{"data":{"id":"10.6084/m9.figshare.6857330.v1","type":"dois","attributes":{"doi":"10.6084/m9.figshare.6857330.v1","prefix":"10.6084","suffix":"m9.figshare.6857330.v1","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Lerici, Laura","nameType":"Personal","givenName":"Laura","familyName":"Lerici","affiliation":[],"nameIdentifiers":[]},{"name":"Femanelli, Carla","nameType":"Personal","givenName":"Carla","familyName":"Femanelli","affiliation":[],"nameIdentifiers":[]},{"name":"Diguilio, Eliana","nameType":"Personal","givenName":"Eliana","familyName":"Diguilio","affiliation":[],"nameIdentifiers":[]},{"name":"Pierella, Liliana","nameType":"Personal","givenName":"Liliana","familyName":"Pierella","affiliation":[],"nameIdentifiers":[]},{"name":"Saux, Clara","nameType":"Personal","givenName":"Clara","familyName":"Saux","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Synthesis and characterization of iron photocatalysts supported on microporous zeolites"}],"publisher":"SciELO journals","container":{},"publicationYear":2018,"subjects":[{"subject":"90502 Construction Engineering","subjectScheme":"FOR"},{"subject":"FOS: Civil engineering","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Civil engineering","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"91207 Metals and Alloy Materials","subjectScheme":"FOR"},{"subject":"FOS: Materials engineering","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Materials engineering","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"91299 Materials Engineering not elsewhere classified","subjectScheme":"FOR"}],"contributors":[],"dates":[{"date":"2018-07-25","dateType":"Created"},{"date":"2018-07-25","dateType":"Updated"},{"date":"2018","dateType":"Issued"}],"language":null,"types":{"ris":"DATA","bibtex":"misc","citeproc":"dataset","schemaOrg":"Dataset","resourceType":"Dataset","resourceTypeGeneral":"Dataset"},"relatedIdentifiers":[{"relationType":"IsSupplementTo","relatedIdentifier":"10.1590/s1517-707620180002.0450","relatedIdentifierType":"DOI"},{"relationType":"IsIdenticalTo","relatedIdentifier":"10.6084/m9.figshare.6857330","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":["694635 