{"data":{"id":"10.6084/m9.figshare.833331.v1","type":"dois","attributes":{"doi":"10.6084/m9.figshare.833331.v1","prefix":"10.6084","suffix":"m9.figshare.833331.v1","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Shufeng Zhang","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"熵：一个不是物理量的概念"}],"publisher":"figshare","container":{},"publicationYear":2013,"subjects":[{"subject":"Condensed Matter Physics"},{"subject":"FOS: Physical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Physical sciences","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"Environmental Chemistry"},{"subject":"Mechanics"},{"subject":"Geochemistry"},{"subject":"FOS: Earth and related environmental sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Earth and related environmental 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Physics"}],"contributors":[],"dates":[{"date":"2013-10-28","dateType":"Created"},{"date":"2016-01-18","dateType":"Updated"},{"date":"2013","dateType":"Issued"}],"language":null,"types":{"ris":"DATA","bibtex":"misc","citeproc":"dataset","schemaOrg":"Dataset","resourceType":"Dataset","resourceTypeGeneral":"Dataset"},"relatedIdentifiers":[{"relationType":"IsIdenticalTo","relatedIdentifier":"10.6084/m9.figshare.833331","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":["0 Bytes"],"formats":[],"version":null,"rightsList":[{"rights":"Creative Commons Attribution 4.0 International","rightsUri":"https://creativecommons.org/licenses/by/4.0/legalcode","schemeUri":"https://spdx.org/licenses/","rightsIdentifier":"cc-by-4.0","rightsIdentifierScheme":"SPDX"}],"descriptions":[{"description":"论文《熵：一个不是物理量的概念》的英文版《Entropy : A concept that is not a physical quantity》已发表在国际期刊Physics Essays [物理文集] [2012年（总25卷）第2期] 上。 英文版（原文）下载网址： http://blog.sciencenet.cn/home.php?mod=space\u0026amp;uid=543672 熵：一个不是物理量的概念 张 树 风 中南大学物理学院 Email: uhsgnahz@126.com 摘 要 论证了“熵”不是物理量，即，不存在所谓的“熵”这个物理量。 当定义热机效率为:η= W/ W1 ,令元可逆循环为TV循环（即斯特令（stirling）循环），如果 ∮dQ/T =0 成立，我们可以证明 ∮dW/T =0,∮dE/T =0 同样成立。 如果认为∮dQ/T=0, ∮dW/T=0 和∮dE/T=0 定义了新的系统状态量，就显示出这样的定义应该是荒谬的。 “熵”的根本错误在于，任意可逆过程中多方过程函数Q不是T的单值函数，P-V图应该是P-V-T图，∑[(ΔQ)/T)] 写为∫dQ/T这关键一步是不成立的，即，∮dQ/T=0不成立。同样，∮dW/T=0 和 ∮dE/T=0 也都不成立。 由于玻尔兹曼所的绝对“熵”是用来解释克劳修斯“熵”的，玻尔兹曼“熵”的单位（J/K）也是从克劳修斯“熵”移植来的，克劳修斯“熵”不存在也就同时否定了玻尔兹曼“熵”。 