{"data":{"id":"10.6084/m9.figshare.7187165","type":"dois","attributes":{"doi":"10.6084/m9.figshare.7187165","prefix":"10.6084","suffix":"m9.figshare.7187165","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Bessa, Larissa C. B. A.","nameType":"Personal","givenName":"Larissa C. B. A.","familyName":"Bessa","affiliation":[],"nameIdentifiers":[]},{"name":"Batista, Eduardo A. C.","nameType":"Personal","givenName":"Eduardo A. C.","familyName":"Batista","affiliation":[],"nameIdentifiers":[]},{"name":"Meirelles, Antonio J. A.","nameType":"Personal","givenName":"Antonio J. A.","familyName":"Meirelles","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"LIQUID-LIQUID EQUILIBRIUM OF SYSTEMS COMPOSED OF SOYBEAN OIL + MONOACYLGLYCEROLS + DIACYLGLYCEROLS + ETHYL OLEATE + OLEIC ACID + ETHANOL AT 303.15 AND 318.15 K"}],"publisher":"SciELO journals","container":{},"publicationYear":2018,"subjects":[{"subject":"90499 Chemical Engineering not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Chemical engineering","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Chemical engineering","subjectScheme":"Fields of Science and Technology (FOS)"}],"contributors":[],"dates":[{"date":"2018-10-10","dateType":"Created"},{"date":"2018-10-10","dateType":"Updated"},{"date":"2018","dateType":"Issued"}],"language":null,"types":{"ris":"DATA","bibtex":"misc","citeproc":"dataset","schemaOrg":"Dataset","resourceType":"Dataset","resourceTypeGeneral":"Dataset"},"relatedIdentifiers":[{"relationType":"IsSupplementTo","relatedIdentifier":"10.1590/0104-6632.20180352s20160271","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":["785882 Bytes"],"formats":[],"version":null,"rightsList":[{"rights":"Creative Commons Attribution 4.0 International","rightsUri":"https://creativecommons.org/licenses/by/4.0/legalcode","schemeUri":"https://spdx.org/licenses/","rightsIdentifier":"cc-by-4.0","rightsIdentifierScheme":"SPDX"}],"descriptions":[{"description":"Abstract Steady increase in prices of petroleum-based fuels and growing environmental concerns are boosting attention to alternative fuels. In this context, biodiesel has drawn attention as an alternative fuel, especially as a substitute to traditional diesel. Biodiesel is commonly produced from triacylglycerols and alcohol through transesterification reaction. Knowledge of equilibrium phase distribution of key components in transesterification systems is essential for a better understanding of the reaction pathway and for guiding the design and optimization of reactors and the products separation. This study reports experimental results and thermodynamic modeling of the liquid-liquid equilibrium of systems composed of soybean oil + monoacylglycerols + diacylglycerols + ethyl oleate + oleic acid + ethanol at 303.15 and 318.15 K. Experimental data were well correlated using NRTL, with a maximum deviation of 0.688%. As for UNIFAC, the deviations between predicted and experimental data ranged from 3.13 to 9.21%.