{"data":{"id":"10.6084/m9.figshare.7677311.v1","type":"dois","attributes":{"doi":"10.6084/m9.figshare.7677311.v1","prefix":"10.6084","suffix":"m9.figshare.7677311.v1","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Mariano, Danielle De Mattos","nameType":"Personal","givenName":"Danielle De Mattos","familyName":"Mariano","affiliation":[],"nameIdentifiers":[]},{"name":"Freitas, Daniela De França Da Silva","nameType":"Personal","givenName":"Daniela De França Da Silva","familyName":"Freitas","affiliation":[],"nameIdentifiers":[]},{"name":"Mendes, Luis Claudio","nameType":"Personal","givenName":"Luis Claudio","familyName":"Mendes","affiliation":[],"nameIdentifiers":[]},{"name":"Carvalho, Ana Luiza Fonseca","nameType":"Personal","givenName":"Ana Luiza Fonseca","familyName":"Carvalho","affiliation":[],"nameIdentifiers":[]},{"name":"Ramos, Flavio James Humberto Tommasini Vieira","nameType":"Personal","givenName":"Flavio James Humberto Tommasini Vieira","familyName":"Ramos","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Investigation on Structural, Morphological and Relaxometric Properties of Lamellar Zrp Modified with Long Chain Amine"}],"publisher":"SciELO journals","container":{},"publicationYear":2019,"subjects":[{"subject":"90499 Chemical Engineering not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Chemical engineering","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Chemical engineering","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"91207 Metals and Alloy Materials","subjectScheme":"FOR"},{"subject":"FOS: Materials engineering","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Materials engineering","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"91299 Materials Engineering not elsewhere classified","subjectScheme":"FOR"}],"contributors":[],"dates":[{"date":"2019-02-06","dateType":"Created"},{"date":"2019-02-06","dateType":"Updated"},{"date":"2019","dateType":"Issued"}],"language":null,"types":{"ris":"DATA","bibtex":"misc","citeproc":"dataset","schemaOrg":"Dataset","resourceType":"Dataset","resourceTypeGeneral":"Dataset"},"relatedIdentifiers":[{"relationType":"IsSupplementTo","relatedIdentifier":"10.1590/1980-5373-mr-2018-0493","relatedIdentifierType":"DOI"},{"relationType":"IsIdenticalTo","relatedIdentifier":"10.6084/m9.figshare.7677311","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":["1477079 Bytes"],"formats":[],"version":null,"rightsList":[{"rights":"Creative Commons Attribution 4.0 International","rightsUri":"https://creativecommons.org/licenses/by/4.0/legalcode","schemeUri":"https://spdx.org/licenses/","rightsIdentifier":"cc-by-4.0","rightsIdentifierScheme":"SPDX"}],"descriptions":[{"description":"In order to search nanofiller for controlling release of drugs lamellar α-zirconium phosphate (α-ZrP) was modified with ether-amine oligomer (E-A). Synthesis and chemical modification followed specific reaction conditions and different EA:ZrP ratios. Infrared spectra showed strong interaction between P-OH and NH2 groups. Thermogravimetric curves showed that ether-amine oligomer was incorporated by ZrP. Interlamellar space of α-ZrP increased at least four times indicating intercalation. The relaxometry analysis indicated that α-ZrP molecular mobility changed according to the ether-amine amount. The scanning electron microscopy/energy dispersive analysis revealed the presence of octadecylamine inside the α-ZrP galleries. The results showed that P-OH group (Brønsted acid) and amine group (Brønsted base) reacted to each other, resulting in an ionic bond PO- + 3HN-[-(CH2-CH2-O)m-(CH2-C-H(CH3)-O)n-]. Partially intercalated nanofiller were achieved.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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","url":"https://scielo.figshare.com/articles/Investigation_on_Structural_Morphological_and_Relaxometric_Properties_of_Lamellar_Zrp_Modified_with_Long_Chain_Amine/7677311/1","contentUrl":null,"metadataVersion":2,"schemaVersion":"http://datacite.org/schema/kernel-4","source":"mds","isActive":true,"state":"findable","reason":null,"viewCount":0,"viewsOverTime":[],"downloadCo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