{"data":{"id":"10.6084/m9.figshare.c.2060831","type":"dois","attributes":{"doi":"10.6084/m9.figshare.c.2060831","prefix":"10.6084","suffix":"m9.figshare.c.2060831","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Zhang, Wenli","givenName":"Wenli","familyName":"Zhang","affiliation":[],"nameIdentifiers":[]},{"name":"Li, Xinghui","givenName":"Xinghui","familyName":"Li","affiliation":[],"nameIdentifiers":[]},{"name":"Wu, Huanhuan","givenName":"Huanhuan","familyName":"Wu","affiliation":[],"nameIdentifiers":[]},{"name":"Shen, Lixia","givenName":"Lixia","familyName":"Shen","affiliation":[],"nameIdentifiers":[]},{"name":"Li, Li","givenName":"Li","familyName":"Li","affiliation":[],"nameIdentifiers":[]},{"name":"Yue, Zhongcheng","givenName":"Zhongcheng","familyName":"Yue","affiliation":[],"nameIdentifiers":[]},{"name":"Niu, Yunyin","givenName":"Yunyin","familyName":"Niu","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Syntheses and Crystal Structure of Three Novel Supramolecular Halides/Pseudohalides {(DMB)[Cu\u003csub\u003e2\u003c/sub\u003e(SCN)\u003csub\u003e4\u003c/sub\u003e]}\u003csub\u003en,\u003c/sub\u003e{(DMB)[Cu(SCN)\u003csub\u003e4\u003c/sub\u003e]}, and {(DMB)[Ag\u003csub\u003e2\u003c/sub\u003e(SCN)\u003csub\u003e4\u003c/sub\u003e]}\u003csub\u003en\u003c/sub\u003e Directed by Dicationic Template Possessing C2-Symmetry"}],"publisher":"Taylor \u0026 Francis","container":{},"publicationYear":2015,"subjects":[{"subject":"Biological Sciences"},{"subject":"Sociology"},{"subject":"FOS: Sociology","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Ecology"},{"subject":"FOS: Biological sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Chemistry"},{"subject":"Earth and Environmental Sciences"},{"subject":"Physiology"},{"subject":"Molecular Biology"},{"subject":"Cell Biology"},{"subject":"Physics"},{"subject":"Biochemistry"},{"subject":"Biophysics"}],"contributors":[],"dates":[{"date":"2015-12-05","dateType":"Created"},{"date":"2019-08-19","dateType":"Updated"},{"date":"2015","dateType":"Issued"}],"language":null,"types":{"ris":"GEN","bibtex":"misc","citeproc":"article","schemaOrg":"Collection","resourceType":"Collection","resourceTypeGeneral":"Collection"},"relatedIdentifiers":[],"relatedItems":[],"sizes":[],"formats":[],"version":null,"rightsList":[{"rights":"Creative Commons Attribution 4.0 International","rightsUri":"https://creativecommons.org/licenses/by/4.0/legalcode","schemeUri":"https://spdx.org/licenses/","rightsIdentifier":"cc-by-4.0","rightsIdentifierScheme":"SPDX"}],"descriptions":[{"description":"Three novel hybrid complexes, namely{(DMB)[Cu\u003csub\u003e2\u003c/sub\u003e(SCN)\u003csub\u003e4\u003c/sub\u003e]}\u003csub\u003en\u003c/sub\u003e (\u003cb\u003e1\u003c/b\u003e), {(DMB)[Cu(SCN)\u003csub\u003e4\u003c/sub\u003e]} (\u003cb\u003e2\u003c/b\u003e), \u003cb\u003eand\u003c/b\u003e {(DMB)[Ag\u003csub\u003e2\u003c/sub\u003e(SCN)\u003csub\u003e4\u003c/sub\u003e]}\u003csub\u003en\u003c/sub\u003e (\u003cb\u003e3\u003c/b\u003e), have been synthesized via the self-assembly in DMF–methanol system based on multidentate ligand DMB, {DMB = α, α\u003ci\u003e′\u003c/i\u003e- di(3-methylimidozole-1-yl)benzene dichloride}. Single-crystal X-ray diffraction analysis shows \u003cb\u003e1\u003c/b\u003e and \u003cb\u003e3\u003c/b\u003e are 1D supramolecules, whereas \u003cb\u003e2\u003c/b\u003e is mononuclear. Electrostatic interactions between the organic counteranions and inorganic moieties are present and do the contribution to the crystal packing. These compounds have been further characterized by IR spectroscopy and thermostability properties.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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