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"PD94bWwgdmVyc2lvbj0iMS4wIiBlbmNvZGluZz0iVVRGLTgiPz4KPHJlc291cmNlIHhtbG5zPSJodHRwOi8vZGF0YWNpdGUub3JnL3NjaGVtYS9rZXJuZWwtNCIgeG1sbnM6eHNpPSJodHRwOi8vd3d3LnczLm9yZy8yMDAxL1hNTFNjaGVtYS1pbnN0YW5jZSIgeHNpOnNjaGVtYUxvY2F0aW9uPSJodHRwOi8vZGF0YWNpdGUub3JnL3NjaGVtYS9rZXJuZWwtNCBodHRwOi8vc2NoZW1hLmRhdGFjaXRlLm9yZy9tZXRhL2tlcm5lbC00LjEvbWV0YWRhdGEueHNkIj4KICA8aWRlbnRpZmllciBpZGVudGlmaWVyVHlwZT0iRE9JIj4xMC42MDg0L005LkZJR1NIQVJFLjcxODcxNjU8L2lkZW50aWZpZXI+CiAgPGNyZWF0b3JzPgogICAgPGNyZWF0b3I+CiAgICAgIDxjcmVhdG9yTmFtZT5MYXJpc3NhIEMuIEIuIEEuIEJlc3NhPC9jcmVhdG9yTmFtZT4KICAgIDwvY3JlYXRvcj4KICAgIDxjcmVhdG9yPgogICAgICA8Y3JlYXRvck5hbWU+RWR1YXJkbyBBLiBDLiBCYXRpc3RhPC9jcmVhdG9yTmFtZT4KICAgIDwvY3JlYXRvcj4KICAgIDxjcmVhdG9yPgogICAgICA8Y3JlYXRvck5hbWU+QW50b25pbyBKLiBBLiBNZWlyZWxsZXM8L2NyZWF0b3JOYW1lPgogICAgPC9jcmVhdG9yPgogIDwvY3JlYXRvcnM+CiAgPHRpdGxlcz4KICAgIDx0aXRsZT5MSVFVSUQtTElRVUlEIEVRVUlMSUJSSVVNIE9GIFNZU1RFTVMgQ09NUE9TRUQgT0YgU09ZQkVBTiBPSUwgKyBNT05PQUNZTEdMWUNFUk9MUyArIERJQUNZTEdMWUNFUk9MUyArIEVUSFlMIE9MRUFURSArIE9MRUlDIEFDSUQgKyBFVEhBTk9MIEFUIDMwMy4xNSBBTkQgMzE4LjE1IEs8L3RpdGxlPgogIDwvdGl0bGVzPgogIDxkZXNjcmlwdGlvbnM+CiAgICA8ZGVzY3JpcHRpb24gZGVzY3JpcHRpb25UeXBlPSJBYnN0cmFjdCI+Jmx0O2RpdiZndDsmbHQ7cCZndDtBYnN0cmFjdCBTdGVhZHkgaW5jcmVhc2UgaW4gcHJpY2VzIG9mIHBldHJvbGV1bS1iYXNlZCBmdWVscyBhbmQgZ3Jvd2luZyBlbnZpcm9ubWVudGFsIGNvbmNlcm5zIGFyZSBib29zdGluZyBhdHRlbnRpb24gdG8gYWx0ZXJuYXRpdmUgZnVlbHMuIEluIHRoaXMgY29udGV4dCwgYmlvZGllc2VsIGhhcyBkcmF3biBhdHRlbnRpb24gYXMgYW4gYWx0ZXJuYXRpdmUgZnVlbCwgZXNwZWNpYWxseSBhcyBhIHN1YnN0aXR1dGUgdG8gdHJhZGl0aW9uYWwgZGllc2VsLiBCaW9kaWVzZWwgaXMgY29tbW9ubHkgcHJvZHVjZWQgZnJvbSB0cmlhY3lsZ2x5Y2Vyb2xzIGFuZCBhbGNvaG9sIHRocm91Z2ggdHJhbnNlc3RlcmlmaWNhdGlvbiByZWFjdGlvbi4gS25vd2xlZGdlIG9mIGVxdWlsaWJyaXVtIHBoYXNlIGRpc3RyaWJ1dGlvbiBvZiBrZXkgY29tcG9uZW50cyBpbiB0cmFuc2VzdGVyaWZpY2F0aW9uIHN5c3RlbXMgaXMgZXNzZW50aWFsIGZvciBhIGJldHRlciB1bmRlcnN0YW5kaW5nIG9mIHRoZSByZWFjdGlvbiBwYXRod2F5IGFuZCBmb3IgZ3VpZGluZyB0aGUgZGVzaWduIGFuZCBvcHRpbWl6YXRpb24gb2YgcmVhY3RvcnMgYW5kIHRoZSBwcm9kdWN0cyBzZXBhcmF0aW9uLiBUaGlzIHN0dWR5IHJlcG9ydHMgZXhwZXJpbWVudGFsIHJlc3VsdHMgYW5kIHRoZXJtb2R5bmFtaWMgbW9kZWxpbmcgb2YgdGhlIGxpcXVpZC1saXF1aWQgZXF1aWxpYnJpdW0gb2Ygc3lzdGVtcyBjb21wb3NlZCBvZiBzb3liZWFuIG9pbCArIG1vbm9hY3lsZ2x5Y2Vyb2xzICsgZGlhY3lsZ2x5Y2Vyb2xzICsgZXRoeWwgb2xlYXRlICsgb2xlaWMgYWNpZCArIGV0aGFub2wgYXQgMzAzLjE1IGFuZCAzMTguMTUgSy4gRXhwZXJpbWVudGFsIGRhdGEgd2VyZSB3ZWxsIGNvcnJlbGF0ZWQgdXNpbmcgTlJUTCwgd2l0aCBhIG1heGltdW0gZGV2aWF0aW9uIG9mIDAuNjg4JS4gQXMgZm9yIFVOSUZBQywgdGhlIGRldmlhdGlvbnMgYmV0d2VlbiBwcmVkaWN0ZWQgYW5kIGV4cGVyaW1lbnRhbCBkYXRhIHJhbmdlZCBmcm9tIDMuMTMgdG8gOS4yMSUuJmx0Oy9wJmd0OyZsdDsvZGl2Jmd0OzwvZGVzY3JpcHRpb24+CiAgPC9kZXNjcmlwdGlvbnM+CiAgPHN1YmplY3RzPgogICAgPHN1YmplY3Qgc2NoZW1lVVJJPSJodHRwOi8vd3d3LmFicy5nb3YuYXUvYXVzc3RhdHMvYWJzQC5uc2YvMC82QkI0MjdBQjk2OTZDMjI1Q0EyNTc0MTgwMDA0NDYzRSIgc3ViamVjdFNjaGVtZT0iRk9SIj45MDQ5OSBDaGVtaWNhbCBFbmdpbmVlcmluZyBub3QgZWxzZXdoZXJlIGNsYXNzaWZpZWQ8L3N1YmplY3Q+CiAgPC9zdWJqZWN0cz4KICA8cHVibGlzaGVyPlNjaUVMTyBqb3VybmFsczwvcHVibGlzaGVyPgogIDxwdWJsaWNhdGlvblllYXI+MjAxODwvcHVibGljYXRpb25ZZWFyPgogIDxkYXRlcz4KICAgIDxkYXRlIGRhdGVUeXBlPSJDcmVhdGVkIj4yMDE4LTEwLTEwPC9kYXRlPgogICAgPGRhdGUgZGF0ZVR5cGU9IlVwZGF0ZWQiPjIwMTgtMTAtMTA8L2RhdGU+CiAgPC9kYXRlcz4KICA8cmVzb3VyY2VUeXBlIHJlc291cmNlVHlwZUdlbmVyYWw9IkRhdGFzZXQiPkRhdGFzZXQ8L3Jlc291cmNlVHlwZT4KICA8c2l6ZXM+CiAgICA8c2l6ZT43ODU4ODIgQnl0ZXM8L3NpemU+CiAgPC9zaXplcz4KICA8cmVsYXRlZElkZW50aWZpZXJzPgogICAgPHJlbGF0ZWRJZGVudGlmaWVyIHJlbGF0ZWRJZGVudGlmaWVyVHlwZT0iRE9JIiByZWxhdGlvblR5cGU9IklzU3VwcGxlbWVudFRvIj4xMC4xNTkwLzAxMDQtNjYzMi4yMDE4MDM1MnMyMDE2MDI3MTwvcmVsYXRlZElkZW50aWZpZXI+CiAgPC9yZWxhdGVkSWRlbnRpZmllcnM+CiAgPHJpZ2h0c0xpc3Q+CiAgICA8cmlnaHRzIHJpZ2h0c1VSST0iaHR0cHM6Ly9jcmVhdGl2ZWNvbW1vbnMub3JnL2xpY2Vuc2VzL2J5LzQuMC8iPkNDIEJZIDQuMDwvcmlnaHRzPgogIDwvcmlnaHRzTGlzdD4KPC9yZXNvdXJjZT4=","url":"https://scielo.figshare.com/articles/LIQUID-LIQUID_EQUILIBRIUM_OF_SYSTEMS_COMPOSED_OF_SOYBEAN_OIL_MONOACYLGLYCEROLS_DIACYLGLYCEROLS_ETHYL_OLEATE_OLEIC_ACID_ETHANOL_AT_303_15_AND_318_15_K/7187165","contentUrl":null,"metadataVersion":2,"schemaVersion":"http://datacite.org/schema/kernel-4","source":"mds","isActive":true,"state":"findable","reason":null,"viewCount":0,"viewsOverTime":[],"downloadCount":0,"downloadsOverTime":[],"referenceCount":1,"citationCount":0,"citationsOverTime":[],"partCount":0,"partOfCount":0,"versionCount":0,"versionOfCount":0,"created":"2018-10-10T03:04:48.000Z","registered":"2018-10-10T03:05:38.000Z","published":"2018","updated":"2020-08-28T07:49:59.000Z"},"relationships":{"client":{"data":{"id":"figshare.ars","type":"clients"}},"provider":{"data":{"id":"otjm","type":"providers"}},"media":{"data":{"id":"10.6084/m9.figshare.7187165","type":"media"}},"references":{"data":[{"id":"10.1590/0104-6632.20180352s20160271","type":"dois"}]},"citations":{"data":[]},"parts":{"data":[]},"partOf":{"data":[]},"versions":{"data":[]},"versionOf":{"data":[]}}}}