{"data":{"id":"10.6084/m9.figshare.6857954.v1","type":"dois","attributes":{"doi":"10.6084/m9.figshare.6857954.v1","prefix":"10.6084","suffix":"m9.figshare.6857954.v1","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"González, Leandro García","nameType":"Personal","givenName":"Leandro García","familyName":"González","affiliation":[],"nameIdentifiers":[]},{"name":"Peredo, Luis Zamora","nameType":"Personal","givenName":"Luis Zamora","familyName":"Peredo","affiliation":[],"nameIdentifiers":[]},{"name":"Pérez, Daniel De Jesús Araujo","nameType":"Personal","givenName":"Daniel De Jesús Araujo","familyName":"Pérez","affiliation":[],"nameIdentifiers":[]},{"name":"Guevara, Joaquín Villalba","nameType":"Personal","givenName":"Joaquín Villalba","familyName":"Guevara","affiliation":[],"nameIdentifiers":[]},{"name":"Ramírez, Nelly Flores","nameType":"Personal","givenName":"Nelly Flores","familyName":"Ramírez","affiliation":[],"nameIdentifiers":[]},{"name":"García, Salomón Ramiro Vásquez","nameType":"Personal","givenName":"Salomón Ramiro Vásquez","familyName":"García","affiliation":[],"nameIdentifiers":[]},{"name":"Romo, María Guadalupe Garnica","nameType":"Personal","givenName":"María Guadalupe Garnica","familyName":"Romo","affiliation":[],"nameIdentifiers":[]},{"name":"Quiroz, Teresa Hernández","nameType":"Personal","givenName":"Teresa Hernández","familyName":"Quiroz","affiliation":[],"nameIdentifiers":[]},{"name":"Torres, Julián Hernández","nameType":"Personal","givenName":"Julián Hernández","familyName":"Torres","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Synthesis and characterization of nanostructured TiO2 and TiO2/W thin films deposited by co-sputtering"}],"publisher":"SciELO journals","container":{},"publicationYear":2018,"subjects":[{"subject":"90502 Construction Engineering","subjectScheme":"FOR"},{"subject":"FOS: Civil engineering","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Civil engineering","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"91207 Metals and Alloy Materials","subjectScheme":"FOR"},{"subject":"FOS: Materials engineering","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Materials engineering","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"91299 Materials Engineering not elsewhere classified","subjectScheme":"FOR"}],"contributors":[],"dates":[{"date":"2018-07-25","dateType":"Created"},{"date":"2018-07-25","dateType":"Updated"},{"date":"2018","dateType":"Issued"}],"language":null,"types":{"ris":"DATA","bibtex":"misc","citeproc":"dataset","schemaOrg":"Dataset","resourceType":"Dataset","resourceTypeGeneral":"Dataset"},"relatedIdentifiers":[{"relationType":"IsSupplementTo","relatedIdentifier":"10.1590/s1517-707620180002.0401","relatedIdentifierType":"DOI"},{"relationType":"IsIdenticalTo","relatedIdentifier":"10.6084/m9.figshare.6857954","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":["1711590 Bytes"],"formats":[],"version":null,"rightsList":[{"rights":"Creative Commons Attribution 4.0 International","rightsUri":"https://creativecommons.org/licenses/by/4.0/legalcode","schemeUri":"https://spdx.org/licenses/","rightsIdentifier":"cc-by-4.0","rightsIdentifierScheme":"SPDX"}],"descriptions":[{"description":"ABSTRACT Nanostructured TiO2 and TiO2/W thin films were deposited on Corning glass substrates by RF and DC magnetron co-sputtering at room temperature, using three targets of TiO, Ti and W. After deposition, samples were subjected to an annealing treatment in air at 500 °C for 3 hrs. The effect of the annealing treatment and tungsten addition to the TiO2 matrix were studied by Raman spectroscopy and X-ray diffraction. Morphology and composition was studied with field emission scanning electron microscopy and optical characterization was made with UV-Vis spectroscopy. All the obtained samples presented an amorphous TiO2 phase; however, after the annealing treatment, a crystallization process from amorphous to anatase phase occurred with gain sizes between 15.6 and 18.3 nm, additionally, a small amount of rutile was also observable. The SEM images corroborated the XRD behavior, besides it was possible to calculate the thickness of the films which was greater for the W-doped films owing the extra power of the sputtering growth, and after the samples had the thermal treatment the thickness decreased due to a more organized structure. Finally, the UV-vis transmittance analysis revealed that the transmittance is higher in heat-treated films as compared to those without any thermal treatment; also, the TiO2 thin films showed a greater transmittance than the W doped TiO2 films, reaching 91%. The lack of transmittance in the non-thermal-treated films made it impossible to compute the band gap of the films; nevertheless, for the thermal-treated films the band gap had a minimal change to the classic TiO2 bang gap value, even for the W doped sample, providing them with the benefits of the tungsten within the same TiO2 structure due to a great homogenization on the structure.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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