{"data":{"id":"10.6084/m9.figshare.c.2035112.v1","type":"dois","attributes":{"doi":"10.6084/m9.figshare.c.2035112.v1","prefix":"10.6084","suffix":"m9.figshare.c.2035112.v1","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Yu, Shaofu","givenName":"Shaofu","familyName":"Yu","affiliation":[],"nameIdentifiers":[]},{"name":"Fu, Shuna","givenName":"Shuna","familyName":"Fu","affiliation":[],"nameIdentifiers":[]},{"name":"Liu, Bailian","givenName":"Bailian","familyName":"Liu","affiliation":[],"nameIdentifiers":[]},{"name":"Zhang, Ying","givenName":"Ying","familyName":"Zhang","affiliation":[],"nameIdentifiers":[]},{"name":"Zhou, Guangxiong","givenName":"Guangxiong","familyName":"Zhou","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Two new quercetin glycoside derivatives from the fruits of \u003ci\u003eGardenia jasminoides\u003c/i\u003e var. \u003ci\u003eradicans\u003c/i\u003e"}],"publisher":"Taylor \u0026 Francis","container":{},"publicationYear":2015,"subjects":[{"subject":"Infectious Diseases"},{"subject":"FOS: Health sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Science Policy"},{"subject":"Developmental Biology"},{"subject":"Biological Sciences"},{"subject":"Immunology"},{"subject":"FOS: Clinical medicine","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Sociology"},{"subject":"FOS: Sociology","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Ecology"},{"subject":"FOS: Biological sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Chemistry"},{"subject":"Earth and Environmental Sciences"},{"subject":"Molecular Biology"},{"subject":"Genetics"},{"subject":"Microbiology"},{"subject":"Biochemistry"}],"contributors":[],"dates":[{"date":"2015-12-05","dateType":"Created"},{"date":"2019-08-19","dateType":"Updated"},{"date":"2015","dateType":"Issued"}],"language":null,"types":{"ris":"GEN","bibtex":"misc","citeproc":"article","schemaOrg":"Collection","resourceType":"Collection","resourceTypeGeneral":"Collection"},"relatedIdentifiers":[{"relationType":"IsIdenticalTo","relatedIdentifier":"10.6084/m9.figshare.c.2035112","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":[],"formats":[],"version":null,"rightsList":[{"rights":"Creative