Bytes"],"formats":[],"version":null,"rightsList":[{"rights":"Creative Commons Attribution 4.0 International","rightsUri":"https://creativecommons.org/licenses/by/4.0/legalcode","schemeUri":"https://spdx.org/licenses/","rightsIdentifier":"cc-by-4.0","rightsIdentifierScheme":"SPDX"}],"descriptions":[{"description":"ABSTRACT ZSM11 and BETA zeolitic materials were synthesized by the hydrothermal method and were further impregnated with a 6 wt% of iron and characterized by different physicochemical techniques in order to be employed in the photocatalytic degradation of methyl orange (MO). Matrices structures and crystallinity were verified by X Ray Diffraction (XRD) and Fourier Transformed Infrared Spectroscopy (FTIR), even for modified zeolites. XRD patterns showed the characteristic signals at 2θ=7, 9, 23 and 24° for ZSM11 matrix, and 2θ= 7-8° and 21- 22°, for BETA. According to BET results, specific surface area were 392 m2/g for ZSM11 and 585 m2/g for BETA. In both cases, an area reduction with metal incorporation were obtained. Iron con-tent was confirmed by Atomic Absorption (AA) spectroscopy, finding similar values than the theoretical ones. Additionaly, iron signals (0,5 y 6,5 KeV) were detected by SEM EDX. Band gap energies of the materials were calculated employing Diffuse Reflectance Spectroscopy- UVvis (DRS-UVvis), obtaining similar values than α-Fe2O3. A reduction of the band gap energy in comparison with the correspondent material was also found by this technique. The materials were further evaluated as catalysts for MO photodegradation obtaining a 96 % and 56% of degradation for Fe-ZSM11 and Fe-BETA, respectively.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"PD94bWwgdmVyc2lvbj0iMS4wIiBlbmNvZGluZz0iVVRGLTgiPz4KPHJlc291cmNlIHhtbG5zPSJodHRwOi8vZGF0YWNpdGUub3JnL3NjaGVtYS9rZXJuZWwtNCIgeG1sbnM6eHNpPSJodHRwOi8vd3d3LnczLm9yZy8yMDAxL1hNTFNjaGVtYS1pbnN0YW5jZSIgeHNpOnNjaGVtYUxvY2F0aW9uPSJodHRwOi8vZGF0YWNpdGUub3JnL3NjaGVtYS9rZXJuZWwtNCBodHRwOi8vc2NoZW1hLmRhdGFjaXRlLm9yZy9tZXRhL2tlcm5lbC00LjEvbWV0YWRhdGEueHNkIj4KICA8aWRlbnRpZmllciBpZGVudGlmaWVyVHlwZT0iRE9JIj4xMC42MDg0L005LkZJR1NIQVJFLjY4NTczMzAuVjE8L2lkZW50aWZpZXI+CiAgPGNyZWF0b3JzPgogICAgPGNyZWF0b3I+CiAgICAgIDxjcmVhdG9yTmFtZT5MYXVyYSBMZXJpY2k8L2NyZWF0b3JOYW1lPgogICAgPC9jcmVhdG9yPgogICAgPGNyZWF0b3I+CiAgICAgIDxjcmVhdG9yTmFtZT5DYXJsYSBGZW1hbmVsbGk8L2NyZWF0b3JOYW1lPgogICAgPC9jcmVhdG9yPgogICAgPGNyZWF0b3I+CiAgICAgIDxjcmVhdG9yTmFtZT5FbGlhbmEgRGlndWlsaW88L2NyZWF0b3JOYW1lPgogICAgPC9jcmVhdG9yPgogICAgPGNyZWF0b3I+CiAgICAgIDxjcmVhdG9yTmFtZT5MaWxpYW5hIFBpZXJlbGxhPC9jcmVhdG9yTmFtZT4KICAgIDwvY3JlYXRvcj4KICAgIDxjcmVhdG9yPgogICAgICA8Y3JlYXRvck5hbWU+Q2xhcmEgU2F1eDwvY3JlYXRvck5hbWU+CiAgICA8L2NyZWF0b3I+CiAgPC9jcmVhdG9ycz4KICA8dGl0bGVzPgogICAgPHRpdGxlPlN5bnRoZXNpcyBhbmQgY2hhcmFjdGVyaXphdGlvbiBvZiBpcm9uIHBob3RvY2F0YWx5c3RzIHN1cHBvcnRlZCBvbiBtaWNyb3Bvcm91cyB6ZW9saXRlczwvdGl0bGU+CiAgPC90aXRsZXM+CiAgPGRlc2NyaXB0aW9ucz4KICAgIDxkZXNjcmlwdGlvbiBkZXNjcmlwdGlvblR5cGU9IkFic3RyYWN0Ij4mbHQ7cCZndDsmbHQ7L3AmZ3Q7Jmx0O3AmZ3Q7QUJTVFJBQ1QgWlNNMTEgYW5kIEJFVEEgemVvbGl0aWMgbWF0ZXJpYWxzIHdlcmUgc3ludGhlc2l6ZWQgYnkgdGhlIGh5ZHJvdGhlcm1hbCBtZXRob2QgYW5kIHdlcmUgZnVydGhlciBpbXByZWduYXRlZCB3aXRoIGEgNiB3dCUgb2YgaXJvbiBhbmQgY2hhcmFjdGVyaXplZCBieSBkaWZmZXJlbnQgcGh5c2ljb2NoZW1pY2FsIHRlY2huaXF1ZXMgaW4gb3JkZXIgdG8gYmUgZW1wbG95ZWQgaW4gdGhlIHBob3RvY2F0YWx5dGljIGRlZ3JhZGF0aW9uIG9mIG1ldGh5bCBvcmFuZ2UgKE1PKS4gTWF0cmljZXMgc3RydWN0dXJlcyBhbmQgY3J5c3RhbGxpbml0eSB3ZXJlIHZlcmlmaWVkIGJ5IFggUmF5IERpZmZyYWN0aW9uIChYUkQpIGFuZCBGb3VyaWVyIFRyYW5zZm9ybWVkIEluZnJhcmVkIFNwZWN0cm9zY29weSAoRlRJUiksIGV2ZW4gZm9yIG1vZGlmaWVkIHplb2xpdGVzLiBYUkQgcGF0dGVybnMgc2hvd2VkIHRoZSBjaGFyYWN0ZXJpc3RpYyBzaWduYWxzIGF0IDLOuD03LCA5LCAyMyBhbmQgMjTCsCBmb3IgWlNNMTEgbWF0cml4LCBhbmQgMs64PSA3LTjCsCBhbmQgMjEtIDIywrAsIGZvciBCRVRBLiBBY2NvcmRpbmcgdG8gQkVUIHJlc3VsdHMsIHNwZWNpZmljIHN1cmZhY2UgYXJlYSB3ZXJlIDM5MiBtMi9nIGZvciBaU00xMSBhbmQgNTg1IG0yL2cgZm9yIEJFVEEuIEluIGJvdGggY2FzZXMsIGFuIGFyZWEgcmVkdWN0aW9uIHdpdGggbWV0YWwgaW5jb3Jwb3JhdGlvbiB3ZXJlIG9idGFpbmVkLiBJcm9uIGNvbi10ZW50IHdhcyBjb25maXJtZWQgYnkgQXRvbWljIEFic29ycHRpb24gKEFBKSBzcGVjdHJvc2NvcHksIGZpbmRpbmcgc2ltaWxhciB2YWx1ZXMgdGhhbiB0aGUgdGhlb3JldGljYWwgb25lcy4gQWRkaXRpb25hbHksIGlyb24gc2lnbmFscyAoMCw1IHkgNiw1IEtlVikgd2VyZSBkZXRlY3RlZCBieSBTRU0gRURYLiBCYW5kIGdhcCBlbmVyZ2llcyBvZiB0aGUgbWF0ZXJpYWxzIHdlcmUgY2FsY3VsYXRlZCBlbXBsb3lpbmcgRGlmZnVzZSBSZWZsZWN0YW5jZSBTcGVjdHJvc2NvcHktIFVWdmlzIChEUlMtVVZ2aXMpLCBvYnRhaW5pbmcgc2ltaWxhciB2YWx1ZXMgdGhhbiDOsS1GZTJPMy4gQSByZWR1Y3Rpb24gb2YgdGhlIGJhbmQgZ2FwIGVuZXJneSBpbiBjb21wYXJpc29uIHdpdGggdGhlIGNvcnJlc3BvbmRlbnQgbWF0ZXJpYWwgd2FzIGFsc28gZm91bmQgYnkgdGhpcyB0ZWNobmlxdWUuIFRoZSBtYXRlcmlhbHMgd2VyZSBmdXJ0aGVyIGV2YWx1YXRlZCBhcyBjYXRhbHlzdHMgZm9yIE1PIHBob3RvZGVncmFkYXRpb24gb2J0YWluaW5nIGEgOTYgJSBhbmQgNTYlIG9mIGRlZ3JhZGF0aW9uIGZvciBGZS1aU00xMSBhbmQgRmUtQkVUQSwgcmVzcGVjdGl2ZWx5LiZsdDsvcCZndDsmbHQ7cCZndDsmbHQ7L3AmZ3Q7PC9kZXNjcmlwdGlvbj4KICA8L2Rlc2NyaXB0aW9ucz4KICA8c3ViamVjdHM+CiAgICA8c3ViamVjdCBzY2hlbWVVUkk9Imh0dHA6Ly93d3cuYWJzLmdvdi5hdS9hdXNzdGF0cy9hYnNALm5zZi8wLzZCQjQyN0FCOTY5NkMyMjVDQTI1NzQxODAwMDQ0NjNFIiBzdWJqZWN0U2NoZW1lPSJGT1IiPjkwNTAyIENvbnN0cnVjdGlvbiBFbmdpbmVlcmluZzwvc3ViamVjdD4KICAgIDxzdWJqZWN0IHNjaGVtZVVSST0iaHR0cDovL3d3dy5hYnMuZ292LmF1L2F1c3N0YXRzL2Fic0AubnNmLzAvNkJCNDI3QUI5Njk2QzIyNUNBMjU3NDE4MDAwNDQ2M0UiIHN1YmplY3RTY2hlbWU9IkZPUiI+OTEyMDcgTWV0YWxzIGFuZCBBbGxveSBNYXRlcmlhbHM8L3N1YmplY3Q+CiAgICA8c3ViamVjdCBzY2hlbWVVUkk9Imh0dHA6Ly93d3cuYWJzLmdvdi5hdS9hdXNzdGF0cy9hYnNALm5zZi8wLzZCQjQyN0FCOTY5NkMyMjVDQTI1NzQxODAwMDQ0NjNFIiBzdWJqZWN0U2NoZW1lPSJGT1IiPjkxMjk5IE1hdGVyaWFscyBFbmdpbmVlcmluZyBub3QgZWxzZXdoZXJlIGNsYXNzaWZpZWQ8L3N1YmplY3Q+CiAgPC9zdWJqZWN0cz4KICA8cHVibGlzaGVyPlNjaUVMTyBqb3VybmFsczwvcHVibGlzaGVyPgogIDxwdWJsaWNhdGlvblllYXI+MjAxODwvcHVibGljYXRpb25ZZWFyPgogIDxkYXRlcz4KICAgIDxkYXRlIGRhdGVUeXBlPSJDcmVhdGVkIj4yMDE4LTA3LTI1PC9kYXRlPgogICAgPGRhdGUgZGF0ZVR5cGU9IlVwZGF0ZWQiPjIwMTgtMDctMjU8L2RhdGU+CiAgPC9kYXRlcz4KICA8cmVzb3VyY2VUeXBlIHJlc291cmNlVHlwZUdlbmVyYWw9IkRhdGFzZXQiPkRhdGFzZXQ8L3Jlc291cmNlVHlwZT4KICA8c2l6ZXM+CiAgICA8c2l6ZT42OTQ2MzUgQnl0ZXM8L3NpemU+CiAgPC9zaXplcz4KICA8cmVsYXRlZElkZW50aWZpZXJzPgogICAgPHJlbGF0ZWRJZGVudGlmaWVyIHJlbGF0ZWRJZGVudGlmaWVyVHlwZT0iRE9JIiByZWxhdGlvblR5cGU9IklzU3VwcGxlbWVudFRvIj4xMC4xNTkwL3MxNTE3LTcwNzYyMDE4MDAwMi4wNDUwPC9yZWxhdGVkSWRlbnRpZmllcj4KICAgIDxyZWxhdGVkSWRlbnRpZmllciByZWxhdGVkSWRlbnRpZmllclR5cGU9IkRPSSIgcmVsYXRpb25UeXBlPSJJc0lkZW50aWNhbFRvIj4xMC42MDg0L205LmZpZ3NoYXJlLjY4NTczMzA8L3JlbGF0ZWRJZGVudGlmaWVyPgogIDwvcmVsYXRlZElkZW50aWZpZXJzPgogIDxyaWdodHNMaXN0PgogICAgPHJpZ2h0cyByaWdodHNVUkk9Imh0dHBzOi8vY3JlYXRpdmVjb21tb25zLm9yZy9saWNlbnNlcy9ieS80LjAvIj5DQyBCWSA0LjA8L3JpZ2h0cz4KICA8L3JpZ2h0c0xpc3Q+CjwvcmVzb3VyY2U+","url":"https://sciel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