{"data":{"id":"10.6084/m9.figshare.6008150.v1","type":"dois","attributes":{"doi":"10.6084/m9.figshare.6008150.v1","prefix":"10.6084","suffix":"m9.figshare.6008150.v1","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Mesias, Ricardo","nameType":"Personal","givenName":"Ricardo","familyName":"Mesias","affiliation":[],"nameIdentifiers":[]},{"name":"Murillo, Edwin","nameType":"Personal","givenName":"Edwin","familyName":"Murillo","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Hyperbranched polyester polyol modified with polylactic acid as a compatibilizer for plasticized tapioca starch/polylactic acid blends"}],"publisher":"SciELO journals","container":{},"publicationYear":2018,"subjects":[{"subject":"91209 Polymers and Plastics","subjectScheme":"FOR"},{"subject":"FOS: Materials engineering","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Materials engineering","subjectScheme":"Fields of Science and Technology (FOS)"}],"contributors":[],"dates":[{"date":"2018-03-21","dateType":"Created"},{"date":"2018-03-21","dateType":"Updated"},{"date":"2018","dateType":"Issued"}],"language":null,"types":{"ris":"DATA","bibtex":"misc","citeproc":"dataset","schemaOrg":"Dataset","resourceType":"Dataset","resourceTypeGeneral":"Dataset"},"relatedIdentifiers":[{"relationType":"IsSupplementTo","relatedIdentifier":"10.1590/0104-1428.09516","relatedIdentifierType":"DOI"},{"relationType":"IsIdenticalTo","relatedIdentifier":"10.6084/m9.figshare.6008150","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":["482510 Bytes"],"formats":[],"version":null,"rightsList":[{"rights":"Creative Commons Attribution 4.0 International","rightsUri":"https://creativecommons.org/licenses/by/4.0/legalcode","schemeUri":"https://spdx.org/licenses/","rightsIdentifier":"cc-by-4.0","rightsIdentifierScheme":"SPDX"}],"descriptions":[{"description":"Abstract A hyperbranched polyester polyol of the second generation (HBP2) was modified with polylactic acid (HBP2-g-PLA) and employed as a compatibilizer for plasticized tapioca starch (TPS)/polylactic acid (PLA) blends. The effect of the compatibilizer HBP2- g-PLA was evaluated in comparison to the control sample (TPS/PLA blend without HBP2-g-PLA). The torque value of the TPS/PLA blends with HBP2- g-PLA was lower than that of the control sample, while thermal stability and crystallinity followed opposite behavior. The glass transition temperature (Tg) and degree of crystallinity of the TPS/PLA blends with HBP2-g-PLA decreased with increasing mass fraction of HBP2-g-PLA. By scanning electron microscopy (SEM), it was observed that the morphology of the TPS/PLA blends with HBP2-g -PLA was more homogeneous than that of the control sample, confirming that HBP2- g-PLA acted as a compatibilizer and plasticizing agent to the TPS/PLA blends. Rheological analysis of the compatibilized TPS/PLA blends indicated the presence of microstructure.