Commons Attribution 4.0 International","rightsUri":"https://creativecommons.org/licenses/by/4.0/legalcode","schemeUri":"https://spdx.org/licenses/","rightsIdentifier":"cc-by-4.0","rightsIdentifierScheme":"SPDX"}],"descriptions":[{"description":"Two new quercetin glycoside derivatives named quercetin-3-\u003ci\u003eO\u003c/i\u003e-[2-\u003ci\u003eO\u003c/i\u003e-\u003ci\u003etrans\u003c/i\u003e-caffeoyl-α-l-rhamnopyranosyl-(1 → 6)-β-d-glucopyranoside] (\u003cb\u003e1\u003c/b\u003e) and quercetin-3-\u003ci\u003eO\u003c/i\u003e-[2-\u003ci\u003eO\u003c/i\u003e-\u003ci\u003etrans\u003c/i\u003e-caffeoyl-β-l-rhamnopyranosyl-(1 → 6)-β-d-glucopyranoside] (\u003cb\u003e2\u003c/b\u003e) along with three known flavonoids, 5-hydroxy-6,7,3′,4′,5′-pentamethoxyflavone (\u003cb\u003e3\u003c/b\u003e), 5,7-dihydroxy-8-methoxyflavone (\u003cb\u003e4\u003c/b\u003e) and kaempferol 3-\u003ci\u003eO\u003c/i\u003e-β-d-glucopyranoside (\u003cb\u003e5\u003c/b\u003e), were isolated from the fruits of \u003ci\u003eGardenia jasminoides\u003c/i\u003e var. \u003ci\u003eradicans\u003c/i\u003e. The structures of the new compounds were determined by means of extensive spectroscopic analysis (1D, 2D NMR and HR-ESI-MS), glycoside hydrolysis and sugar HPLC analysis after derivatisation. This is the first report on the isolation of a pair of compounds with α or β-l-rhamnopyranosyl configuration from plant and the first detail assignment of their NMR data.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"PD94bWwgdmVyc2lvbj0iMS4wIiBlbmNvZGluZz0iVVRGLTgiPz4KPHJlc291cmNlIHhtbG5zPSJodHRwOi8vZGF0YWNpdGUub3JnL3NjaGVtYS9rZXJuZWwtNCIgeG1sbnM6eHNpPSJodHRwOi8vd3d3LnczLm9yZy8yMDAxL1hNTFNjaGVtYS1pbnN0YW5jZSIgeHNpOnNjaGVtYUxvY2F0aW9uPSJodHRwOi8vZGF0YWNpdGUub3JnL3NjaGVtYS9rZXJuZWwtNCBodHRwOi8vc2NoZW1hLmRhdGFjaXRlLm9yZy9tZXRhL2tlcm5lbC00LjQvbWV0YWRhdGEueHNkIj4KICA8aWRlbnRpZmllciBpZGVudGlmaWVyVHlwZT0iRE9JIj4xMC42MDg0L005LkZJR1NIQVJFLkMuMjAzNTExMi5WMTwvaWRlbnRpZmllcj4KICA8Y3JlYXRvcnM+CiAgICA8Y3JlYXRvcj4KICAgICAgPGNyZWF0b3JOYW1lPlNoYW9mdSBZdTwvY3JlYXRvck5hbWU+CiAgICAgIDxnaXZlbk5hbWU+U2hhb2Z1PC9naXZlbk5hbWU+CiAgICAgIDxmYW1pbHlOYW1lPll1PC9mYW1pbHlOYW1lPgogICAgPC9jcmVhdG9yPgogICAgPGNyZWF0b3I+CiAgICAgIDxjcmVhdG9yTmFtZT5TaHVuYSBGdTwvY3JlYXRvck5hbWU+CiAgICAgIDxnaXZlbk5hbWU+U2h1bmE8L2dpdmVuTmFtZT4KICAgICAgPGZhbWlseU5hbWU+RnU8L2ZhbWlseU5hbWU+CiAgICA8L2NyZWF0b3I+CiAgICA8Y3JlYXRvcj4KICAgICAgPGNyZWF0b3JOYW1lPkJhaWxpYW4gTGl1PC9jcmVhdG9yTmFtZT4KICAgICAgPGdpdmVuTmFtZT5CYWlsaWFuPC9naXZlbk5hbWU+CiAgICAgIDxmYW1pbHlOYW1lPkxpdTwvZmFtaWx5TmFtZT4KICAgIDwvY3JlYXRvcj4KICAgIDxjcmVhdG9yPgogICAgICA8Y3JlYXRvck5hbWU+WWluZyBaaGFuZzwvY3JlYXRvck5hbWU+CiAgICAgIDxnaXZlbk5hbWU+WWluZzwvZ2l2ZW5OYW1lPgogICAgICA8ZmFtaWx5TmFtZT5aaGFuZzwvZmFtaWx5TmFtZT4KICAgIDwvY3JlYXRvcj4KICAgIDxjcmVhdG9yPgogICAgICA8Y3JlYXRvck5hbWU+R3Vhbmd4aW9uZyBaaG91PC9jcmVhdG9yTmFtZT4KICAgICAgPGdpdmVuTmFtZT5HdWFuZ3hpb25nPC9naXZlbk5hbWU+CiAgICAgIDxmYW1pbHlOYW1lPlpob3U8L2ZhbWlseU5hbWU+CiAgICA8L2NyZWF0b3I+CiAgPC9jcmVhdG9ycz4KICA8dGl0bGVzPgogICAgPHRpdGxlPlR3byBuZXcgcXVlcmNldGluIGdseWNvc2lkZSBkZXJpdmF0aXZlcyBmcm9tIHRoZSBmcnVpdHMgb2YgJmx0O2kmZ3Q7R2FyZGVuaWEgamFzbWlub2lkZXMmbHQ7L2kmZ3Q7IHZhci4gJmx0O2kmZ3Q7cmFkaWNhbnMmbHQ7L2kmZ3Q7PC90aXRsZT4KICA8L3RpdGxlcz4KICA8ZGVzY3JpcHRpb25zPgogICAgPGRlc2NyaXB0aW9uIGRlc2NyaXB0aW9uVHlwZT0iQWJzdHJhY3QiPiZsdDtkaXYmZ3Q7Jmx0O3AmZ3Q7VHdvIG5ldyBxdWVyY2V0aW4gZ2x5Y29zaWRlIGRlcml2YXRpdmVzIG5hbWVkIHF1ZXJjZXRpbi0zLSZsdDtpJmd0O08mbHQ7L2kmZ3Q7LVsyLSZsdDtpJmd0O08mbHQ7L2kmZ3Q7LSZsdDtpJmd0O3RyYW5zJmx0Oy9pJmd0Oy1jYWZmZW95bC3OsS1sLXJoYW1ub3B5cmFub3N5bC0oMcKg4oaSwqA2KS3Osi1kLWdsdWNvcHlyYW5vc2lkZV0gKCZsdDtiJmd0OzEmbHQ7L2ImZ3Q7KSBhbmQgcXVlcmNldGluLTMtJmx0O2kmZ3Q7TyZsdDsvaSZndDstWzItJmx0O2kmZ3Q7TyZsdDsvaSZndDstJmx0O2kmZ3Q7dHJhbnMmbHQ7L2kmZ3Q7LWNhZmZlb3lsLc6yLWwtcmhhbW5vcHlyYW5vc3lsLSgxwqDihpLCoDYpLc6yLWQtZ2x1Y29weXJhbm9zaWRlXSAoJmx0O2ImZ3Q7MiZsdDsvYiZndDspIGFsb25nIHdpdGggdGhyZWUga25vd24gZmxhdm9ub2lkcywgNS1oeWRyb3h5LTYsNywz4oCyLDTigLIsNeKAsi1wZW50YW1ldGhveHlmbGF2b25lICgmbHQ7YiZndDszJmx0Oy9iJmd0OyksIDUsNy1kaWh5ZHJveHktOC1tZXRob3h5Zmxhdm9uZSAoJmx0O2ImZ3Q7NCZsdDsvYiZndDspIGFuZCBrYWVtcGZlcm9sIDMtJmx0O2kmZ3Q7TyZsdDsvaSZndDstzrItZC1nbHVjb3B5cmFub3NpZGUgKCZsdDtiJmd0OzUmbHQ7L2ImZ3Q7KSwgd2VyZSBpc29sYXRlZCBmcm9tIHRoZSBmcnVpdHMgb2YgJmx0O2kmZ3Q7R2FyZGVuaWEgamFzbWlub2lkZXMmbHQ7L2kmZ3Q7IHZhci4gJmx0O2kmZ3Q7cmFkaWNhbnMmbHQ7L2kmZ3Q7LiBUaGUgc3RydWN0dXJlcyBvZiB0aGUgbmV3IGNvbXBvdW5kcyB3ZXJlIGRldGVybWluZWQgYnkgbWVhbnMgb2YgZXh0ZW5zaXZlIHNwZWN0cm9zY29waWMgYW5hbHlzaXMgKDFELCAyRCBOTVIgYW5kIEhSLUVTSS1NUyksIGdseWNvc2lkZSBoeWRyb2x5c2lzIGFuZCBzdWdhciBIUExDIGFuYWx5c2lzIGFmdGVyIGRlcml2YXRpc2F0aW9uLiBUaGlzIGlzIHRoZSBmaXJzdCByZXBvcnQgb24gdGhlIGlzb2xhdGlvbiBvZiBhIHBhaXIgb2YgY29tcG91bmRzIHdpdGggzrEgb3IgzrItbC1yaGFtbm9weXJhbm9zeWwgY29uZmlndXJhdGlvbiBmcm9tIHBsYW50IGFuZCB0aGUgZmlyc3QgZGV0YWlsIGFzc2lnbm1lbnQgb2YgdGhlaXIgTk1SIGRhdGEuJmx0Oy9wJmd0OyZsdDsvZGl2Jmd0OzwvZGVzY3JpcHRpb24+CiAgPC9kZXNjcmlwdGlvbnM+CiAgPHN1YmplY3RzPgogICAgPHN1YmplY3Q+SW5mZWN0aW91cyBEaXNlYXNlczwvc3ViamVjdD4KICAgIDxzdWJqZWN0PlNjaWVuY2UgUG9saWN5PC9zdWJqZWN0PgogICAgPHN1YmplY3Q+RGV2ZWxvcG1lbnRhbCBCaW9sb2d5PC9zdWJqZWN0PgogICAgPHN1YmplY3Q+QmlvbG9naWNhbCBTY2llbmNlczwvc3ViamVjdD4KICAgIDxzdWJqZWN0PkltbXVub2xvZ3k8L3N1YmplY3Q+CiAgICA8c3ViamVjdD5Tb2Npb2xvZ3k8L3N1YmplY3Q+CiAgICA8c3ViamVjdD5FY29sb2d5PC9zdWJqZWN0PgogICAgPHN1YmplY3Q+Q2hlbWlzdHJ5PC9zdWJqZWN0PgogICAgPHN1YmplY3Q+RWFydGggYW5kIEVudmlyb25tZW50YWwgU2NpZW5jZXM8L3N1YmplY3Q+CiAgICA8c3ViamVjdD5Nb2xlY3VsYXIgQmlvbG9neTwvc3ViamVjdD4KICAgIDxzdWJqZWN0PkdlbmV0aWNzPC9zdWJqZWN0PgogICAgPHN1YmplY3Q+TWljcm9iaW9sb2d5PC9zdWJqZWN0PgogICAgPHN1YmplY3Q+QmlvY2hlbWlzdHJ5PC9zdWJqZWN0PgogIDwvc3ViamVjdHM+CiAgPHB1Ymxpc2hlcj5UYXlsb3IgJmFtcDsgRnJhbmNpczwvcHVibGlzaGVyPgogIDxwdWJsaWNhdGlvblllYXI+MjAxNTwvcHVibGljYXRpb25ZZWFyPgogIDxkYXRlcz4KICAgIDxkYXRlIGRhdGVUeXBlPSJDcmVhdGVkIj4yMDE1LTEyLTA1PC9kYXRlPgogICAgPGRhdGUgZGF0ZVR5cGU9IlVwZGF0ZWQiPjIwMTktMDgtMTk8L2RhdGU+CiAgPC9kYXRlcz4KICA8cmVzb3VyY2VUeXBlIHJlc291cmNlVHlwZUdlbmVyYWw9IkNvbGxlY3Rpb24iPkNvbGxlY3Rpb248L3Jlc291cmNlVHlwZT4KICA8cmVsYXRlZElkZW50aWZpZXJzPgogICAgPHJlbGF0ZWRJZGVudGlmaWVyIHJlbGF0ZWRJZGVudGlmaWVyVHlwZT0iRE9JIiByZWxhdGlvblR5cGU9IklzSWRlbnRpY2FsVG8iPjEwLjYwODQvbTkuZmlnc2hhcmUuYy4yMDM1MTEyPC9yZWxhdGVkSWRlbnRpZmllcj4KICA8L3JlbGF0ZWRJZGVudGlmaWVycz4KICA8cmlnaHRzTGlzdD4KICAgIDxyaWdodHMgcmlnaHRzVVJJPSJodHRwczovL2NyZWF0aXZlY29tbW9ucy5vcmcvbGljZW5zZXMvYnkvNC4wLyI+Q0MgQlkgNC4wPC9yaWdodHM+CiAgPC9yaWdodHNMaXN0Pgo8L3Jlc291cmNlPg==","url":"https://tandf.figshare.com/collections/Two_new_quercetin_glycoside_deriva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