{"data":{"id":"10.6084/m9.figshare.6857915.v1","type":"dois","attributes":{"doi":"10.6084/m9.figshare.6857915.v1","prefix":"10.6084","suffix":"m9.figshare.6857915.v1","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Murakami, Lidia Mattos Silva","nameType":"Personal","givenName":"Lidia Mattos Silva","familyName":"Murakami","affiliation":[],"nameIdentifiers":[]},{"name":"Azevedo, Joyce Baracho","nameType":"Personal","givenName":"Joyce Baracho","familyName":"Azevedo","affiliation":[],"nameIdentifiers":[]},{"name":"Diniz, Milton Faria","nameType":"Personal","givenName":"Milton Faria","familyName":"Diniz","affiliation":[],"nameIdentifiers":[]},{"name":"Silva, Leandro Mattos","nameType":"Personal","givenName":"Leandro Mattos","familyName":"Silva","affiliation":[],"nameIdentifiers":[]},{"name":"Dutra, Rita De Cássia Lazzarini","nameType":"Personal","givenName":"Rita De Cássia Lazzarini","familyName":"Dutra","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Characterization of additives in NR formulations by TLC-IR (UATR)"}],"publisher":"SciELO journals","container":{},"publicationYear":2018,"subjects":[{"subject":"91209 Polymers and Plastics","subjectScheme":"FOR"},{"subject":"FOS: Materials engineering","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Materials engineering","subjectScheme":"Fields of Science and Technology (FOS)"}],"contributors":[],"dates":[{"date":"2018-07-25","dateType":"Created"},{"date":"2018-07-25","dateType":"Updated"},{"date":"2018","dateType":"Issued"}],"language":null,"types":{"ris":"DATA","bibtex":"misc","citeproc":"dataset","schemaOrg":"Dataset","resourceType":"Dataset","resourceTypeGeneral":"Dataset"},"relatedIdentifiers":[{"relationType":"IsSupplementTo","relatedIdentifier":"10.1590/0104-1428.06317","relatedIdentifierType":"DOI"},{"relationType":"IsIdenticalTo","relatedIdentifier":"10.6084/m9.figshare.6857915","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":["825390 Bytes"],"formats":[],"version":null,"rightsList":[{"rights":"Creative Commons Attribution 4.0 International","rightsUri":"https://creativecommons.org/licenses/by/4.0/legalcode","schemeUri":"https://spdx.org/licenses/","rightsIdentifier":"cc-by-4.0","rightsIdentifierScheme":"SPDX"}],"descriptions":[{"description":"Abstract It is a well-established fact that rubber accelerator is essential to provide solution in different sectors. However, there is a reversal process which can reduce the material performance. Sulfur accelerators donors and organic peroxides have been presented as a solution to the problem. The methodology development that can separate or characterize those components is a challenge and still allows gaps, explained by the application of conventional technique to reach this goal. This study aimed at contributing to the use of off-line coupling of thin layer chromatography (TLC)/infrared spectroscopy (IR) by Universal Attenuated Total Reflection (UATR) for analysis of N-cyclohexyl-2-benzotiazolsulfenamide (CBS), tetraethylthiuram disulfide (TMTD) and dicumyl peroxide (DCP), in natural poly-cis-isoprene (NR) formulations, containing naphthenic oil. The best results were obtained for the plasticizer and DCP, in formulations that had a greater proportion of these compounds. The separation of CBS and TMTD was made with less effectiveness, due to bands overlapping.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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","url":"https://scielo.figshare.com/articles/Characterization_of_additives_in_NR_formulations_by_TLC-IR_UATR_/6857915/1","contentUrl":null,"metadataVersion":2,"schemaVersion":"http://datacite.org/schema/kernel-4","source":"mds","isActive":true,"state":"findable","reason":null,"viewCount":0,"viewsOverTime":[],"downloadCount":0,"downloadsOverTime":[],"referenceCount":1,"citationCount":0,"citationsOverTime":[],"partCount":0,"partOfCount":0,"versionCount":0,"versionOfCount":0,"created":"2018-07-25T02:59:41.000Z","registered":"2018-07-25T03:01:00.000Z","published":"2018","updated":"2020-08-28T16:21:35.000Z"},"relationships":{"client":{"data":{"id":"figshare.ars","type":"clients"}},"provider":{"data":{"id":"otjm","type":"providers"}},"media":{"data":{"id":"10.6084/m9.figshare.6857915.v1","type":"media"}},"references":{"data"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