{"data":{"id":"10.6084/m9.figshare.5668840","type":"dois","attributes":{"doi":"10.6084/m9.figshare.5668840","prefix":"10.6084","suffix":"m9.figshare.5668840","identifiers":[],"alternateIdentifiers":[],"creators":[{"name":"Leite, Ana Karina Pereira","nameType":"Personal","givenName":"Ana Karina Pereira","familyName":"Leite","affiliation":[],"nameIdentifiers":[]},{"name":"Bráulio Silva Barros","affiliation":[],"nameIdentifiers":[]},{"name":"Kulesza, Joanna","nameType":"Personal","givenName":"Joanna","familyName":"Kulesza","affiliation":[],"nameIdentifiers":[]},{"name":"Jarley Fagner Silva Do Nascimento","affiliation":[],"nameIdentifiers":[]},{"name":"Melo, Dulce Maria De Araújo","nameType":"Personal","givenName":"Dulce Maria De Araújo","familyName":"Melo","affiliation":[],"nameIdentifiers":[]},{"name":"Oliveira, Angelo Anderson Silva De","nameType":"Personal","givenName":"Angelo Anderson Silva De","familyName":"Oliveira","affiliation":[],"nameIdentifiers":[]}],"titles":[{"title":"Modulator Effect of Acetic Acid on the Morphology of Luminescent Mixed Lanthanide-Organic Frameworks"}],"publisher":"SciELO journals","container":{},"publicationYear":2017,"subjects":[{"subject":"90499 Chemical Engineering not elsewhere classified","subjectScheme":"FOR"},{"subject":"FOS: Chemical engineering","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Chemical engineering","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"91207 Metals and Alloy Materials","subjectScheme":"FOR"},{"subject":"FOS: Materials engineering","schemeUri":"http://www.oecd.org/science/inno/38235147.pdf","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"FOS: Materials engineering","subjectScheme":"Fields of Science and Technology (FOS)"},{"subject":"91299 Materials Engineering not elsewhere classified","subjectScheme":"FOR"}],"contributors":[],"dates":[{"date":"2017-12-05","dateType":"Created"},{"date":"2017-12-05","dateType":"Updated"},{"date":"2017","dateType":"Issued"}],"language":null,"types":{"ris":"DATA","bibtex":"misc","citeproc":"dataset","schemaOrg":"Dataset","resourceType":"Dataset","resourceTypeGeneral":"Dataset"},"relatedIdentifiers":[{"relationType":"IsSupplementTo","relatedIdentifier":"10.1590/1980-5373-mr-2016-1015","relatedIdentifierType":"DOI"}],"relatedItems":[],"sizes":["2487227 Bytes"],"formats":[],"version":null,"rightsList":[{"rights":"Creative Commons Attribution 4.0 International","rightsUri":"https://creativecommons.org/licenses/by/4.0/legalcode","schemeUri":"https://spdx.org/licenses/","rightsIdentifier":"cc-by-4.0","rightsIdentifierScheme":"SPDX"}],"descriptions":[{"description":"The control of the size and morphology of Metal-Organic Frameworks is a challenge that must be overcome to ensure the use of these materials in advanced applications. Mixed Lanthanide-Organic Frameworks (MLOFs) were synthesized via solvo(hydro)thermal method and then characterized by PXRD, IR, TG/DTA, SEM and PL spectroscopy. The effect of the modulator (acetic acid) on the morphological characteristics of the obtained powders was investigated. Trivalent terbium ions were successfully incorporated into La-framework conferring green luminescence to the prepared samples. It was observed that a gradual increase in acetic acid concentration led to the morphology change from micro-rods to flower-like small particle agglomerates. Moreover, a higher concentration of the acetic acid prevented the crystallization of secondary phases.","descriptionType":"Abstract"}],"geoLocations":[],"fundingReferences":[],"xml":"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","url":"https://scielo.figshare.com/articles/Modulator_Effect_of_Acetic_Acid_on_the_Morphology_of_Luminescent_Mixed_Lanthanide-Organic_Frameworks/5668840","contentUrl":null,"metadataVersion":1,"schemaVersion":"http://datacite.org/schema/kernel-4","source":"mds","isActive":true,"state":"findable","reason":null,"viewCount":0,"viewsOverTime":[],"downloadCount":0,"downloadsOverTime":[],"referenceCount":0,"citationCount":0,"citationsOverTime":[],"partCount":0,"partOfCount":0,"versionCount":0,"versionOfCount":0,"created":"2017-12-05T09:44:00.000Z","registered":"2017-12-05T09:44:00.000Z","published":"2017","updated":"2020-08-31T09:21:05.000Z"},"relations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