{"data":{"id":"10.6084/m9.figshare.654811","type":"dois","attributes":{"doi":"10.6084/m9.figshare.654811","prefix":"10.6084","suffix":"m9.figshare.654811","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"MITHLESH AGRAWAL","affiliation":[],"nameIdentifiers":[]},{"name":"GOPAL LALYADAV","affiliation":[],"nameIdentifiers":[]},{"name":"ANSHU KHANDELWAL, ","nameType":"Personal","familyName":"ANSHU KHANDELWAL","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"“ SYNTHESIS AND SPECTRAL STUDIES OF MIXED LIGAND COMPLEXES OF FE(III) WITH BENZOYLACETONE AND SALICYLALDEHYDE, SUBSTITUTED SALICYLALDEHYDES, 2-HYDROXY- ARYL CARBONYL COMPOUNDS OR Â-DIKETONES”"}],"publisher":"figshare","container":{},"publicationYear":2013,"subjects":[{"subject":"Organic Chemistry"},{"subject":"FOS: Chemical sciences","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Chemical sciences","subjectScheme":"Fields of Science and Technology (FOS)"}],"contributors":[],"dates":[{"date":"2013-03-20","dateType":"Created"},{"date":"2013-03-20","dateType":"Updated"},{"date":"2013","dateType":"Issued"}],"language":null,"types":{"ris":"DATA","bibtex":"misc","citeproc":"dataset","schemaOrg":"Dataset","resourceType":"Dataset","resourceTypeGeneral":"Dataset"},"relatedIdentifiers":[],"relatedItems":[],"sizes":["790924 Bytes"],"formats":[],"version":null,"rightsList":[{"rights":"Creative Commons Attribution 4.0 International","rightsUri":"https://creativecommons.org/licenses/by/4.0/legalcode","schemeUri":"https://spdx.org/licenses/","rightsIdentifier":"cc-by-4.0","rightsIdentifierScheme":"SPDX"}],"descriptions":[{"description":"Mixed ligand complexes of Fe(III) of the type and [Fe(bzac) L], where bzac is\u003cbr\u003ebenzoylacetone and HL is substituted salicylaldehyde, â-Diketones or hydroxylaryl\u003cbr\u003eketones have been synthesized by the condensation reactions of Iron (III) chloride with\u003cbr\u003ea mixture of two different ligands in 1:2:1 molar ratios. The solid complexes were\u003cbr\u003eseparated, filtered, washed with ethanol and ether successively and dried under reduced\u003cbr\u003epressure. The resulting complexes have been characterized by elemental analyses, molar\u003cbr\u003econductances, magnetic moments, electronic spectra, IR spectra and FAB mass spectra\u003cbr\u003eanalysis. At the same time, above mentioned complexes were studied for in vitro\u003cbr\u003eantimicrobial properties and found to be more potent bactericides than parent ligands.\u003cbr\u003eOctahedral geometry has been proposed for the mixed ligand complexes","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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","url":"https://figshare.com/articles/dataset/_SYNTHESIS_AND_SPECTRAL_STUDIES_OF_MIXED_LIGAND_COMPLEXES_OF_FE_III_WITH_BENZOYLACETONE_AND_SALICYLALDEHYDE_SUBSTITUTED_SALICYLALDEHYDES_2_HYDROXY_ARYL_CARBONYL_COMPOUNDS_OR_DIKETONES_/654811","contentUrl":null,"metadataVersion":2,"schemaVersion":"http://datacite.org/schema/kernel-4","source":"mds","isActive":true,"state":"findable","reason":null,"viewCount":0,"viewsOverTime":[],"downloadCount":0,"downloadsOverTime":[],"referenceCount":0,"citationCount":0,"citationsOverTime":[],"partCount":0,"partOfCount":0,"versionCount":0,"versionOfCount":0,"created":"2013-03-20T07:34:06.000Z","registered":"2013-03-20T07:34:07.000Z","published":"2013","updated":"2020-09-05T02:24:16.000Z"},"relationships":{"client":{"data":{"id":"figshare.ars","type":"clients"}},"provider":{"data":{"id":"otjm","type":"providers"}},"media":{"data":{"id":"10.6084/m9.figshare.654811","type":"media"}},"references":{"data":[]},"citations":{"data":[]},"parts":{"data":[]},"partOf":{"data":[]},"versions":{"data":[]},"versionOf":{"data":[]}}}}