{"data":{"id":"10.6084/m9.figshare.c.1957199","type":"dois","attributes":{"doi":"10.6084/m9.figshare.c.1957199","prefix":"10.6084","suffix":"m9.figshare.c.1957199","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Vaughan Griffiths, D.","givenName":"D.","familyName":"Vaughan Griffiths","affiliation":[],"nameIdentifiers":[]},{"name":"M. Benoit, David","givenName":"David","familyName":"M. Benoit","affiliation":[],"nameIdentifiers":[]},{"name":"Cheong, Yuen-Ki","givenName":"Yuen-Ki","familyName":"Cheong","affiliation":[],"nameIdentifiers":[]},{"name":"Duncanson, Philip","givenName":"Philip","familyName":"Duncanson","affiliation":[],"nameIdentifiers":[]},{"name":"Han, Xiao","givenName":"Xiao","familyName":"Han","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Novel Ylidic Phosphoryl Compounds from Halogenated Furan-2,5-Diones with Trivalent Phosphorus Esters: Application of this Approach to New Trisphosphonates Containing a Geminal Bisphosphonate Unit"}],"publisher":"Taylor \u0026 Francis","container":{},"publicationYear":2015,"subjects":[{"subject":"Plant Biology"},{"subject":"FOS: Biological sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Developmental Biology"},{"subject":"Mathematics"},{"subject":"FOS: Mathematics","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Biological Sciences"},{"subject":"Ecology"},{"subject":"Chemistry"},{"subject":"Earth and Environmental Sciences"},{"subject":"Evolutionary Biology"},{"subject":"Pharmacology"},{"subject":"Microbiology"},{"subject":"Biochemistry"},{"subject":"Biophysics"}],"contributors":[],"dates":[{"date":"2015-12-05","dateType":"Created"},{"date":"2019-08-19","dateType":"Updated"},{"date":"2015","dateType":"Issued"}],"language":null,"types":{"ris":"GEN","bibtex":"misc","citeproc":"article","schemaOrg":"Collection","resourceType":"Collection","resourceTypeGeneral":"Collection"},"relatedIdentifiers":[],"relatedItems":[],"sizes":[],"formats":[],"version":null,"rightsList":[{"rights":"Creative Commons Attribution 4.0 International","rightsUri":"https://creativecommons.org/licenses/by/4.0/legalcode","schemeUri":"https://spdx.org/licenses/","rightsIdentifier":"cc-by-4.0","rightsIdentifierScheme":"SPDX"}],"descriptions":[{"description":"The reactions of trivalent phosphorus esters, including trialkyl phosphites, dialkyl phosphonites, and alkyl phosphinites, with 3-halo- and 3,4-dihalo-furan-2,5-diones has been shown to lead to the formation of novel phosphorus ylides possessing additional phosphoryl-containing groups. For the reaction of 3,4-dihalo-furan-2,5-diones with trialkyl phosphites, the products are trialkoxyphosphonium ylides containing an adjacent geminal bisphosphonate unit. These can be used to provide a convenient route to novel 2,3,3-tris(dialkoxyphosphoryl)-substituted propionate esters which can be hydrolyzed to give the corresponding novel trisphosphonic monocarboxylic acid.