{"data":{"id":"10.6084/m9.figshare.7591604","type":"dois","attributes":{"doi":"10.6084/m9.figshare.7591604","prefix":"10.6084","suffix":"m9.figshare.7591604","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Penaloza, David Penuliar","nameType":"Personal","givenName":"David Penuliar","familyName":"Penaloza","affiliation":[],"nameIdentifiers":[]},{"name":"Seery, Thomas Andrew Patrick","nameType":"Personal","givenName":"Thomas Andrew Patrick","familyName":"Seery","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Preparation and Characterization of Clay-polymer Nanocomposite Having Covalently-bound poly(norbornenes) with Pendant Cholesterols"}],"publisher":"SciELO journals","container":{},"publicationYear":2019,"subjects":[{"subject":"90499 Chemical Engineering not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Chemical engineering","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Chemical engineering","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"91207 Metals and Alloy Materials","subjectScheme":"FOR"},{"subject":"FOS: Materials engineering","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Materials engineering","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"91299 Materials Engineering not elsewhere classified","subjectScheme":"FOR"}],"contributors":[],"dates":[{"date":"2019-01-16","dateType":"Created"},{"date":"2019-01-16","dateType":"Updated"},{"date":"2019","dateType":"Issued"}],"language":null,"types":{"ris":"DATA","bibtex":"misc","citeproc":"dataset","schemaOrg":"Dataset","resourceType":"Dataset","resourceTypeGeneral":"Dataset"},"relatedIdentifiers":[{"relationType":"IsSupplementTo","relatedIdentifier":"10.1590/1980-5373-mr-2018-0192","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":["908661 Bytes"],"formats":[],"version":null,"rightsList":[{"rights":"Creative Commons Attribution 4.0 International","rightsUri":"https://creativecommons.org/licenses/by/4.0/legalcode","schemeUri":"https://spdx.org/licenses/","rightsIdentifier":"cc-by-4.0","rightsIdentifierScheme":"SPDX"}],"descriptions":[{"description":"We have successfully prepared a clay-based polymer nanocomposite having grown cholesterol bearing poly(norbornene) brushes end-tethered from a naturally-occurring montmorillonite clay template. The synthesis of this hybrid material involved the treatment of the clay with first generation Grubbs catalyst, a ruthenium alkylidene, which induced a ring-opening metathesis and subsequent surface initiated polymerization of the cholesterol bearing monomer. This results in an inorganic/organic hybrid functional nanomaterial where the inclusion of the clay particles in a liquid crystalline domain modifies the thermal transitions.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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","url":"https://scielo.figshare.com/articles/Preparation_and_Characterization_of_Clay-polymer_Nanocomposite_Having_Covalently-bound_poly_norbornenes_with_Pendant_Cholesterols/7591604","contentUrl":null,"metadataVersion":1,"schemaVersion":"http://datacite.org/schema/kernel-4","source":"mds","isActive":true,"state":"findable","reason":null,"viewCount":0,"viewsOverTime":[],"downloadCount":0,"downloadsOverTime":[],"referenceCount":1,"citationCount":0,"citationsOverTime":[],"partCount":0,"partOfCount":0,"versionCount":0,"versionOfCount":0,"created":"2019-01-16T02:44:34.000Z","registered":"2019-01-16T02:44:35.000Z","published":"2019","updated":"2020-08-27T20:42:48.000Z"},"relationships":{"client":{"data":{"id":"figshare.ars","type":"clients"}},"provider":{"data":{"id":"otjm","type":"providers"}},"media":{"data":{"id":"10.6084/m9.figshare.7591604","type":"media"}},"references":{"data":[{"id":"10.1590/1980-5373-mr-2018-0192","type":"dois"}]},"citations":{"data":[]},"parts":{"data":[]},"partOf":{"data":[]},"versions":{"data":[]},"versionOf":{"data":[]}}}}