{"data":{"id":"10.6084/m9.figshare.5862294","type":"dois","attributes":{"doi":"10.6084/m9.figshare.5862294","prefix":"10.6084","suffix":"m9.figshare.5862294","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"A. M. Elias","affiliation":[],"nameIdentifiers":[]},{"name":"V. C. N. Santana","affiliation":[],"nameIdentifiers":[]},{"name":"G. L. V. Coelho","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Measurement of Activity Coefficients at Infinite Dilution for Alcohols in [BMIM][CH3SO4] using HS-SPME/GC-FID"}],"publisher":"SciELO journals","container":{},"publicationYear":2018,"subjects":[{"subject":"90499 Chemical Engineering not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Chemical engineering","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Chemical engineering","subjectScheme":"Fields of Science and Technology (FOS)"}],"contributors":[],"dates":[{"date":"2018-02-07","dateType":"Created"},{"date":"2018-02-07","dateType":"Updated"},{"date":"2018","dateType":"Issued"}],"language":null,"types":{"ris":"DATA","bibtex":"misc","citeproc":"dataset","schemaOrg":"Dataset","resourceType":"Dataset","resourceTypeGeneral":"Dataset"},"relatedIdentifiers":[{"relationType":"IsSupplementTo","relatedIdentifier":"10.1590/0104-6632.20170343s20150640","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":["213457 Bytes"],"formats":[],"version":null,"rightsList":[{"rights":"Creative Commons Attribution 4.0 International","rightsUri":"https://creativecommons.org/licenses/by/4.0/legalcode","schemeUri":"https://spdx.org/licenses/","rightsIdentifier":"cc-by-4.0","rightsIdentifierScheme":"SPDX"}],"descriptions":[{"description":"ABSTRACT The activity coefficient at infinite dilution (\u0026amp;IN1) and distribution ratios at infinite dilution (\u0026amp;IN2) were determined for alkanols (methanol, ethanol, 1-propanol, 1-butanol, 2-butanol, and 2-methyl-2-propanol) in the ionic liquid (IL) 1-butyl-3-methylimidazolium methyl sulfate ([BMIM][CH3SO4]) by HS-SPME (Headspace - Solid Phase Micro Extraction) at four temperatures (298.15, 313.15, 333.15, and 353.15K) using headspace - solid phase microextraction (SPME-HS). The results showed significant agreement with literature data. In addition, partial molar excess enthalpies at infinite dilution (\u0026amp;IN3), excess Gibbs energies (\u0026amp;IN4), and excess entropies (\u0026amp;IN5) were calculated from the (\u0026amp;IN6) values.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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","url":"https://scielo.figshare.com/articles/Measurement_of_Activity_Coefficients_at_Infinite_Dilution_for_Alcohols_in_BMIM_CH3SO4_using_HS-SPME_GC-FID/5862294","contentUrl":null,"metadataVersion":1,"schemaVersion":"http://datacite.org/schema/kernel-4","source":"mds","isActive":true,"state":"findable","reason":null,"viewCount":0,"viewsOverTime":[],"downloadCount":0,"downloadsOverTime":[],"referenceCount":0,"citationCount":0,"citationsOverTime":[],"partCount":0,"partOfCount":0,"versionCount":0,"versionOfCount":0,"created":"2018-02-07T02:58:50.000Z","registered":"2018-02-07T02:58:51.000Z","published":"2018","updated":"2020-08-30T17:58:31.000Z"},"relationships":{"client":{"data":{"id":"figshare.ars","type":"clients"}},"provider":{"data":{"id":"otjm","type":"providers"}},"media":{"data":{"id":"10.6084/m9.figshare.5862294","type":"media"}},"references":{"data":[]},"citations":{"data":[]},"parts":{"data":[]},"partOf":{"data":[]},"versions":{"data":[]},"versionOf":{"data":[]}}}}