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"PD94bWwgdmVyc2lvbj0iMS4wIiBlbmNvZGluZz0iVVRGLTgiPz4KPHJlc291cmNlIHhtbG5zPSJodHRwOi8vZGF0YWNpdGUub3JnL3NjaGVtYS9rZXJuZWwtNCIgeG1sbnM6eHNpPSJodHRwOi8vd3d3LnczLm9yZy8yMDAxL1hNTFNjaGVtYS1pbnN0YW5jZSIgeHNpOnNjaGVtYUxvY2F0aW9uPSJodHRwOi8vZGF0YWNpdGUub3JnL3NjaGVtYS9rZXJuZWwtNCBodHRwOi8vc2NoZW1hLmRhdGFjaXRlLm9yZy9tZXRhL2tlcm5lbC00LjQvbWV0YWRhdGEueHNkIj4KICA8aWRlbnRpZmllciBpZGVudGlmaWVyVHlwZT0iRE9JIj4xMC42MDg0L005LkZJR1NIQVJFLkMuMTk1NzE5OTwvaWRlbnRpZmllcj4KICA8Y3JlYXRvcnM+CiAgICA8Y3JlYXRvcj4KICAgICAgPGNyZWF0b3JOYW1lPkQuIFZhdWdoYW4gR3JpZmZpdGhzPC9jcmVhdG9yTmFtZT4KICAgICAgPGdpdmVuTmFtZT5ELjwvZ2l2ZW5OYW1lPgogICAgICA8ZmFtaWx5TmFtZT5WYXVnaGFuIEdyaWZmaXRoczwvZmFtaWx5TmFtZT4KICAgIDwvY3JlYXRvcj4KICAgIDxjcmVhdG9yPgogICAgICA8Y3JlYXRvck5hbWU+RGF2aWQgTS4gQmVub2l0PC9jcmVhdG9yTmFtZT4KICAgICAgPGdpdmVuTmFtZT5EYXZpZDwvZ2l2ZW5OYW1lPgogICAgICA8ZmFtaWx5TmFtZT5NLiBCZW5vaXQ8L2ZhbWlseU5hbWU+CiAgICA8L2NyZWF0b3I+CiAgICA8Y3JlYXRvcj4KICAgICAgPGNyZWF0b3JOYW1lPll1ZW4tS2kgQ2hlb25nPC9jcmVhdG9yTmFtZT4KICAgICAgPGdpdmVuTmFtZT5ZdWVuLUtpPC9naXZlbk5hbWU+CiAgICAgIDxmYW1pbHlOYW1lPkNoZW9uZzwvZmFtaWx5TmFtZT4KICAgIDwvY3JlYXRvcj4KICAgIDxjcmVhdG9yPgogICAgICA8Y3JlYXRvck5hbWU+UGhpbGlwIER1bmNhbnNvbjwvY3JlYXRvck5hbWU+CiAgICAgIDxnaXZlbk5hbWU+UGhpbGlwPC9naXZlbk5hbWU+CiAgICAgIDxmYW1pbHlOYW1lPkR1bmNhbnNvbjwvZmFtaWx5TmFtZT4KICAgIDwvY3JlYXRvcj4KICAgIDxjcmVhdG9yPgogICAgICA8Y3JlYXRvck5hbWU+WGlhbyBIYW48L2NyZWF0b3JOYW1lPgogICAgICA8Z2l2ZW5OYW1lPlhpYW88L2dpdmVuTmFtZT4KICAgICAgPGZhbWlseU5hbWU+SGFuPC9mYW1pbHlOYW1lPgogICAgPC9jcmVhdG9yPgogIDwvY3JlYXRvcnM+CiAgPHRpdGxlcz4KICAgIDx0aXRsZT5Ob3ZlbCBZbGlkaWMgUGhvc3Bob3J5bCBDb21wb3VuZHMgZnJvbSBIYWxvZ2VuYXRlZCBGdXJhbi0yLDUtRGlvbmVzIHdpdGggVHJpdmFsZW50IFBob3NwaG9ydXMgRXN0ZXJzOiBBcHBsaWNhdGlvbiBvZiB0aGlzIEFwcHJvYWNoIHRvIE5ldyBUcmlzcGhvc3Bob25hdGVzIENvbnRhaW5pbmcgYSBHZW1pbmFsIEJpc3Bob3NwaG9uYXRlIFVuaXQ8L3RpdGxlPgogIDwvdGl0bGVzPgogIDxkZXNjcmlwdGlvbnM+CiAgICA8ZGVzY3JpcHRpb24gZGVzY3JpcHRpb25UeXBlPSJBYnN0cmFjdCI+Jmx0O2RpdiZndDsmbHQ7cCZndDsmbHQ7L3AmZ3Q7Jmx0O3AmZ3Q7VGhlIHJlYWN0aW9ucyBvZiB0cml2YWxlbnQgcGhvc3Bob3J1cyBlc3RlcnMsIGluY2x1ZGluZyB0cmlhbGt5bCBwaG9zcGhpdGVzLCBkaWFsa3lsIHBob3NwaG9uaXRlcywgYW5kIGFsa3lsIHBob3NwaGluaXRlcywgd2l0aCAzLWhhbG8tIGFuZCAzLDQtZGloYWxvLWZ1cmFuLTIsNS1kaW9uZXMgaGFzIGJlZW4gc2hvd24gdG8gbGVhZCB0byB0aGUgZm9ybWF0aW9uIG9mIG5vdmVsIHBob3NwaG9ydXMgeWxpZGVzIHBvc3Nlc3NpbmcgYWRkaXRpb25hbCBwaG9zcGhvcnlsLWNvbnRhaW