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"PD94bWwgdmVyc2lvbj0iMS4wIiBlbmNvZGluZz0iVVRGLTgiPz4KPHJlc291cmNlIHhtbG5zPSJodHRwOi8vZGF0YWNpdGUub3JnL3NjaGVtYS9rZXJuZWwtNCIgeG1sbnM6eHNpPSJodHRwOi8vd3d3LnczLm9yZy8yMDAxL1hNTFNjaGVtYS1pbnN0YW5jZSIgeHNpOnNjaGVtYUxvY2F0aW9uPSJodHRwOi8vZGF0YWNpdGUub3JnL3NjaGVtYS9rZXJuZWwtNCBodHRwOi8vc2NoZW1hLmRhdGFjaXRlLm9yZy9tZXRhL2tlcm5lbC00LjEvbWV0YWRhdGEueHNkIj4KICA8aWRlbnRpZmllciBpZGVudGlmaWVyVHlwZT0iRE9JIj4xMC42MDg0L005LkZJR1NIQVJFLjYwMDgxNTAuVjE8L2lkZW50aWZpZXI+CiAgPGNyZWF0b3JzPgogICAgPGNyZWF0b3I+CiAgICAgIDxjcmVhdG9yTmFtZT5SaWNhcmRvIE1lc2lhczwvY3JlYXRvck5hbWU+CiAgICA8L2NyZWF0b3I+CiAgICA8Y3JlYXRvcj4KICAgICAgPGNyZWF0b3JOYW1lPkVkd2luIE11cmlsbG88L2NyZWF0b3JOYW1lPgogICAgPC9jcmVhdG9yPgogIDwvY3JlYXRvcnM+CiAgPHRpdGxlcz4KICAgIDx0aXRsZT5IeXBlcmJyYW5jaGVkIHBvbHllc3RlciBwb2x5b2wgbW9kaWZpZWQgd2l0aCBwb2x5bGFjdGljIGFjaWQgYXMgYSBjb21wYXRpYmlsaXplciBmb3IgcGxhc3RpY2l6ZWQgdGFwaW9jYSBzdGFyY2gvcG9seWxhY3RpYyBhY2lkIGJsZW5kczwvdGl0bGU+CiAgPC90aXRsZXM+CiAgPGRlc2NyaXB0aW9ucz4KICAgIDxkZXNjcmlwdGlvbiBkZXNjcmlwdGlvblR5cGU9IkFic3RyYWN0Ij4mbHQ7ZGl2Jmd0OyZsdDtwJmd0O0Fic3RyYWN0ICBBIGh5cGVyYnJhbmNoZWQgcG9seWVzdGVyIHBvbHlvbCBvZiB0aGUgc2Vjb25kIGdlbmVyYXRpb24gKEhCUDIpIHdhcyBtb2RpZmllZCB3aXRoIHBvbHlsYWN0aWMgYWNpZCAoSEJQMi1nLVBMQSkgYW5kIGVtcGxveWVkIGFzIGEgY29tcGF0aWJpbGl6ZXIgZm9yIHBsYXN0aWNpemVkIHRhcGlvY2Egc3RhcmNoIChUUFMpL3BvbHlsYWN0aWMgYWNpZCAoUExBKSBibGVuZHMuIFRoZSBlZmZlY3Qgb2YgdGhlIGNvbXBhdGliaWxpemVyIEhCUDItIGctUExBIHdhcyBldmFsdWF0ZWQgaW4gY29tcGFyaXNvbiB0byB0aGUgY29udHJvbCBzYW1wbGUgKFRQUy9QTEEgYmxlbmQgd2l0aG91dCBIQlAyLWctUExBKS4gVGhlIHRvcnF1ZSB2YWx1ZSBvZiB0aGUgVFBTL1BMQSBibGVuZHMgd2l0aCBIQlAyLSBnLVBMQSB3YXMgbG93ZXIgdGhhbiB0aGF0IG9mIHRoZSBjb250cm9sIHNhbXBsZSwgd2hpbGUgdGhlcm1hbCBzdGFiaWxpdHkgYW5kIGNyeXN0YWxsaW5pdHkgZm9sbG93ZWQgb3Bwb3NpdGUgYmVoYXZpb3IuIFRoZSBnbGFzcyB0cmFuc2l0aW9uIHRlbXBlcmF0dXJlIChUZykgYW5kIGRlZ3JlZSBvZiBjcnlzdGFsbGluaXR5IG9mIHRoZSBUUFMvUExBIGJsZW5kcyB3aXRoIEhCUDItZy1QTEEgZGVjcmVhc2VkIHdpdGggaW5jcmVhc2luZyBtYXNzIGZyYWN0aW9uIG9mIEhCUDItZy1QTEEuIEJ5IHNjYW5uaW5nIGVsZWN0cm9uIG1pY3Jvc2NvcHkgKFNFTSksIGl0IHdhcyBvYnNlcnZlZCB0aGF0IHRoZSBtb3JwaG9sb2d5IG9mIHRoZSBUUFMvUExBIGJsZW5kcyB3aXRoIEhCUDItZyAtUExBIHdhcyBtb3JlIGhvbW9nZW5lb3VzIHRoYW4gdGhhdCBvZiB0aGUgY29udHJvbCBzYW1wbGUsIGNvbmZpcm1pbmcgdGhhdCBIQlAyLSBnLVBMQSBhY3RlZCBhcyBhIGNvbXBhdGliaWxpemVyIGFuZCBwbGFzdGljaXppbmcgYWdlbnQgdG8gdGhlIFRQUy9QTEEgYmxlbmRzLiBSaGVvbG9naWNhbCBhbmFseXNpcyBvZiB0aGUgY29tcGF0aWJpbGl6ZWQgVFBTL1BMQSBibGVuZHMgaW5kaWNhdGVkIHRoZSBwcmVzZW5jZSBvZiBtaWNyb3N0cnVjdHVyZS4mbHQ7L3AmZ3Q7Jmx0Oy9kaXYmZ3Q7PC9kZXNjcmlwdGlvbj4KICA8L2Rlc2NyaXB0aW9ucz4KICA8c3ViamVjdHM+CiAgICA8c3ViamVjdCBzY2hlbWVVUkk9Imh0dHA6Ly93d3cuYWJzLmdvdi5hdS9hdXNzdGF0cy9hYnNALm5zZi8wLzZCQjQyN0FCOTY5NkMyMjVDQTI1NzQxODAwMDQ0NjNFIiBzdWJqZWN0U2NoZW1lPSJGT1IiPjkxMjA5IFBvbHltZXJzIGFuZCBQbGFzdGljczwvc3ViamVjdD4KICA8L3N1YmplY3RzPgogIDxwdWJsaXNoZXI+U2NpRUxPIGpvdXJuYWxzPC9wdWJsaXNoZXI+CiAgPHB1YmxpY2F0aW9uWWVhcj4yMDE4PC9wdWJsaWNhdGlvblllYXI+CiAgPGRhdGVzPgogICAgPGRhdGUgZGF0ZVR5cGU9IkNyZWF0ZWQiPjIwMTgtMDMtMjE8L2RhdGU+CiAgICA8ZGF0ZSBkYXRlVHlwZT0iVXBkYXRlZCI+MjAxOC0wMy0yMTwvZGF0ZT4KICA8L2RhdGVzPgogIDxyZXNvdXJjZVR5cGUgcmVzb3VyY2VUeXBlR2VuZXJhbD0iRGF0YXNldCI+RGF0YXNldDwvcmVzb3VyY2VUeXBlPgogIDxzaXplcz4KICAgIDxzaXplPjQ4MjUxMCBCeXRlczwvc2l6ZT4KICA8L3NpemVzPgogIDxyZWxhdGVkSWRlbnRpZmllcnM+CiAgICA8cmVsYXRlZElkZW50aWZpZXIgcmVsYXRlZElkZW50aWZpZXJUeXBlPSJET0kiIHJlbGF0aW9uVHlwZT0iSXNTdXBwbGVtZW50VG8iPjEwLjE1OTAvMDEwNC0xNDI4LjA5NTE2PC9yZWxhdGVkSWRlbnRpZmllcj4KICAgIDxyZWxhdGVkSWRlbnRpZmllciByZWxhdGVkSWRlbnRpZmllclR5cGU9IkRPSSIgcmVsYXRpb25UeXBlPSJJc0lkZW50aWNhbFRvIj4xMC42MDg0L205LmZpZ3NoYXJlLjYwMDgxNTA8L3JlbGF0ZWRJZGVudGlmaWVyPgogIDwvcmVsYXRlZElkZW50aWZpZXJzPgogIDxyaWdodHNMaXN0PgogICAgPHJpZ2h0cyByaWdodHNVUkk9Imh0dHBzOi8vY3JlYXRpdmVjb21tb25zLm9yZy9saWNlbnNlcy9ieS80LjAvIj5DQyBCWSA0LjA8L3JpZ2h0cz4KICA8L3JpZ2h0c0xpc3Q+CjwvcmVzb3VyY2U+","url":"https://scielo.figshare.com/articles/Hyperbranched_polyester_polyol_modified_with_polylactic_acid_as_a_compatibilizer_for_plasticized_tapioca_starch_polylactic_acid_blends/6008150/1","contentUrl":null,"metadataVersion":2,"schemaVersion":"http://datacite.org/schema/kernel-4","source":"mds","isActive":true,"state":"findable","reason":null,"viewCount":0,"viewsOverTime":[],"downloadCount":0,"downloadsOverTime":[],"referenceCount":1,"citationCount":0,"citationsOverTime":[],"partCount":0,"partOfCount":0,"versionCount":0,"versionOfCount":0,"created":"2018-03-21T02:44:03.000Z","registered":"2018-03-21T02:44:03.000Z","published":"2018","updated":"2020-08-30T07:32:01.000Z"},"relationships":{"client":{"data":{"id":"figshare.ars","type":"clients"}},"provider":{"data":{"id":"otjm","type":"providers"}},"media":{"data":{"id":"10.6084/m9.figshare.6008150.v1","type":"media"}},"references":{"data":[{"id":"10.1590/0104-1428.09516","type":"dois"}]},"citations":{"data":[]},"parts":{"data":[]},"partOf":{"data":[]},"versions":{"data":[]},"versionOf":{"data":[]}}}}