{"data":{"id":"10.6084/m9.figshare.977921.v2","type":"dois","attributes":{"doi":"10.6084/m9.figshare.977921.v2","prefix":"10.6084","suffix":"m9.figshare.977921.v2","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Ren, Hai-Yun","nameType":"Personal","givenName":"Hai-Yun","familyName":"Ren","affiliation":[],"nameIdentifiers":[]},{"name":"Ning, Zhi-Xue","nameType":"Personal","givenName":"Zhi-Xue","familyName":"Ning","affiliation":[],"nameIdentifiers":[]},{"name":"Hou, Juan-Juan","nameType":"Personal","givenName":"Juan-Juan","familyName":"Hou","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Ultrasound and solvent-induced reversible chromism in a luminescent chalcogenidostannate"}],"publisher":"Taylor \u0026 Francis","container":{},"publicationYear":2014,"subjects":[{"subject":"Biophysics"},{"subject":"Biochemistry"},{"subject":"Space Science"},{"subject":"29999 Physical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Physical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Physical sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Medicine"},{"subject":"Cell Biology"},{"subject":"Molecular Biology"},{"subject":"Physiology"},{"subject":"FOS: Biological sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Biological sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"39999 Chemical Sciences not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Chemical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Chemical sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Ecology"},{"subject":"Marine Biology"},{"subject":"Cancer"},{"subject":"Plant Biology"}],"contributors":[],"dates":[{"date":"2014-04-30","dateType":"Created"},{"date":"2017-10-30","dateType":"Updated"},{"date":"2014","dateType":"Issued"}],"language":null,"types":{"ris":"DATA","bibtex":"misc","citeproc":"dataset","schemaOrg":"Dataset","resourceType":"Dataset","resourceTypeGeneral":"Dataset"},"relatedIdentifiers":[{"relationType":"IsSupplementTo","relatedIdentifier":"10.1080/00958972.2014.901505","relatedIdentifierType":"DOI"},{"relationType":"IsIdenticalTo","relatedIdentifier":"10.6084/m9.figshare.977921","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":["25280258 Bytes"],"formats":[],"version":null,"rightsList":[{"rights":"Creative Commons Attribution 4.0 International","rightsUri":"https://creativecommons.org/licenses/by/4.0/legalcode","schemeUri":"https://spdx.org/licenses/","rightsIdentifier":"cc-by-4.0","rightsIdentifierScheme":"SPDX"}],"descriptions":[{"description":"Solvothermal treatment of a mixture of Se, SnC1\u003csub\u003e2\u003c/sub\u003e, CoC1\u003csub\u003e2\u003c/sub\u003e, and dien (dien = diethylenetriamine) generated yellow crystals of [Co(dien)\u003csub\u003e2\u003c/sub\u003e]\u003csub\u003e2\u003c/sub\u003eSn\u003csub\u003e2\u003c/sub\u003eSe\u003csub\u003e6\u003c/sub\u003e (\u003cb\u003e1\u003c/b\u003e), which could transform into black \u003cb\u003e2\u003c/b\u003e with the same formula via rinsing with water. In the presence of water, ultrasound irradiation of black \u003cb\u003e2\u003c/b\u003e went back to yellow \u003cb\u003e1\u003c/b\u003e. The reversible ultrasound and solvent-induced chromism has never been observed before. Compared with yellow \u003cb\u003e1\u003c/b\u003e, hyperchromism was apparent around 550 nm in the visible absorption spectrum of \u003cb\u003e2\u003c/b\u003e. The fluorescent properties for \u003cb\u003e1\u003c/b\u003e and \u003cb\u003e2\u003c/b\u003e were investigated and the mechanisms were validated by density functional theory calculations on the experimental geometries. In addition, electron paramagnetic resonance spectra of yellow \u003cb\u003e1\u003c/b\u003e are similar to chromic black \u003cb\u003e2\u003c/b\u003e in the signal at \u003ci\u003eg\u003c/i\u003e = 4.22 and \u003ci\u003eg\u003c/i\u003e = 2.19; the signal at \u003ci\u003eg\u003c/i\u003e = 2.19 of \u003cb\u003e2\u003c/b\u003e shows a sharp increase.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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","url":"https://tandf.figshare.com/articles/datas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