{"data":{"id":"10.6084/m9.figshare.5861484.v1","type":"dois","attributes":{"doi":"10.6084/m9.figshare.5861484.v1","prefix":"10.6084","suffix":"m9.figshare.5861484.v1","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Kashish Aggarwal","affiliation":[],"nameIdentifiers":[]},{"name":"Anoop Verma","affiliation":[],"nameIdentifiers":[]},{"name":"Palak Bansal","affiliation":[],"nameIdentifiers":[]},{"name":"Amanjit Singh","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Heterogeneous photo-Fenton and photocatalytic degradation studies of 2-chloro-4-nitrophenol (2Cl4NP) using foundry sand and TiO2 coated cement/clay beads"}],"publisher":"SciELO journals","container":{},"publicationYear":2018,"subjects":[{"subject":"90499 Chemical Engineering not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Chemical engineering","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Chemical engineering","subjectScheme":"Fields of Science and Technology (FOS)"}],"contributors":[],"dates":[{"date":"2018-02-07","dateType":"Created"},{"date":"2018-02-07","dateType":"Updated"},{"date":"2018","dateType":"Issued"}],"language":null,"types":{"ris":"DATA","bibtex":"misc","citeproc":"dataset","schemaOrg":"Dataset","resourceType":"Dataset","resourceTypeGeneral":"Dataset"},"relatedIdentifiers":[{"relationType":"IsSupplementTo","relatedIdentifier":"10.1590/0104-6632.20170343s2015070","relatedIdentifierType":"DOI"},{"relationType":"IsIdenticalTo","relatedIdentifier":"10.6084/m9.figshare.5861484","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":["218474 Bytes"],"formats":[],"version":null,"rightsList":[{"rights":"Creative Commons Attribution 4.0 International","rightsUri":"https://creativecommons.org/licenses/by/4.0/legalcode","schemeUri":"https://spdx.org/licenses/","rightsIdentifier":"cc-by-4.0","rightsIdentifierScheme":"SPDX"}],"descriptions":[{"description":"ABSTRACT Cement and clay beads coated with TiO2were used for the photo-degradation and mineralization of 2-chloro-4-nitrophenol (2Cl4NP) along with a heterogeneous solar photo-Fenton process using foundry sand (FS) as the iron source. The degradation process was optimized using slurry photocatalysis where 96% degradation of 2Cl4NP was achieved in 120 min at optimized conditions of C0=50 mgL-1, pH=4, 0.75 gL-1 TiO2 and H2O2= 0.1 mL/200 mL. Degradation of 2Cl4NP was analyzed through HPLC along with UV-Visible spectrophotometer at 266 nm. The degradation of 68% and 52% of 2Cl4NP was attained in fixed-bed photocatalysis using cement and clay beads, respectively. The durability studies of cement and clay beads were carried out in terms of number of recycles. 97.19% degradation was obtained in a solar photo-Fenton process after 105 min at pH=3. Complete mineralization of 2Cl4NP was confirmed through reduction in COD along with the disappearance of the parent compound peak in HPLC chromatograms.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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","url":"https://scielo.figshare.com/articles/Heterogeneous_photo-Fenton_and_photocatalytic_degradation_studies_of_2-chloro-4-nitrophenol_2Cl4NP_using_foundry_sand_and_TiO2_coated_cement_clay_beads/5861484/1","contentUrl":null,"metadataVersion":2,"schemaVersion":"http://datacite.org/schema/kernel-4","source":"mds","isActive":true,"state":"findable","reason":null,"viewCount":0,"viewsOverTime":[],"downloadCount":0,"downloadsOverTime":[],"referenceCount":1,"citationCount":0,"citationsOverTime":[],"partCount":0,"partOfCount":0,"versionCount":0,"versionOfCount":0,"created":"2018-02-07T02:46:19.000Z","registered":"2018-02-07T02:46:19.000Z","published":"2018","updated":"2020-08-30T18:09:52.000Z"},"relationships":{"client":{"data":{"id":"figshare.ars","type":"clients"}},"provider":{"data":{"id":"otjm","type":"providers"}},"media":{"data":{"id":"10.6084/m9.figshare.5861484.v1","type":"media"}},"references":{"data":[{"id":"10.1590/01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