{"data":{"id":"10.6084/m9.figshare.825559","type":"dois","attributes":{"doi":"10.6084/m9.figshare.825559","prefix":"10.6084","suffix":"m9.figshare.825559","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"J. Blesa","affiliation":[],"nameIdentifiers":[]},{"name":"R. Marín","affiliation":[],"nameIdentifiers":[]},{"name":"C.M. Lino","affiliation":[],"nameIdentifiers":[]},{"name":"J. Mañes","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Evaluation of enniatins A, A1, B, B1 and beauvericin in Portuguese cereal-based foods"}],"publisher":"Taylor \u0026 Francis","container":{},"publicationYear":2012,"subjects":[{"subject":"Microbiology"},{"subject":"FOS: Biological sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Biological sciences","subjectScheme":"Fields of Science and Technology (FOS)"}],"contributors":[],"dates":[{"date":"2013-10-17","dateType":"Created"},{"date":"2013-10-21","dateType":"Updated"},{"date":"2012","dateType":"Issued"}],"language":null,"types":{"ris":"DATA","bibtex":"misc","citeproc":"dataset","schemaOrg":"Dataset","resourceType":"Dataset","resourceTypeGeneral":"Dataset"},"relatedIdentifiers":[{"relationType":"IsSupplementTo","relatedIdentifier":"10.1080/19440049.2012.702929","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":["307374 Bytes"],"formats":[],"version":null,"rightsList":[{"rights":"Creative Commons Attribution 4.0 International","rightsUri":"https://creativecommons.org/licenses/by/4.0/legalcode","schemeUri":"https://spdx.org/licenses/","rightsIdentifier":"cc-by-4.0","rightsIdentifierScheme":"SPDX"}],"descriptions":[{"description":"Sixty-one samples of Portuguese cereal-based foods were analysed for the occurrence of emerging mycotoxins called enniatins (A, A1, B and B1) and beauvericin. Samples were extracted with a mixture of acetonitrile/water (85/15, v/v) using an Ultra-Turrax homogeniser, and mycotoxins were detected with liquid chromatography coupled to a mass spectrometer. This method was validated and adequate values of recovery (70–103%) and relative standard deviation (\u0026lt;15%) were obtained. Signal suppression/enhancement was studied and matrix-matched calibration used to minimise this effect, but no additional clean-up step was necessary. The mass spectrometer was operated in selected reaction monitoring (SRM) mode and with selected transitions for each compound to quantify and to qualify them. Fifty-nine per cent of samples were contaminated. The percentages of enniatins were 53%, 49%, 44% and 16% for A1, B, B1, and A, respectively, and for beauvericin it was 1.6%. For the total samples, the mean contamination was 30, 24, 15, 2.1 and 0.1 ng g\u003csup\u003e−1\u003c/sup\u003e for enniatins A1, B, B1 and A, and beauvericin, respectively. The wheat-based samples showed higher levels and greater prevalence than any other cereals monitored. These results were used to estimate the daily intake of ENs from wheat-based cereal by the Portuguese population. At the same time, the usefulness of this method in the analysis of other important mycotoxins (aflatoxin B\u003csub\u003e1\u003c/sub\u003e, ochratoxin A, deoxynivalenol, T-2 toxin, fumonisin B\u003csub\u003e1\u003c/sub\u003e and zearalenone) was evaluated.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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","url":"https://tandf.figshare.com/articles/dataset/Evaluation_of_enniatins_A_A1_B_B1_and_beauvericin_in_Portuguese_cereal_based_foods/825559","contentUrl":null,"metadataVersion":3,"schemaVersion":"http://datacite.org/schema/kernel-4","source":"mds","isActive":true,"state":"findable","reason":null,"viewCount":0,"viewsOverTime":[],"downloadCount":0,"downloadsOverTime":[],"referenceCount":0,"citationCount":0,"citationsOverTime":[],"partCount":0,"partOfCount":0,"versionCount":0,"versionOfCount":0,"created":"2013-10-18T10:35:39.000Z","registered":"2013-10-18T10:35:40.000Z","published":"2012","updated":"2020-09-05T01:16:05.000Z"},"re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