{"data":{"id":"10.6084/m9.figshare.6832796.v1","type":"dois","attributes":{"doi":"10.6084/m9.figshare.6832796.v1","prefix":"10.6084","suffix":"m9.figshare.6832796.v1","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"França, Danyelle Campos","nameType":"Personal","givenName":"Danyelle Campos","familyName":"França","affiliation":[],"nameIdentifiers":[]},{"name":"Dayanne Diniz Morais","affiliation":[],"nameIdentifiers":[]},{"name":"Elieber Barros Bezerra","affiliation":[],"nameIdentifiers":[]},{"name":"Edcleide Maria Araújo","affiliation":[],"nameIdentifiers":[]},{"name":"Wellen, Renate Maria Ramos","nameType":"Personal","givenName":"Renate Maria Ramos","familyName":"Wellen","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Photodegradation Mechanisms on Poly(ε-caprolactone) (PCL)"}],"publisher":"SciELO journals","container":{},"publicationYear":2018,"subjects":[{"subject":"90499 Chemical Engineering not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Chemical engineering","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Chemical engineering","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"91207 Metals and Alloy Materials","subjectScheme":"FOR"},{"subject":"FOS: Materials engineering","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Materials engineering","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"91299 Materials Engineering not elsewhere classified","subjectScheme":"FOR"}],"contributors":[],"dates":[{"date":"2018-07-18","dateType":"Created"},{"date":"2018-07-18","dateType":"Updated"},{"date":"2018","dateType":"Issued"}],"language":null,"types":{"ris":"DATA","bibtex":"misc","citeproc":"dataset","schemaOrg":"Dataset","resourceType":"Dataset","resourceTypeGeneral":"Dataset"},"relatedIdentifiers":[{"relationType":"IsSupplementTo","relatedIdentifier":"10.1590/1980-5373-mr-2017-0837","relatedIdentifierType":"DOI"},{"relationType":"IsIdenticalTo","relatedIdentifier":"10.6084/m9.figshare.6832796","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":["1816044 Bytes"],"formats":[],"version":null,"rightsList":[{"rights":"Creative Commons Attribution 4.0 International","rightsUri":"https://creativecommons.org/licenses/by/4.0/legalcode","schemeUri":"https://spdx.org/licenses/","rightsIdentifier":"cc-by-4.0","rightsIdentifierScheme":"SPDX"}],"descriptions":[{"description":"Photodegradation of PCL was performed exposing injected specimens to ultraviolet radiation (UV-B) up to 9 weeks. Photodegradated PCL specimens were tested by Differential Scanning Calorimetry (DSC), Infrared Spectroscopy (FTIR), mechanical properties, Optical Microscopy (MO) and Scanning Electron Microscopy (SEM).Upon exposure decrease in elongation at break and increase of elastic modulus were verified, higher degree of crystallinity was observed for longer exposure what can be due to the chemi-crystallization mechanism. From IR spectra new carbonyl group (C=O) peaks were observed. Presence of micro cracks on specimens’ surface was identified by MO. From morphological analyses is suggested that the photodegradation in PCL takes place by bulk erosion mechanism.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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","url":"https://scielo.figshare.com/articles/Photodegradation_Mechanisms_on_Poly_-caprolactone_PCL_/6832796/1","contentUrl":null,"metadataVersion":2,"schemaVersion":"http://datacite.org/schema/kernel-4","source":"mds","isActive":true,"state":"findable","reason":null,"viewCount":0,"viewsOverTime":[],"downloadCount":0,"downloadsOverTime":[],"referenceCount":1,"citationCount":0,"citationsOverTime":[],"partCount":0,"partOfCount":0,"versionCount":0,"versionOfCount":0,"created":"2018-07-18T05:06:22.000Z","registered":"2018-07-18T08:09:49.000Z","published":"2018","updated":"2020-08-28T17:08:53.000Z"},"relationships":{"client":{"data":{"id":"figshare.ars","type":"clients"}},"provider":{"data":{"id":"otjm","type":"providers"}},"media":{"data":{"id":"1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