5pbmcgZ3JvdXBzLiBGb3IgdGhlIHJlYWN0aW9uIG9mIDMsNC1kaWhhbG8tZnVyYW4tMiw1LWRpb25lcyB3aXRoIHRyaWFsa3lsIHBob3NwaGl0ZXMsIHRoZSBwcm9kdWN0cyBhcmUgdHJpYWxrb3h5cGhvc3Bob25pdW0geWxpZGVzIGNvbnRhaW5pbmcgYW4gYWRqYWNlbnQgZ2VtaW5hbCBiaXNwaG9zcGhvbmF0ZSB1bml0LiBUaGVzZSBjYW4gYmUgdXNlZCB0byBwcm92aWRlIGEgY29udmVuaWVudCByb3V0ZSB0byBub3ZlbCAyLDMsMy10cmlzKGRpYWxrb3h5cGhvc3Bob3J5bCktc3Vic3RpdHV0ZWQgcHJvcGlvbmF0ZSBlc3RlcnMgd2hpY2ggY2FuIGJlIGh5ZHJvbHl6ZWQgdG8gZ2l2ZSB0aGUgY29ycmVzcG9uZGluZyBub3ZlbCB0cmlzcGhvc3Bob25pYyBtb25vY2FyYm94eWxpYyBhY2lkLiZsdDsvcCZndDsmbHQ7L2RpdiZndDs8L2Rlc2NyaXB0aW9uPgogIDwvZGVzY3JpcHRpb25zPgogIDxzdWJqZWN0cz4KICAgIDxzdWJqZWN0PlBsYW50IEJpb2xvZ3k8L3N1YmplY3Q+CiAgICA8c3ViamVjdD5EZXZlbG9wbWVudGFsIEJpb2xvZ3k8L3N1YmplY3Q+CiAgICA8c3ViamVjdD5NYXRoZW1hdGljczwvc3ViamVjdD4KICAgIDxzdWJqZWN0PkJpb2xvZ2ljYWwgU2NpZW5jZXM8L3N1YmplY3Q+CiAgICA8c3ViamVjdD5FY29sb2d5PC9zdWJqZWN0PgogICAgPHN1YmplY3Q+Q2hlbWlzdHJ5PC9zdWJqZWN0PgogICAgPHN1YmplY3Q+RWFydGggYW5kIEVudmlyb25tZW50YWwgU2NpZW5jZXM8L3N1YmplY3Q+CiAgICA8c3ViamVjdD5Fdm9sdXRpb25hcnkgQmlvbG9neTwvc3ViamVjdD4KICAgIDxzdWJqZWN0PlBoYXJtYWNvbG9neTwvc3ViamVjdD4KICAgIDxzdWJqZWN0Pk1pY3JvYmlvbG9neTwvc3ViamVjdD4KICAgIDxzdWJqZWN0PkJpb2NoZW1pc3RyeTwvc3ViamVjdD4KICAgIDxzdWJqZWN0PkJpb3BoeXNpY3M8L3N1YmplY3Q+CiAgPC9zdWJqZWN0cz4KICA8cHVibGlzaGVyPlRheWxvciAmYW1wOyBGcmFuY2lzPC9wdWJsaXNoZXI+CiAgPHB1YmxpY2F0aW9uWWVhcj4yMDE1PC9wdWJsaWNhdGlvblllYXI+CiAgPGRhdGVzPgogICAgPGRhdGUgZGF0ZVR5cGU9IkNyZWF0ZWQiPjIwMTUtMTItMDU8L2RhdGU+CiAgICA8ZGF0ZSBkYXRlVHlwZT0iVXBkYXRlZCI+MjAxOS0wOC0xOTwvZGF0ZT4KICA8L2RhdGVzPgogIDxyZXNvdXJjZVR5cGUgcmVzb3VyY2VUeXBlR2VuZXJhbD0iQ29sbGVjdGlvbiI+Q29sbGVjdGlvbjwvcmVzb3VyY2VUeXBlPgogIDxyaWdodHNMaXN0PgogICAgPHJpZ2h0cyByaWdodHNVUkk9Imh0dHBzOi8vY3JlYXRpdmVjb21tb25zLm9yZy9saWNlbnNlcy9ieS80LjAvIj5DQyBCWSA0LjA8L3JpZ2h0cz4KICA8L3JpZ2h0c0xpc3Q+CjwvcmVzb3VyY2U+","url":"https://tandf.figshare.com/collections/Novel_Ylidic_Phosphoryl_Compounds_from_Halogenated_Furan_2_5_Diones_with_Trivalent_Phosphorus_Esters_Application_of_this_Approach_to_New_Trisphosphonates_Containing_a_Geminal_Bisphosphonate_Unit/1957199","contentUrl":null,"metadataVersion":2,"schemaVersion":"http://datacite.org/schema/kernel-4","source":"mds","isActive":true,"state":"findable","reason":null,"viewCount":0,"viewsOverTime":[],"downloadCount":0,"downloadsOverTime":[],"referenceCount":0,"citationCount":0,"citationsOverTime":[],"partCount":0,"partOfCount":0,"versionCount":0,"versionOfCount":0,"created":"2015-12-05T14:52:38.000Z","registered":"2015-12-05T14:52:39.000Z","published":"2015","updated":"2024-03-21T08:25:49.000Z"},"relationships":{"client":{"data":{"id":"figshar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