{"data":{"id":"10.6084/m9.figshare.c.2040191.v1","type":"dois","attributes":{"doi":"10.6084/m9.figshare.c.2040191.v1","prefix":"10.6084","suffix":"m9.figshare.c.2040191.v1","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Meng, Gao-Xiang","givenName":"Gao-Xiang","familyName":"Meng","affiliation":[],"nameIdentifiers":[]},{"name":"Feng, Ya-Min","givenName":"Ya-Min","familyName":"Feng","affiliation":[],"nameIdentifiers":[]},{"name":"Wang, Yin","givenName":"Yin","familyName":"Wang","affiliation":[],"nameIdentifiers":[]},{"name":"Gao, Yong-Li","givenName":"Yong-Li","familyName":"Gao","affiliation":[],"nameIdentifiers":[]},{"name":"Wan, Wen-Wu","givenName":"Wen-Wu","familyName":"Wan","affiliation":[],"nameIdentifiers":[]},{"name":"Huang, Xin-Tang","givenName":"Xin-Tang","familyName":"Huang","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Effect of pH on the self-assembly of three Cd(II) coordination compounds containing 5-(4-pyridyl)tetrazole: syntheses, structures, and properties"}],"publisher":"Taylor \u0026 Francis","container":{},"publicationYear":2015,"subjects":[{"subject":"Mathematics"},{"subject":"FOS: Mathematics","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Biological Sciences"},{"subject":"Chemistry"},{"subject":"Earth and Environmental Sciences"},{"subject":"Cell Biology"},{"subject":"Physics"},{"subject":"Biochemistry"},{"subject":"Biophysics"}],"contributors":[],"dates":[{"date":"2015-12-05","dateType":"Created"},{"date":"2019-08-19","dateType":"Updated"},{"date":"2015","dateType":"Issued"}],"language":null,"types":{"ris":"GEN","bibtex":"misc","citeproc":"article","schemaOrg":"Collection","resourceType":"Collection","resourceTypeGeneral":"Collection"},"relatedIdentifiers":[{"relationType":"IsIdenticalTo","relatedIdentifier":"10.6084/m9.figshare.c.2040191","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":[],"formats":[],"version":null,"rightsList":[{"rights":"Creative Commons Attribution 4.0 International","rightsUri":"https://creativecommons.org/licenses/by/4.0/legalcode","schemeUri":"https://spdx.org/licenses/","rightsIdentifier":"cc-by-4.0","rightsIdentifierScheme":"SPDX"}],"descriptions":[{"description":"Hydrothermal reactions of CdSO\u003csub\u003e4\u003c/sub\u003e, 4-cyanopyridine, and sodium azide yield three metal coordination compounds via controlling the pH, [Cd\u003csub\u003e2\u003c/sub\u003e(4-ptz)(SO\u003csub\u003e4\u003c/sub\u003e)(OH)(H\u003csub\u003e2\u003c/sub\u003eO)\u003csub\u003e2\u003c/sub\u003e](H\u003csub\u003e2\u003c/sub\u003eO) (\u003cb\u003e1\u003c/b\u003e) [Cd\u003csub\u003e2\u003c/sub\u003e(4-ptz)(SO\u003csub\u003e4\u003c/sub\u003e)(OH)(H\u003csub\u003e2\u003c/sub\u003eO)]\u003csub\u003en\u003c/sub\u003e (\u003cb\u003e2\u003c/b\u003e), and known [Cd\u003csub\u003e2\u003c/sub\u003e(4-ptz)\u003csub\u003e2\u003c/sub\u003e(H\u003csub\u003e2\u003c/sub\u003eO)\u003csub\u003e4\u003c/sub\u003e](H\u003csub\u003e2\u003c/sub\u003eO)\u003csub\u003e2\u003c/sub\u003e (\u003cb\u003e3\u003c/b\u003e) (4-ptz = 5-(4-pyridyl)tetrazole). The \u003ci\u003ein situ\u003c/i\u003e [2 + 3] cycloaddition reaction of nitrile and azide in the presence of Cd(II) produces the multidentate 4-ptz in these compounds. X-ray diffraction results indicate that metal centers in \u003cb\u003e1\u003c/b\u003e are linked by 4-ptz\u003csup\u003e–\u003c/sup\u003e, , and OH\u003csup\u003e−\u003c/sup\u003e in their respective \u003ci\u003eμ\u003c/i\u003e\u003csub\u003e5\u003c/sub\u003e-, \u003ci\u003eμ\u003c/i\u003e\u003csub\u003e2\u003c/sub\u003e-, \u003ci\u003eμ\u003c/i\u003e\u003csub\u003e3\u003c/sub\u003e-bridging modes, forming a 3-D coordination polymer. For \u003cb\u003e2\u003c/b\u003e, although the same raw materials are used, the component anions are linked to Cd(II) centers in completely different ways, i.e. for 4-ptz\u003csup\u003e−\u003c/sup\u003e in \u003ci\u003eμ\u003c/i\u003e\u003csub\u003e3\u003c/sub\u003e−, in \u003ci\u003eμ\u003c/i\u003e\u003csub\u003e5\u003c/sub\u003e-, and OH\u003csup\u003e−\u003c/sup\u003e in \u003ci\u003eμ\u003c/i\u003e\u003csub\u003e3\u003c/sub\u003e-bridging modes, forming another 3-D coordination network. Thermal stabilities and photoluminescent properties of \u003cb\u003e1\u003c/b\u003e and \u003cb\u003e2\u003c/b\u003e have also been investigated.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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