e3\u003c/b\u003e, (μ-MeO\u003csub\u003e2\u003c/sub\u003eCCH\u003csub\u003e2\u003c/sub\u003eS)Fe\u003csub\u003e2\u003c/sub\u003e(CO)\u003csub\u003e6\u003c/sub\u003e(μ-k\u003csup\u003e2\u003c/sup\u003eC,S-EtNHCS). Reaction of [Et\u003csub\u003e3\u003c/sub\u003eNH][(μ-PhS)Fe\u003csub\u003e2\u003c/sub\u003e(CO)\u003csub\u003e6\u003c/sub\u003e(μ-CO)] \u003ci\u003ein situ\u003c/i\u003e formed from the mixture of PhSH, Et\u003csub\u003e3\u003c/sub\u003eN, and Fe\u003csub\u003e3\u003c/sub\u003e(CO)\u003csub\u003e12\u003c/sub\u003e with EtNCS affords \u003cb\u003e4\u003c/b\u003e, (μ-PhS)Fe\u003csub\u003e2\u003c/sub\u003e(CO)\u003csub\u003e6\u003c/sub\u003e(μ-k\u003csup\u003e2\u003c/sup\u003eC,S-EtNHCS). Reaction of [Et\u003csub\u003e3\u003c/sub\u003eNH][(μ-EtS)Fe\u003csub\u003e2\u003c/sub\u003e(CO)\u003csub\u003e6\u003c/sub\u003e(μ-CO)] \u003ci\u003ein situ\u003c/i\u003e produced from the mixture of EtSH, Et\u003csub\u003e3\u003c/sub\u003eN, and Fe\u003csub\u003e3\u003c/sub\u003e(CO)\u003csub\u003e12\u003c/sub\u003e with EtNCS offers \u003cb\u003e5\u003c/b\u003e, (μ-EtS)Fe\u003csub\u003e2\u003c/sub\u003e(CO)\u003csub\u003e6\u003c/sub\u003e(μ-k\u003csup\u003e2\u003c/sup\u003eC,S-EtNHCS). All new complexes have been fully characterized by EA, IR, \u003csup\u003e1\u003c/sup\u003eH NMR, and \u003csup\u003e13\u003c/sup\u003eC NMR and structurally determined by X-ray crystallography. Electrochemical studies on \u003cb\u003e2\u003c/b\u003e and \u003cb\u003e5\u003c/b\u003e confirm that \u003cb\u003e2\u003c/b\u003e shows high H\u003csub\u003e2\u003c/sub\u003e-producing activity.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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