关键词：熵、热力学、统计物理学","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"PD94bWwgdmVyc2lvbj0iMS4wIiBlbmNvZGluZz0iVVRGLTgiPz4KPHJlc291cmNlIHhtbG5zPSJodHRwOi8vZGF0YWNpdGUub3JnL3NjaGVtYS9rZXJuZWwtNCIgeG1sbnM6eHNpPSJodHRwOi8vd3d3LnczLm9yZy8yMDAxL1hNTFNjaGVtYS1pbnN0YW5jZSIgeHNpOnNjaGVtYUxvY2F0aW9uPSJodHRwOi8vZGF0YWNpdGUub3JnL3NjaGVtYS9rZXJuZWwtNCBodHRwOi8vc2NoZW1hLmRhdGFjaXRlLm9yZy9tZXRhL2tlcm5lbC00LjEvbWV0YWRhdGEueHNkIj4KICA8aWRlbnRpZmllciBpZGVudGlmaWVyVHlwZT0iRE9JIj4xMC42MDg0L005LkZJR1NIQVJFLjgzMzMzMS5WMTwvaWRlbnRpZmllcj4KICA8Y3JlYXRvcnM+CiAgICA8Y3JlYXRvcj4KICAgICAgPGNyZWF0b3JOYW1lPlNodWZlbmcgWmhhbmc8L2NyZWF0b3JOYW1lPgogICAgPC9jcmVhdG9yPgogIDwvY3JlYXRvcnM+CiAgPHRpdGxlcz4KICAgIDx0aXRsZT7nhrXvvJrkuIDkuKrkuI3mmK/niannkIbph4/nmoTmpoLlv7U8L3RpdGxlPgogIDwvdGl0bGVzPgogIDxkZXNjcmlwdGlvbnM+CiAgICA8ZGVzY3JpcHRpb24gZGVzY3JpcHRpb25UeXBlPSJBYnN0cmFjdCI+Jmx0O3AmZ3Q76K665paH44CK54a177ya5LiA5Liq5LiN5piv54mp55CG6YeP55qE5qaC5b+144CL55qE6Iux5paH54mI44CKRW50cm9weSA6IEEgY29uY2VwdCB0aGF0IGlzIG5vdCBhIHBoeXNpY2FsIHF1YW50aXR544CL5bey5Y+R6KGo5Zyo5Zu96ZmF5pyf5YiKUGh5c2ljcyBFc3NheXMgW+eJqeeQhuaWh+mbhl0gWzIwMTLlubTvvIjmgLsyNeWNt++8ieesrDLmnJ9dIOS4iuOAgiZsdDsvcCZndDsKJmx0O3AmZ3Q7wqAmbHQ7L3AmZ3Q7CiZsdDtwJmd0O+iLseaWh+eJiO+8iOWOn+aWh++8ieS4i+i9vee9keWdgO+8miZsdDsvcCZndDsKJmx0O3AmZ3Q7aHR0cDovL2Jsb2cuc2NpZW5jZW5ldC5jbi9ob21lLnBocD9tb2Q9c3BhY2UmYW1wO3VpZD01NDM2NzImbHQ7L3AmZ3Q7CiZsdDtwJmd0O8KgJmx0Oy9wJmd0OwombHQ7cCZndDvnhrXvvJrkuIDkuKrkuI3mmK/niannkIbph4/nmoTmpoLlv7UmbHQ7L3AmZ3Q7CiZsdDtwJmd0O+W8oCDmoJEg6aOOJmx0Oy9wJmd0OwombHQ7cCZndDvkuK3ljZflpKflrabniannkIblrabpmaImbHQ7L3AmZ3Q7CiZsdDtwJmd0O0VtYWlsOiB1aHNnbmFoekAxMjYuY29tJmx0Oy9wJmd0OwombHQ7cCZndDvmkZgg6KaBJmx0Oy9wJmd0OwombHQ7cCZndDvorrror4HkuobigJznhrXigJ3kuI3mmK/niannkIbph4/vvIzljbPvvIzkuI3lrZjlnKjmiYDosJPnmoTigJznhrXigJ3ov5nkuKrniannkIbph4/jgIImbHQ7L3AmZ3Q7CiZsdDtwJmd0O+W9k+WumuS5ieeDreacuuaViOeOh+S4ujrOtz0gVy8gVzEgLOS7pOWFg+WPr+mAhuW+queOr+S4ulRW5b6q546v77yI5Y2z5pav54m55Luk77yIc3RpcmxpbmfvvInlvqrnjq/vvInvvIzlpoLmnpwg4oiuZFEvVCA9MCDmiJDnq4vvvIzmiJHku6zlj6/ku6Xor4HmmI4g4oiuZFcvVCA9MCziiK5kRS9UID0wIOWQjOagt+aIkOeri+OAgiZsdDsvcCZndDsKJmx0O3AmZ3Q75aaC5p6c6K6k5Li64oiuZFEvVD0wLCDiiK5kVy9UPTAg5ZKM4oiuZEUvVD0wIOWumuS5ieS6huaWsOeahOezu+e7n+eKtuaAgemHj++8jOWwseaYvuekuuWHuui/meagt+eahOWumuS5ieW6lOivpeaYr+iNkuiwrOeahOOAgiZsdDsvcCZndDsKJmx0O3AmZ3Q74oCc54a14oCd55qE5qC55pys6ZSZ6K+v5Zyo5LqO77yM5Lu75oSP5Y+v6YCG6L+H56iL5Lit5aSa5pa56L+H56iL5Ye95pWwUeS4jeaYr1TnmoTljZXlgLzlh73mlbDvvIxQLVblm77lupTor6XmmK9QLVYtVOWbvu+8jOKIkVsozpRRKS9UKV0g5YaZ5Li64oirZFEvVOi/meWFs+mUruS4gOatpeaYr+S4jeaIkOeri+eahO+8jOWNs++8jOKIrmRRL1Q9MOS4jeaIkOeri+OAguWQjOagt++8jOKIrmRXL1Q9MCDlkowg4oiuZEUvVD0wIOS5n+mDveS4jeaIkOeri+OAgiZsdDsvcCZndDsKJmx0O3AmZ3Q755Sx5LqO54675bCU5YW55pu85omA55qE57ud5a+54oCc54a14oCd5piv55So5p2l6Kej6YeK5YWL5Yqz5L+u5pav4oCc54a14oCd55qE77yM54675bCU5YW55pu84oCc54a14oCd55qE5Y2V5L2N77yISi9L77yJ5Lmf5piv5LuO5YWL5Yqz5L+u5pav4oCc54a14oCd56e75qSN5p2l55qE77yM5YWL5Yqz5L+u5pav4oCc54a14oCd5LiN5a2Y5Zyo5Lmf5bCx5ZCM5pe25ZCm5a6a5LqG54675bCU5YW55pu84oCc54a14oCd44CCJmx0Oy9wJmd0OwombHQ7cCZndDvlhbPplK7or43vvJrnhrXjgIHng63lipvlrabjgIHnu5/orqHniannkIblraYmbHQ7L3AmZ3Q7PC9kZXNjcmlwdGlvbj4KICA8L2Rlc2NyaXB0aW9ucz4KICA8c3ViamVjdHM+CiAgICA8c3ViamVjdD5Db25kZW5zZWQgTWF0dGVyIFBoeXNpY3M8L3N1YmplY3Q+CiAgICA8c3ViamVjdD5FbnZpcm9ubWVudGFsIENoZW1pc3RyeTwvc3ViamVjdD4KICAgIDxzdWJqZWN0Pk1lY2hhbmljczwvc3ViamVjdD4KICAgIDxzdWJqZWN0Pkdlb2NoZW1pc3RyeTwvc3ViamVjdD4KICAgIDxzdWJqZWN0PlN1cHJhbW9sZWN1bGFyIENoZW1pc3RyeTwvc3ViamVjdD4KICAgIDxzdWJqZWN0Pk9yZ2FuaWMgQ2hlbWlzdHJ5PC9zdWJqZWN0PgogICAgPHN1YmplY3Qgc2NoZW1lVVJJPSJodHRwOi8vd3d3LmFicy5nb3YuYXUvYXVzc3RhdHMvYWJzQC5uc2YvMC82QkI0MjdBQjk2OTZDMjI1Q0EyNTc0MTgwMDA0NDYzRSIgc3ViamVjdFNjaGVtZT0iRk9SIj4yMDEwNCBHYWxhY3RpYyBBc3Ryb25vbXk8L3N1YmplY3Q+CiAgICA8c3ViamVjdD5Db3Ntb2xvZ3k8L3N1YmplY3Q+CiAgICA8c3ViamVjdD5QbGFuZXRhcnkgR2VvbG9neTwvc3ViamVjdD4KICAgIDxzdWJqZWN0PlN0ZWxsYXIgQXN0cm9ub215PC9zdWJqZWN0PgogICAgPHN1YmplY3Q+QXN0cm9waHlzaWNzPC9zdWJqZWN0PgogICAgPHN1YmplY3Q+UGxhbmV0YXJ5IFNjaWVuY2U8L3N1YmplY3Q+CiAgICA8c3ViamVjdD5BcHBsaWVkIFBoeXNpY3M8L3N1YmplY3Q+CiAgICA8c3ViamVjdD5Nb2xlY3VsYXIgUGh5c2ljczwvc3ViamVjdD4KICAgIDxzdWJqZWN0Pk51Y2xlYXIgQ2hlbWlzdHJ5PC9zdWJqZWN0PgogICAgPHN1YmplY3Q+UmFkaW9jaGVtaXN0cnk8L3N1YmplY3Q+CiAgICA8c3ViamVjdD5Db21wdXRhdGlvbmFsIFBoeXNpY3M8L3N1YmplY3Q+CiAgICA8c3ViamVjdD5BdG9taWMgUGh5c2ljczwvc3ViamVjdD4KICAgIDxzdWJqZWN0PlNwZWNpYWwgUmVsYXRpdml0eTwvc3ViamVjdD4KICAgIDxzdWJqZWN0PkNvbXB1dGF0aW9uYWwgQ2hlbWlzdHJ5PC9zdWJqZWN0PgogICAgPHN1YmplY3Q+QmlvY2hlbWlzdHJ5PC9zdWJqZWN0PgogICAgPHN1YmplY3Q+U3RlcmVvY2hlbWlzdHJ5PC9zdWJqZWN0PgogICAgPHN1YmplY3Q+R2VuZXJhbCBSZWxhdGl2aXR5PC9zdWJqZWN0PgogICAgPHN1YmplY3Q+TS1UaGVvcnk8L3N1YmplY3Q+CiAgICA8c3ViamVjdD5Jbm9yZ2FuaWMgQ2hlbWlzdHJ5PC9zdWJqZWN0PgogICAgPHN1YmplY3Qgc2NoZW1lVVJJPSJodHRwOi8vd3d3LmFicy5nb3YuYXUvYXVzc3RhdHMvYWJzQC5uc2YvMC82QkI0MjdBQjk2OTZDMjI1Q0EyNTc0MTgwMDA0NDYzRSIgc3ViamVjdFNjaGVtZT0iRk9SIj4yMDIwMyBQYXJ0aWNsZSBQaHlzaWNzPC9zdWJqZWN0PgogICAgPHN1YmplY3Q+Q3J5c3RhbGxvZ3JhcGh5PC9zdWJqZWN0PgogICAgPHN1YmplY3Q+Tk1SIFNwZWN0cm9zY29weTwvc3ViamVjdD4KICAgIDxzdWJqZWN0PkNoZW1p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